负载型非晶态Co-B催化剂在1-辛烯氢甲酰化中的应用

引用本文: 龙俊英, 马兰, 贺德华. 负载型非晶态Co-B催化剂在1-辛烯氢甲酰化中的应用[J]. 物理化学学报, 2010, 26(10): 2719-2725. doi: 10.3866/PKU.WHXB20101022 shu

Citation: LONG Jun-Ying, MA Lan, HE De-Hua. 1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts[J]. Acta Physico-Chimica Sinica, 2010, 26(10): 2719-2725. doi: 10.3866/PKU.WHXB20101022 shu

负载型非晶态Co-B催化剂在1-辛烯氢甲酰化中的应用

基金项目:
国家自然科学基金(20921001)资助项目 (20921001)

摘要:

以醇凝胶-氮气热处理方法制备的ZrO₂、碳纳米管(CNTs) 及介孔分子筛SBA -15作为载体, 采用化学还原法制备了负载型非晶态Co-B催化剂, 利用粉末X 射线衍射(XRD) 、氮气吸附等温线、透射电子显微镜(TEM) 、电感耦合等离子体-原子发射光谱(ICP-AES) 以及X 射线光电子能谱(XPS) 等对催化剂进行了表征. 以1-辛烯的氢甲酰化为目标反应, 考察了负载型非晶态Co-B 催化剂在氢甲酰化反应中的性能及循环使用效果. 表征结果显示, 以NaBH₄ 为还原剂制备的负载型Co-B 催化剂上的Co-B 为非晶态, 负载Co-B 组分对载体的晶相结构没有影响. 反应结果表明, 在1-辛烯的氢甲酰化反应中, 负载型非晶态Co-B 催化剂都显示较高的初始活性. 随着循环次数的增加, 三种催化剂的活性下降, 但下降幅度有所不同, Co-B/CNTs 和Co-B/SBA-15 的循环使用稳定性高于Co-B/ZrO₂.

关键词:

English

1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts

1.
1. Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;
2. Institute of Chemical Defence, Beijing 102205, P. R. China
Received Date: 26 April 2010
Available Online: 27 September 2010
Fund Project:
国家自然科学基金(20921001)资助项目

Abstract:

Co-B catalysts supported on ZrO₂ (prepared by alcogel nitrogen thermo-treatment method), carbon nanotubes (CNTs), and mesoporous SBA-15 as supports were prepared by chemical reduction method and characterized by X-ray diffraction (XRD), nitrogen physisorption, transmission electron microscopy (TEM), inductively coupled plasma -atomic emission spectrometry (ICP-AES) and X-ray photoelectron spectroscopy (XPS). Hydroformylation of 1-octene was used as a probe reaction to investigate the catalytic performance and stability of the catalysts in recycles. The as-prepared Co-B catalysts showed amorphous characteristics and the support structures were unchanged. The reaction results reveal that the catalytic activities of Co-B/CNTs, Co-B/ZrO₂ and Co-B/SBA-15 in the hydroformylation of 1-octene were comparatively high. However, the catalytic activities decreased upon recycling. Nevertheless, the Co-B/ CNTs and Co-B/SBA-15 were relatively stable compared with Co-B/ZrO₂.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

负载型非晶态Co-B催化剂在1-辛烯氢甲酰化中的应用

English

1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

负载型非晶态Co-B催化剂在1-辛烯氢甲酰化中的应用

English

1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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