引用本文:
张国鼎, 于秀芳. 量热法研究Cr3+水解聚合作用的热力学性质[J]. 物理化学学报,
1995, 11(08): 766-768.
doi:
10.3866/PKU.WHXB19950821
Citation: Zhang Guo-Xiu, Yu xiu-Fang. Study on the Thermodynamical Functions of the Hydrolytic Polymerization of Chromium(III) Ion by Microcalorimetric Method[J]. Acta Physico-Chimica Sinica, 1995, 11(08): 766-768. doi: 10.3866/PKU.WHXB19950821
Citation: Zhang Guo-Xiu, Yu xiu-Fang. Study on the Thermodynamical Functions of the Hydrolytic Polymerization of Chromium(III) Ion by Microcalorimetric Method[J]. Acta Physico-Chimica Sinica, 1995, 11(08): 766-768. doi: 10.3866/PKU.WHXB19950821
English
Study on the Thermodynamical Functions of the Hydrolytic Polymerization of Chromium(III) Ion by Microcalorimetric Method
Abstract:
The hydrolytic polymerization of Cr3+ at relative high concentrations have measured by microcalorimetric method. The thermogram have determined using the 2277 Thermoal Activity Monitor. The heat of reaction (△rHm■), the hydrolysis equilibrium constans (K■) and thermodynamical function (△rGm■、△rSm■) at different temperatures have been calculated.
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