引用本文:
徐映宏, 邓郁. 热动力学的研究 X. 一级反应的热谱峰高法[J]. 物理化学学报,
1991, 7(05): 601-604.
doi:
10.3866/PKU.WHXB19910517
Citation: Xu Ying-Hong, Deng Yu. Studies on Thermokinetics X. Thermogram's Peak-Heights Method for First Order Reactions[J]. Acta Physico-Chimica Sinica, 1991, 7(05): 601-604. doi: 10.3866/PKU.WHXB19910517
Citation: Xu Ying-Hong, Deng Yu. Studies on Thermokinetics X. Thermogram's Peak-Heights Method for First Order Reactions[J]. Acta Physico-Chimica Sinica, 1991, 7(05): 601-604. doi: 10.3866/PKU.WHXB19910517
热动力学的研究 X. 一级反应的热谱峰高法
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关键词:
- 热动力学; 一级反应; 热谱峰高法
English
Studies on Thermokinetics X. Thermogram's Peak-Heights Method for First Order Reactions
Abstract:
In the previous articles~[1,2], a data processing method for studies on thermokinetics of a first order reaction in liquid phase had been developed. It was called the dimensionless parameter method, in which the dimensionless parameter and the rate constant of a reaction system were calculated from the thermogram's peak-area. In this paper in the light of a theoretical thermogram's equation of a first order reaction, a novel data processing method is proposed, in which the dimensionless parameter and the rate constant are calculated from the thermogram's peak-heights with-out using any peak-area. Thereby the problems arisen from the peak-area-computation can be avoided.
In order to test the validity of this novel method, ...
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