引用本文:
白同春, 王健吉, 刘文彬, 卢锦梭. 非水溶液盐效应的气液色谱研究——非电解质(烃、芳烃、氯代烃、酮)+盐(Nal、NaSCN、KSCN)+碳酸丙烯酯体系[J]. 物理化学学报,
1991, 7(04): 480-484.
doi:
10.3866/PKU.WHXB19910420
Citation: Bai Tong-Chun, Wang Jian-Ji, Liu Wen-Bin, Lu Jin-Suo. Study on the Salt Effect in Nonaqueous Solutions by Gas Liquid Chromatography——For Nonelectrolyte Solute (Hydrocarbons,Aromatic Hydrocarbons,Chloro-Hydrocarbons,Ketones) in Salt (Nal, NaSCN, KSCN) and Propy-Lene Carbonate Solutions[J]. Acta Physico-Chimica Sinica, 1991, 7(04): 480-484. doi: 10.3866/PKU.WHXB19910420
Citation: Bai Tong-Chun, Wang Jian-Ji, Liu Wen-Bin, Lu Jin-Suo. Study on the Salt Effect in Nonaqueous Solutions by Gas Liquid Chromatography——For Nonelectrolyte Solute (Hydrocarbons,Aromatic Hydrocarbons,Chloro-Hydrocarbons,Ketones) in Salt (Nal, NaSCN, KSCN) and Propy-Lene Carbonate Solutions[J]. Acta Physico-Chimica Sinica, 1991, 7(04): 480-484. doi: 10.3866/PKU.WHXB19910420
非水溶液盐效应的气液色谱研究——非电解质(烃、芳烃、氯代烃、酮)+盐(Nal、NaSCN、KSCN)+碳酸丙烯酯体系
English
Study on the Salt Effect in Nonaqueous Solutions by Gas Liquid Chromatography——For Nonelectrolyte Solute (Hydrocarbons,Aromatic Hydrocarbons,Chloro-Hydrocarbons,Ketones) in Salt (Nal, NaSCN, KSCN) and Propy-Lene Carbonate Solutions
Abstract:
The gas-liquid chromatographic method was used to measure the activity coefficients at infinite dilution (γ_1~∞) of some nonelectrolyte solutes in salt containing solutions of propylene carbonate at 333.2 K. For examining the relationship between lgγ_1~∞ and salt concentrations, the salt effect coefficients of solutes were calculated, and the interactions of solute with salt were disscused. Furthermore, the equilibrium constant of complex interaction between chloroform with anions has been obtained.
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