引用本文:
常光洁, 李隽. 等性扩展基杂化轨道的构造[J]. 物理化学学报,
1991, 7(04): 462-466.
doi:
10.3866/PKU.WHXB19910416
Citation: Chang Guang-Jie, Li Jun. A Constructuion Method of the Extended Basis Hybrid Orbital[J]. Acta Physico-Chimica Sinica, 1991, 7(04): 462-466. doi: 10.3866/PKU.WHXB19910416
Citation: Chang Guang-Jie, Li Jun. A Constructuion Method of the Extended Basis Hybrid Orbital[J]. Acta Physico-Chimica Sinica, 1991, 7(04): 462-466. doi: 10.3866/PKU.WHXB19910416
等性扩展基杂化轨道的构造
English
A Constructuion Method of the Extended Basis Hybrid Orbital
Abstract:
On the basis of the analysis of various construction methods of the hybrid orbitals, the conept of the extended basis hybrid orbital has been proposed for the hybrid orbital containing the atomic orbitals of nonvalent shell. Taking the bound conditions into account, we have derived the analytical form of the extended basis hybrid orbital with equivalent characters by using the principle of the maximum overlap. It is found that the hybrid character of one atomic orbital belonging to the central atom depends on its degree of overlap with the ligand orbitals. Some applications of this method have been given.
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