Citation: CAI Hong-Lan, AN Xue-Qin, SHEN Wei-Guo. Critical Phenomena of Three-component Nonaqueous Microemulsion Systemof DMA+AOT+n-octane[J]. Acta Physico-Chimica Sinica, 2007, 23(06): 921-925. doi: 10.3866/PKU.WHXB20070624
DMA+AOT+正辛烷三组分非水微乳体系的临界现象
采用折射率法在离临界温度7 K的范围内测定N,N-二甲基乙酰胺(DMA)与二-(2-乙基己基)琥珀酸酯磺酸钠(AOT)摩尔比为3.46的非水微乳体系(DMA+AOT+正辛烷)的温度-折射率(T-n)共存曲线, 利用标准曲线转化为温度-体积分数(T-φ)共存曲线和温度-有效体积分数(T-ψ)共存曲线, 进而求得临界指数β. 研究结果表明, 该体系的临界指数β与已经报道的微乳液不同, 在较宽的温度范围内均符合Fisher重整化理论值0.365. 分析实验数据, 获得指数因子B、Wegner校正项因子B1和共存曲线的直径籽d, 并讨论所选择的序参量的优劣性.
English
Critical Phenomena of Three-component Nonaqueous Microemulsion Systemof DMA+AOT+n-octane
The coexistence curves of (T-n) (T and n are temperature and refractive index, respectively) for the system of DMA+AOT+n-octane have been determined within about 7 K from the critical temperature (Tc) by measurements of refractive index at a constantmolar ratio of DMAto AOT (3.46). The coexistence curves of (T-n) have been converted to the coexistence curves of (T-φ) and (T-ψ) (φand ψare volume fraction and effective volume fraction, respectively) through the standard curves determined by measurements of refractive indexes at various volume fractions and temperatures. The critical exponent β was deduced from the coexistence curves, which was found to be inconsistent with the 3D-Ising value and approach the Fisher-normalization value 0.365 in a rather wide temperature range. The experimental results were also analyzed to obtain the critical amplitude B and the Wegner correction terms B1 to examine the diameters of coexistence curves, and to discuss the odness of the order parameter.
扫一扫看文章
计量
- PDF下载量: 2789
- 文章访问数: 3880
- HTML全文浏览量: 90

下载: