引用本文:
沈关林, 李学初, 宁宝纲, 楼南泉. Bi+N2O化学发光反应机理研究[J]. 物理化学学报,
1988, 4(01): 77-79.
doi:
10.3866/PKU.WHXB19880115
Citation: Shen Guanlin*, Li Xuechu, Ning Baogang, Lou Nanquan. THE MECHANISM OF CHEMILUMINESCENT REACTION OF Bi+N2O[J]. Acta Physico-Chimica Sinica, 1988, 4(01): 77-79. doi: 10.3866/PKU.WHXB19880115
Citation: Shen Guanlin*, Li Xuechu, Ning Baogang, Lou Nanquan. THE MECHANISM OF CHEMILUMINESCENT REACTION OF Bi+N2O[J]. Acta Physico-Chimica Sinica, 1988, 4(01): 77-79. doi: 10.3866/PKU.WHXB19880115
Bi+N2O化学发光反应机理研究
English
THE MECHANISM OF CHEMILUMINESCENT REACTION OF Bi+N2O
Abstract:
The emission spectra of BiO(A ~2Π_(1/2)) have been first obtained by studying the reaction Bi+N_2O in the heat pipe oven. 18 new bands are obtained from the emission spectra of BiO(A ~2Π_(1/2)) which are attributed to the reaction of atomic Bi~*(~2D_(3/2)) with N_2O(~1Σ_g~+). The metastable Bi~*(~2D_(3/2)) is produced by the following processes: Bi(~4S_(3/2))+N_2O(~1Σ_g~+)→BiO(X_2~2Π_(3/2)), and then,BiO(X_2~2Π_(3/2))+Bi(~4S_(3/2))→Bi~*(~2D_(3/2))+BiO(X_1~2Π_(1/2)).
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