Rheological, Thermal and Mechanical Properties of Biodegradable Poly(propylene carbonate)/Polylactide/Poly(1,2-propylene glycol adipate) Blown Films

Citation: Yan-ping Hao, Hui-li Yang, Gui-bao Zhang, Hui-liang Zhang, Ge Gao, Li-song Dong. Rheological, Thermal and Mechanical Properties of Biodegradable Poly(propylene carbonate)/Polylactide/Poly(1,2-propylene glycol adipate) Blown Films[J]. Chinese Journal of Polymer Science, 2015, 33(12): 1702-1712. doi: 10.1007/s10118-015-1714-z shu

Rheological, Thermal and Mechanical Properties of Biodegradable Poly(propylene carbonate)/Polylactide/Poly(1,2-propylene glycol adipate) Blown Films

1.
1. College of Chemistry, Jilin University, Changchun 130012, China
2.
2. Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
3.
4.
Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
5.
College of Chemistry, Jilin University, Changchun 130012, China

通讯作者: Hui-liang Zhang,

基金项目:
This work was financially supported by the fund of Science Technology Bureau of Jilin Province of China(No.20130305028NY), Chinese Science Academy(Changchun Branch)(No.2014SYHZ0019), the National High Technology Research and Development Program of China(863 Program)(No.2012AA062904) and the National Natural Science Foundation of China(No.51021003).

摘要: Poly(propylene carbonate)(PPC) was blended with polylactide(PLA) and poly(1,2-propylene glycol adipate)(PPA) using a twin screw extruder. Then the PPC/PLA/PPA films were prepared using the blown film technique. DMA results showed that PPA could act as a plasticizer and improve the miscibility between PPC and PLA. Crystal morphology displayed that blending PLA with the amorphous PPC led to a decrease of the spherulite size of PLA. The results of mechanical tests indicated that PPC-rich films showed high elongation at break and PLA-rich films showed high tear strength and good optical properties. The content of PPC and PLA significantly affected the physical properties of the films. With increasing PPC content, the melt strengths of the PPC/PLA/PPA films were enhanced. These findings contributed to the biodegradable materials application for designing and manufacturing polymer packaging.

关键词:

English

Rheological, Thermal and Mechanical Properties of Biodegradable Poly(propylene carbonate)/Polylactide/Poly(1,2-propylene glycol adipate) Blown Films

1.
1. College of Chemistry, Jilin University, Changchun 130012, China
2.
2. Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
3.
4.
Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
5.
College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: Hui-liang Zhang,

Received Date: 18 May 2015
Revised Date: 03 June 2015
Available Online: 05 December 2015
Fund Project:
This work was financially supported by the fund of Science Technology Bureau of Jilin Province of China(No.20130305028NY), Chinese Science Academy(Changchun Branch)(No.2014SYHZ0019), the National High Technology Research and Development Program of China(863 Program)(No.2012AA062904) and the National Natural Science Foundation of China(No.51021003).

Abstract: Poly(propylene carbonate)(PPC) was blended with polylactide(PLA) and poly(1,2-propylene glycol adipate)(PPA) using a twin screw extruder. Then the PPC/PLA/PPA films were prepared using the blown film technique. DMA results showed that PPA could act as a plasticizer and improve the miscibility between PPC and PLA. Crystal morphology displayed that blending PLA with the amorphous PPC led to a decrease of the spherulite size of PLA. The results of mechanical tests indicated that PPC-rich films showed high elongation at break and PLA-rich films showed high tear strength and good optical properties. The content of PPC and PLA significantly affected the physical properties of the films. With increasing PPC content, the melt strengths of the PPC/PLA/PPA films were enhanced. These findings contributed to the biodegradable materials application for designing and manufacturing polymer packaging.

Key words:

1. [1]
  Tao, J., Song, C.J., Cao, M.F., Hu, D., Liu, L., Liu, N. and Wang, S.F., Polym. Degrad. Stab., 2009, 94(4):575
2. [2]
  Li, J., Sun, C.R. and Zhang, X.Q., Polym. Compos., 2012, 33(10):1737
3. [3]
  Wang, N., Zhang, X.X., Yu, J.G. and Fang, J.M., Polym. Int., 2008, 57(9):1027
4. [4]
  Ma, X.F., Chang, P.R., Yu, J.G. and Wang, N., Carbohyd. Polym., 2008, 71(2):229
5. [5]
  Yao, M., Deng, H., Mai, F., Wang, K., Zhang, Q., Chen, F. and Fu, Q., Express Polym. Lett., 2011, 5(11):937
6. [6]
  Chen, L.J., Qin, Y.S., Wang, X.H., Zhao, X.J. and Wang, F.S., Polymer, 2011, 52(21):4873
7. [7]
  Jiao, J., Wang, S.J., Xiao, M., Xu, Y. and Meng, Y.Z., Polym. Eng. Sci., 2007, 47(2):174
8. [8]
  Zeng, S.S., Wang, S.J., Xiao, M., Han, D.M. and Meng, Y.Z., Carbohyd. Polym., 2011, 86(3):1260
9. [9]
  Xing, C.Y., Wang, H.T., Hu, Q.Q., Xu, F.F., Cao, X.J., You, J.C. and Li, Y.J., Carbohyd. Polym., 2013, 92(2):1921
10. [10]
  Wang, X.Y., Peng, S.W. and Dong, L.S., Colloid Polym. Sci., 2005, 284(2):167
11. [11]
  Li, Y.J. and Shimizu, H., ACS Appl. Mater. Inter., 2009, 1(8):1650
12. [12]
  Hao, Y.P., Ge, H.H., Han, L.J., Liang, H.Y., Zhang, H.L. and Dong, L.S., Polym. Bull., 2013, 70(7):1991
13. [13]
  Wu, D.D., Li, W., Zhao, Y., Deng, Y.J., Zhang, H.L., Zhang, H.X. and Dong, L.S., Chinese J. Polym. Sci., 2015, 33(3):444
14. [14]
  Wu, D.D., Li, W., Liang, H.Y., Hao, Y.P., Liu, S.R., Fang, J.Y., Zhang, H.L. and Dong, L.S., Chinese J. Polym. Sci., 2014, 32(7):914
15. [15]
  Wu, D.D., Li, W., Hao, Y.P., Li Z.L., Yang, H.L., Zhang, H.L., Zhang, H.X. and Dong, L.S., Polym. Bull., 2015, 72(4):851
16. [16]
  HiljanenVainio, M., Varpomaa, P., Seppala, J. and Tormala, P., Macromol. Chem. Phys., 1996, 197(4):1503
17. [17]
  Rashkov, I., Manolova, N., Li, S.M., Espartero, J.L. and Vert, M., Macromolecules, 1996, 29(1):50
18. [18]
  Chen, X.H., McCarthy, S.P. and Gross, R.A., Macromolecules, 1997, 30(15):4295
19. [19]
  Maglio, G., Migliozzi, A. and Palumbo, R., Polymer, 2003, 44(2):369
20. [20]
  Focarete, M.L., Scandola, M., Dobrzynski, P. and Kowalczuk, M., Macromolecules, 2002, 35(22):8472
21. [21]
  Wang, L., Ma, W., Gross, R.A. and McCarthy, S.P., Polym. Degrad. Stab., 1998, 59(1-3):161
22. [22]
  Martin, O. and Averous, L., Polymer, 2001, 42(14):6209
23. [23]
  Ljungberg, N. and Wesslen, B., J. Appl. Polym. Sci., 2002, 86(5):1227
24. [24]
  Ljungberg, N. and Wesslen, B., Biomacromolecules, 2005, 6(3):1789
25. [25]
  Ljungberg, N. and Wesslen, B., Polymer, 2003, 44(25):7679
26. [26]
  Zhang, H.L., Fang, J.Y., Ge, H.H., Han, L.J., Wang, X.M., Hao, Y.P., Han, C.Y. and Dong, L.S., Polym. Eng. Sci., 2013, 53(1):112
27. [27]
  Ge, H.H., Yang, F., Hao, Y.P., Wu, G.F., Zhang, H.L. and Dong, L.S., J. Appl. Polym. Sci., 2013, 127(4):2832
28. [28]
  Ma, X.F. and Yu, J.G., J. Polym. Sci., Part B:Polym. Phys., 2006, 44(1):94
29. [29]
  Park, D.H., Kan, T.G., Lee, Y.K. and Kim, W.N., J. Mater. Sci., 2013, 48(1):481
30. [30]
  Ge, X.C., Zhu, Q. and Meng, Y.Z., J. Appl. Polym. Sci., 2006, 99(3):782
31. [31]
  Hirotsu, T., Ketelaars, A.A.J. and Nakayama, K., Polym. Degrad. Stab., 2000, 68(3):311
32. [32]
  Li, J., Lai, F. and Liu, J.J., J. Appl. Polym. Sci., 2004, 92(4):2514
33. [33]
  Fischer, E.W., Sterzel, H.J. and Wegner, G., Colloid Polym. Sci., 1973, 251(11):980
34. [34]
  Sarasua, J.R., Prud'Homme, R.E., Wisniewski, M., Borgne, A.L. and Spassky, N., Macromolecules, 1998, 31(12):3895
35. [35]
  Zhao, Y.Q., Cheung, H.Y., Lau, K.T., Xu, C.L., Zhao, D.D. and Li, H.L., Polym. Degrad. Stab., 2010, 95(10):1978
36. [36]
  Jiang, L., Wolcott, M.P. and Zhang, J.W., Biomacromolecules, 2006, 7(1):199
37. [37]
  Lin, Y., Zhang, K.Y., Dong, Z.M., Dong, L.S. and Li, Y.S., Macromolecules, 2007, 40(17):6257
38. [38]
  Gao, M., Ren, Z.J., Yan, S.K., Sun, J.R. and Chen, X.S., J. Phys. Chem. B., 2012, 116(32):9832
39. [39]
  Sun, P., Zheng L.X. and Chui, C.Z., China Plastic Industry(in Chinese), 2009, 37(10):22

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Rheological, Thermal and Mechanical Properties of Biodegradable Poly(propylene carbonate)/Polylactide/Poly(1,2-propylene glycol adipate) Blown Films

通讯作者: Hui-liang Zhang,

English

Rheological, Thermal and Mechanical Properties of Biodegradable Poly(propylene carbonate)/Polylactide/Poly(1,2-propylene glycol adipate) Blown Films

Corresponding author: Hui-liang Zhang,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Rheological, Thermal and Mechanical Properties of Biodegradable Poly(propylene carbonate)/Polylactide/Poly(1,2-propylene glycol adipate) Blown Films

通讯作者: Hui-liang Zhang,

English

Rheological, Thermal and Mechanical Properties of Biodegradable Poly(propylene carbonate)/Polylactide/Poly(1,2-propylene glycol adipate) Blown Films

Corresponding author: Hui-liang Zhang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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