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含二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸的Co(Ⅱ)配合物的合成、晶体结构及光催化性能研究

施伟东 ,  任傲 ,  刘春波 ,  白红叶 ,  车广波 ,  孙赫一 ,  丛尧

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引用本文: 施伟东, 任傲, 刘春波, 白红叶, 车广波, 孙赫一, 丛尧. 含二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸的Co(Ⅱ)配合物的合成、晶体结构及光催化性能研究[J]. 无机化学学报, 2013, 29(12): 2649-2654. doi: 10.3969/j.issn.1001-4861.2013.00.404 shu
Citation:  SHI Wei-Dong, REN Ao, LIU Chun-Bo, BAI Hong-Ye, CHE Guang-Bo, SUN He-Yi, CONG Yao. Synthesis, Crystal Structure and Photocatalytic Property of Co(Ⅱ) Compound with Dipyrido[3,2-a∶2’,3’-c]-phenazine-2-carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2649-2654. doi: 10.3969/j.issn.1001-4861.2013.00.404 shu

含二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸的Co(Ⅱ)配合物的合成、晶体结构及光催化性能研究

  • 基金项目:

    国家科学自然基金(No.61205040)，江苏大学自然科学基金(No.09JDG001，11jdg104)，江苏省自然科学基金(No.BK2012701，BK2011528)资助项目。 (No.61205040)，江苏大学自然科学基金(No.09JDG001，11jdg104)，江苏省自然科学基金(No.BK2012701，BK2011528)

摘要: 本文利用二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸(HDPPZC)作为有机配体在水热条件下制备了配合物[CoCl0.5(H2O)0.5(HDPPZC)2](PW12O40)0.5·3.5H2O (1)，利用X-射线单晶衍射、元素分析、紫外可见吸收光谱和差热分析对该化合物的结构进行了表征。单晶结构分析表明该晶体属于三斜晶系，P1空间群，晶胞系数a=1.036 0(2) nm，b=1.564 0(3) nm，c=1.656 0(3) nm，α=80.99(3)°，β=84.93(3)°，γ=85.44(3)°，V=2.6339(9) nm3，Z=1。配合物1是由零维离散结构通过氢键和π-π堆积形成的二维超分子结构。本文还研究了该化合物对罗丹明B的光催化降解性质。

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  • 收稿日期:  2013-05-14
  • 网络出版日期:  2013-10-09
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