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Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物

孙岳 ,  张先徽 ,  那延祥 ,  李昌立 ,  冯克成

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引用本文: 孙岳, 张先徽, 那延祥, 李昌立, 冯克成. Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物[J]. 无机化学学报, 2013, 29(12): 2568-2574. doi: 10.3969/j.issn.1001-4861.2013.00.401 shu
Citation:  SUN Yue, ZHANG Xian-Hui, NA Yan-Xiang, LI Chang-Li, FENG Ke-Cheng. Construction of Organic-Inorganic Hybrid from Dawson-Type Tungstophosphate and Tetranuclear Copper Complex[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2568-2574. doi: 10.3969/j.issn.1001-4861.2013.00.401 shu

Dawson型磷钨酸盐与混合配体桥连的四核Cu-Phen配合物构筑的杂化物

摘要: 通过水热合成得到了一个新颖的包含四核铜配合物的无机-有机杂化化合物[CuCl(H2O)4)][CuCl(H2O)(Phen)][{(CuPhen)2Cl2}2(bdc)]2[P2W18O62]·5H2O (1)(Phen=1，10-phenanthroline和bdc=1，4-benzenedicarboxylate)，对其进行了元素分析、红外光谱、热重、电化学等表征，并用X-射线单晶衍射测定了它的晶体结构。化合物1含有由Cl和bdc桥连的四核铜配合物阳离子[{(CuPhen)2Cl2}2(bdc)]2+。此外，化合物1的电化学研究表明其对亚硝酸的还原具有很好的电催化活性。

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    1. [1] Pope M T, MÜ ller A. Angew. Chem. Int. Ed., 1991, 30:34-48[1] Pope M T, MÜ ller A. Angew. Chem. Int. Ed., 1991, 30:34-48

    2. [2] Hill C L, Prosser-McCartha C M. Coord. Chem. Rev., 1995, 143:407-455[2] Hill C L, Prosser-McCartha C M. Coord. Chem. Rev., 1995, 143:407-455

    3. [3] MÜ ller A, Peters F, Pope M T, et al. Chem. Rev., 1998, 98: 239-271[3] MÜ ller A, Peters F, Pope M T, et al. Chem. Rev., 1998, 98: 239-271

    4. [4] Rhule J T, Hill C L, Judd D A, et al. Chem. Rev., 1998, 98: 327-357[4] Rhule J T, Hill C L, Judd D A, et al. Chem. Rev., 1998, 98: 327-357

    5. [5] Gouzerh P, Proust A. Chem. Rev., 1998, 98:77-111[5] Gouzerh P, Proust A. Chem. Rev., 1998, 98:77-111

    6. [6] Clemente-Juan J M, Coronado R. Coord. Chem. Rev., 1999, 193-195:361-394[6] Clemente-Juan J M, Coronado R. Coord. Chem. Rev., 1999, 193-195:361-394

    7. [7] Hagraman P J, Hagraman K, Zubieta J. Angew. Chem. Int. Ed, 1999, 38:2638-2684[7] Hagraman P J, Hagraman K, Zubieta J. Angew. Chem. Int. Ed, 1999, 38:2638-2684

    8. [8] Chesnut D J, Hagrman D, Zapf P J, et al. J. Coord. Chem. Rev., 1999, 190-192:737-769[8] Chesnut D J, Hagrman D, Zapf P J, et al. J. Coord. Chem. Rev., 1999, 190-192:737-769

    9. [9] Hagrman P J, Finn R C, Zubieta J. Solid State Sci., 2001, 3: 745-774[9] Hagrman P J, Finn R C, Zubieta J. Solid State Sci., 2001, 3: 745-774

    10. [10] Kozhevnikov I V. Catalsis by Polyoxometalates. Chichester (UK): Wiley, 2002.[10] Kozhevnikov I V. Catalsis by Polyoxometalates. Chichester (UK): Wiley, 2002.

    11. [11] Contant R, Hervé G. Rev. Inorg. Chem., 2002, 22:63-111[11] Contant R, Hervé G. Rev. Inorg. Chem., 2002, 22:63-111

    12. [12] Ushak S, Spodine E, Fur E L, et al. Inorg. Chem., 2006, 45: 5393-5399[12] Ushak S, Spodine E, Fur E L, et al. Inorg. Chem., 2006, 45: 5393-5399

    13. [13] Burrows A D, Chan C W, Chowdhry M M. Chem. Soc. Rev., 1995, 24:329-339[13] Burrows A D, Chan C W, Chowdhry M M. Chem. Soc. Rev., 1995, 24:329-339

    14. [14] Wang S T, Wang E B, Hou Y, et al. Inorg. Chim. Acta, 2003, 349:123-127[14] Wang S T, Wang E B, Hou Y, et al. Inorg. Chim. Acta, 2003, 349:123-127

    15. [15] Ghosh A K, Ghoshal D, Ribas J, et al. Cryst. Growth Des., 2006, 6:36-39[15] Ghosh A K, Ghoshal D, Ribas J, et al. Cryst. Growth Des., 2006, 6:36-39

    16. [16] Reinoso S, Vitoria P, Felices L S, et al. Chem. Eur. J., 2005, 11:1538-1548[16] Reinoso S, Vitoria P, Felices L S, et al. Chem. Eur. J., 2005, 11:1538-1548

    17. [17] Reinoso S, Vitoria P, Felices L S, et al. Inorg. Chem., 2006, 45:108-118[17] Reinoso S, Vitoria P, Felices L S, et al. Inorg. Chem., 2006, 45:108-118

    18. [18] Shivaiah V, Chatterijee T, Srinivasu K, et al. Eur. J. Inorg. Chem., 2007:231-234[18] Shivaiah V, Chatterijee T, Srinivasu K, et al. Eur. J. Inorg. Chem., 2007:231-234

    19. [19] Reinoso S, Vitoria P, Gutié rrez-Zorrilla J M, et al. Inorg. Chem., 2007, 46:4010-4021[19] Reinoso S, Vitoria P, Gutié rrez-Zorrilla J M, et al. Inorg. Chem., 2007, 46:4010-4021

    20. [20] Bian H, Xu J, Gu W, et al. Inorg. Chem. Commun., 2003, 6: 573-576[20] Bian H, Xu J, Gu W, et al. Inorg. Chem. Commun., 2003, 6: 573-576

    21. [21] Mukherjee P A, Hoshal D, Zangrando E, et al. Eur. J. Inorg. Chem., 2004:4675-4680[21] Mukherjee P A, Hoshal D, Zangrando E, et al. Eur. J. Inorg. Chem., 2004:4675-4680

    22. [22] Paul B, Zimmermann B, Fromm K M, et al. Z. Anorg. Allgem. Chem., 2004, 630:1650-1654[22] Paul B, Zimmermann B, Fromm K M, et al. Z. Anorg. Allgem. Chem., 2004, 630:1650-1654

    23. [23] Contant R. Inorg. Synth., 1990, 27:104-109[23] Contant R. Inorg. Synth., 1990, 27:104-109

    24. [24] WANG En-Bo (王恩波), HU Chang-Wen (胡长文), XU Lin (许琳). Introduction of Polyacid Chemistry (多酸化学导论). Beijing: Chemical Industry Press, 1998.[24] WANG En-Bo (王恩波), HU Chang-Wen (胡长文), XU Lin (许琳). Introduction of Polyacid Chemistry (多酸化学导论). Beijing: Chemical Industry Press, 1998.

    25. [25] Zhang C D, Liu S X, Ma F J, et al. Dalton Trans., 2010, 39: 8033-8037[25] Zhang C D, Liu S X, Ma F J, et al. Dalton Trans., 2010, 39: 8033-8037

    26. [26] Zhao J W, Zheng S T, Liu W, et al. J. Solid State Chem., 2008, 181:637-645[26] Zhao J W, Zheng S T, Liu W, et al. J. Solid State Chem., 2008, 181:637-645

    27. [27] Niu J, Guo D, Zhao J, et al. New J. Chem., 2004, 28:980- 987[27] Niu J, Guo D, Zhao J, et al. New J. Chem., 2004, 28:980- 987

    28. [28] Lu Y, Xu Y, Li Y, et al. Inorg. Chem., 2006, 45:2055-2060[28] Lu Y, Xu Y, Li Y, et al. Inorg. Chem., 2006, 45:2055-2060

    29. [29] Tian A, Ying J, Peng J, et al. Inorg. Chem., 2008, 47:3274- 3283[29] Tian A, Ying J, Peng J, et al. Inorg. Chem., 2008, 47:3274- 3283

    30. [30] Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3896[30] Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3896

    31. [31] Deakin L, Arif A M, Miller J S. Inorg. Chem., 1999, 38: 5072-5077[31] Deakin L, Arif A M, Miller J S. Inorg. Chem., 1999, 38: 5072-5077

    32. [32] Massoud S S, Mautner F A, Vicente R, et al. Inorg. Chim. Acta, 2006, 359:1489-1500[32] Massoud S S, Mautner F A, Vicente R, et al. Inorg. Chim. Acta, 2006, 359:1489-1500

    33. [33] Sadakane M, Steckhan E. Chem. Rev., 1998, 98:219-237[33] Sadakane M, Steckhan E. Chem. Rev., 1998, 98:219-237

    34. [34] McCormac T, Fabre B, Bidan G J. Electroanal. Chem., 1997, 425:49-54[34] McCormac T, Fabre B, Bidan G J. Electroanal. Chem., 1997, 425:49-54

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  • 收稿日期:  2012-07-16
  • 网络出版日期:  2013-06-06
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