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基于4-(4-咪唑基-亚甲基氨基)苯甲酸配体配合物的合成及结构

徐静 ,  陈敏东

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引用本文: 徐静, 陈敏东. 基于4-(4-咪唑基-亚甲基氨基)苯甲酸配体配合物的合成及结构[J]. 无机化学学报, 2013, 29(12): 2666-2672. doi: 10.3969/j.issn.1001-4861.2013.00.398 shu
Citation:  XU Jing, CHEN Min-Dong. Syntheses and Crystal Structures of Complexes Based on 4-[(1H-imidazol-4-yl)methylamino]benzoic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2666-2672. doi: 10.3969/j.issn.1001-4861.2013.00.398 shu

基于4-(4-咪唑基-亚甲基氨基)苯甲酸配体配合物的合成及结构

  • 基金项目:

    国家自然科学基金(No.21272118)资助项目。 (No.21272118)

摘要: 利用不同的方法由配体4-(4-咪唑基-亚甲基氨基)苯甲酸(H2L)和过渡金属盐反应合成了3个配合物[M(HL)2(H2O)2](M(Ⅱ)=Mn(Ⅱ)(1)，Cd(Ⅱ)(2)，Cu(Ⅱ)(3))，进行了X-射线单晶衍射等表征。晶体结构解析结果表明：配合物1~3都属于三斜晶系，P1空间群，分子之间通过丰富的氢键相互作用最终形成了三维超分子结构。并且研究了配合物的热稳定性和电化学性质。

English

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  • 收稿日期:  2013-07-19
  • 网络出版日期:  2013-08-27
通讯作者: 陈斌, bchen63@163.com
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