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3，5-二硝基苯甲酸镉配合物的合成、晶体结构、热稳定性和荧光性质

聂雪 ,  陈满生 ,  庾江喜

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引用本文: 聂雪, 陈满生, 庾江喜. 3，5-二硝基苯甲酸镉配合物的合成、晶体结构、热稳定性和荧光性质[J]. 无机化学学报, 2013, 29(12): 2704-2708. doi: 10.3969/j.issn.1001-4861.2013.00.395 shu
Citation:  NIE Xue, CHEN Man-Sheng, YU Jiang-Xi. Synthesis, Crystal Structure, Thermal Stability and Luminescent Properties of Cd(Ⅱ) Complex Constructed from 3,5-Dinitrobenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2704-2708. doi: 10.3969/j.issn.1001-4861.2013.00.395 shu

3，5-二硝基苯甲酸镉配合物的合成、晶体结构、热稳定性和荧光性质

  • 基金项目:

    湖南省自然科学基金(No.13JJ6069) (No.13JJ6069)

    湖南省教育厅一般项目(No.13C082)资助项目。 (No.13C082)

摘要: 以3，5-二硝基苯甲酸，咪唑为配体，合成了新化合物[Cd(H2O)2(DNBA)(Im)2](DNBA)·H2O，(DNBA=3，5-二硝基苯甲酸阴离子)。该配合物属正交晶系，空间群为Ccc2，晶胞参数：a=1.324 99(4) nm，b=1.516 01(5) nm，c=2.789 22(8) nm；V=5.602 7(3) nm3，Dc=1.719 g·cm-3，Z=8，μ=0.866 mm-1，F(000)=2 912，最终偏离因子R1=0.058 3，wR2=0.146 4。该配合物中包含两个单核镉(Ⅱ)配合物，且配合物中还包含未配位的3，5-二硝基苯甲酸，金属中心均是六配位变形八面体结构。并测定和研究了标题化合物的热重和荧光性能。

English

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  • 收稿日期:  2013-03-27
  • 网络出版日期:  2013-05-26
通讯作者: 陈斌, bchen63@163.com
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