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苯基多羧酸及含氮配体构筑的三维框架结构锌配位聚合物的合成、晶体结构和荧光性质

汪鹏飞 ,  方勤 ,  吴国志 ,  汪新

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引用本文: 汪鹏飞, 方勤, 吴国志, 汪新. 苯基多羧酸及含氮配体构筑的三维框架结构锌配位聚合物的合成、晶体结构和荧光性质[J]. 无机化学学报, 2013, 29(12): 2521-2527. doi: 10.3969/j.issn.1001-4861.2013.00.387 shu
Citation:  WANG Peng-Fei, FANG Qin, WU Guo-Zhi, WANG Xin. Synthesis, Crystal Structure and Luminescent Property of a Three-Dimensional Framework Zinc Coordination Polymer Constructed from the Benzenemulticarboxylic Acid and N-donor Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2521-2527. doi: 10.3969/j.issn.1001-4861.2013.00.387 shu

苯基多羧酸及含氮配体构筑的三维框架结构锌配位聚合物的合成、晶体结构和荧光性质

  • 基金项目:

    国家自然科学基金(No.21101019) (No.21101019)

    池州学院材料学重点学科(No.2011XK04)资助项目。 (No.2011XK04)

摘要: 以醋酸锌、5-溴-1，2，4-苯基三羧酸(BTCAH3)和4，4’-联吡啶(4，4’-bipy)为原料，在水热条件下合成了1个三维框架结构化合物[Zn3(BTCA)2(4，4’-bipy)2](1)，利用红外光谱、元素分析、热重、X-粉末衍射以及X-单晶衍射对该化合物进行了表征。化合物1是单斜晶系，C2/c空间群。在化合物1中，锌离子通过BTCA3-配体的羧酸氧原子形成一个具有3-节点、4-连接的三维框架结构。4，4’-联吡啶配体在框架结构中连接锌离子。另外，研究了该化合物的热稳定性和固体荧光性质。

English

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  • 收稿日期:  2013-04-07
  • 网络出版日期:  2013-05-31
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