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两种含有十二元环的层状稀土硫酸盐的合成、结构表征及性质研究

吕赟 ,  张登 ,  范新蓉 ,  万洪祥 ,  许岩

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引用本文: 吕赟, 张登, 范新蓉, 万洪祥, 许岩. 两种含有十二元环的层状稀土硫酸盐的合成、结构表征及性质研究[J]. 无机化学学报, 2013, 29(12): 2623-2630. doi: 10.3969/j.issn.1001-4861.2013.00.381 shu
Citation:  LU Yun, ZHANG Deng, FAN Xin-Rong, WAN Hong-Xiang, XU Yan. Synthesis，Structural Characterization and Properties of Two New Layered Lanthanide Sulfates Containing 12-Membered-Rings[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2623-2630. doi: 10.3969/j.issn.1001-4861.2013.00.381 shu

两种含有十二元环的层状稀土硫酸盐的合成、结构表征及性质研究

  • 基金项目:

    教育部博士点新教师基金(No.20113221120002) (No.20113221120002)

    江苏省科技厅自然科学基金(No.BK2012823)资助项目。 (No.BK2012823)

摘要: 通过溶剂热合成技术，我们得到了两种新的二维层状稀土硫酸盐：[Tb2(SO4)5][(CH3)2NH2]4(1)和[Y2(SO4)5][(CH3)2NH2]4(2)，并通过X-射线衍射、元素分析及红外、热重对化合物进行了表征。两种化合物都属于三斜晶系，P1空间群。其中化合物1：a=0.988 7(3) nm，b=1.106 1(3) nm，c=1.535 4(4) nm，α=70.45(4)°，β=75.12(3)°，γ=67.11(3)°，Z=2；化合物2：a=0.981 6(5) nm，b=1.100 1(5) nm，c=1.528 6(8) nm，α=70.44(6)°，β=75.45(6)°，γ=67.48(6)°，Z=2。通过对晶体结构进行表征我们发现两种化合物都含有二维层状无机骨架结构，该层由2种不同类型的双链和十二元环构成。我们还对化合物1的荧光性质进行了研究，其在369 nm的激发波长下表现出了Tb3+的特征发射。

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  • 收稿日期:  2012-12-06
  • 网络出版日期:  2013-05-04
通讯作者: 陈斌, bchen63@163.com
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