一维化合物(C2H8N)[Hg2Cl5]的晶体结构与介电性质的研究

周本华 蔡进 吉民

引用本文: 周本华, 蔡进, 吉民. 一维化合物(C2H8N)[Hg2Cl5]的晶体结构与介电性质的研究[J]. 无机化学学报, 2013, 29(12): 2709-2713. doi: 10.3969/j.issn.1001-4861.2013.00.372 shu
Citation:  ZHOU Ben-Hua, CAI Jin, JI Min. Crystal Structure and Dielectric Property of a One-Dimentional Compound (C2H8N)[Hg2Cl5][J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2709-2713. doi: 10.3969/j.issn.1001-4861.2013.00.372 shu

一维化合物(C2H8N)[Hg2Cl5]的晶体结构与介电性质的研究

  • 基金项目:

    国家重点基础研究发展计划(No.2011CB933500,No.2011CB933503) (No.2011CB933500,No.2011CB933503)

    江苏省科技支撑计划(No.BE2009639,BE2012657)资助项目。 (No.BE2009639,BE2012657)

摘要: 二甲基胺盐酸盐与氯化汞在水溶液中的反应,生产了一种有机无机杂化化合物(C2H8N)[Hg2Cl5](1)。单晶衍射分析证明化合物1的阴离子为沿b轴方向由氯桥构成的一维阴离子链,每1个汞都与4个氯离子配位。在处于80~298 K温度区间中,化合物1的介电没有出现介电异常的现象,这表明没有相变的发生。

English

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  • 收稿日期:  2013-04-02
  • 网络出版日期:  2013-07-04
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