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以PW9为结构基元构筑的夹心型多金属氧酸盐化合物的合成与晶体结构

冯秀玲

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引用本文: 冯秀玲. 以PW9为结构基元构筑的夹心型多金属氧酸盐化合物的合成与晶体结构[J]. 无机化学学报, 2013, 29(12): 2603-2608. doi: 10.3969/j.issn.1001-4861.2013.00.366 shu
Citation:  FENG Xiu-Ling. Synthesis and Crystal Structure of a Sandwich-Type Polyoxometalate Built up of the PW9 Unit[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2603-2608. doi: 10.3969/j.issn.1001-4861.2013.00.366 shu

以PW9为结构基元构筑的夹心型多金属氧酸盐化合物的合成与晶体结构

  • 基金项目:

    湖南省教育厅(No.12C0839)资助项目。 (No.12C0839)

摘要: 通过水热合成方法合成了以夹心多酸阴离子{Ni4(H2O)2(PW9O34)2}10-，乙二胺(en)和Ni(Ⅱ)构筑的夹心型多金属氧酸盐化合物[Ni(en)2]2[{Ni(en)2}{Ni(en)2H2O}2{(PW9O34)2Ni4(H2O)2}]·16H2O(1)，采用IR、单晶X-射线衍射法、TG/DTG及循环伏安法对标题化合物进行结构和性质研究。该化合物的夹心多酸阴离子通过[Ni(en)2]2+连接形成一维链，并进一步通过氢键作用形成3D超分子结构。

English

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  • 收稿日期:  2013-02-26
  • 网络出版日期:  2013-06-13
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