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氧桥桥连四核M4[2×2]格子状结构锌(Ⅱ)配合物的自组装、晶体结构及荧光性质

王娟娟 ,  张丽 ,  许贯诚 ,  贾殿赠

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引用本文: 王娟娟, 张丽, 许贯诚, 贾殿赠. 氧桥桥连四核M4[2×2]格子状结构锌(Ⅱ)配合物的自组装、晶体结构及荧光性质[J]. 无机化学学报, 2013, 29(12): 2609-2614. doi: 10.3969/j.issn.1001-4861.2013.00.360 shu
Citation:  WANG Juan-Juan, ZHANG Li, XU Guan-Cheng, JIA Dian-Zeng. Oxygen-Bridged Tetranuclear Zn(Ⅱ) Complex of M4[2×2] Square Grid：Self-Assembly, Crystal Structure and Fluorescent Property[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2609-2614. doi: 10.3969/j.issn.1001-4861.2013.00.360 shu

氧桥桥连四核M4[2×2]格子状结构锌(Ⅱ)配合物的自组装、晶体结构及荧光性质

  • 基金项目:

    新疆自治区自然科学基金面上项目(No.2012211A009)资助项目。 (No.2012211A009)

摘要: 以席夫碱碳腙类配体H2L自组装合成了一个新的M4[2×2]四方格子状结构锌(Ⅱ)配合物[Zn4(HL)4](ClO4)4·2MeCN·2MeOH(H2L=1，5-bis(1-(pyridine-2-yl)ethylidene)carbonhydrazide)，并对其进行了元素分析、红外光谱、紫外可见光谱和X-射线单晶衍射法表征。单晶结构分析结果表明配合物中，Zn(Ⅱ)离子具有N4O2型扭曲的八面体配位构型，4个配体分别失去1个质子后以醇式与金属离子配位，由4个酚氧原子桥连4个Zn(Ⅱ)离子形成[2×2]格子状结构四核配合物。固态荧光测试表明配合物在530 nm附近有强的荧光发射峰。

English

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  • 收稿日期:  2013-02-16
  • 网络出版日期:  2013-06-07
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