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锌(Ⅱ)配合物Zn(2-PMBBA)2(Phen)的合成、电化学、磁性及荧光性能研究

唐斯萍 ,  许志锋 ,  冯泳兰 ,  王海洋

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引用本文: 唐斯萍, 许志锋, 冯泳兰, 王海洋. 锌(Ⅱ)配合物Zn(2-PMBBA)2(Phen)的合成、电化学、磁性及荧光性能研究[J]. 无机化学学报, 2013, 29(12): 2683-2687. doi: 10.3969/j.issn.1001-4861.2013.00.358 shu
Citation:  TANG Si-Ping, XU Zhi-Feng, FENG Yong-Lan, WANG Hai-Yang. Synthesis, Electrochemical, Magnetic and Fluorescent Properties of a Zinc(Ⅱ) Complex Zn(2-PMBBA)2(Phen)[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(12): 2683-2687. doi: 10.3969/j.issn.1001-4861.2013.00.358 shu

锌(Ⅱ)配合物Zn(2-PMBBA)2(Phen)的合成、电化学、磁性及荧光性能研究

  • 基金项目:

    国家自然科学基金(No.21102040)，湖南省自然科学基金(No.12JJ6013，11JJ9005)，湖南省科学技术厅科技计划项目(No.2012FJ3020)，湖南省高校青年骨干教师资助项目，湖南省教育厅创新平台开放基金(No.12K125)，湖南省重点学科基金资助项目。 (No.21102040)，湖南省自然科学基金(No.12JJ6013，11JJ9005)，湖南省科学技术厅科技计划项目(No.2012FJ3020)，湖南省高校青年骨干教师资助项目，湖南省教育厅创新平台开放基金(No.12K125)

摘要: 以2-(对甲基苯甲酰基)苯甲酸(2-PMBBA)和1，10-邻菲啰啉(Phen)为配体合成了一个新的锌(Ⅱ)配合物Zn(2-PMBBA)2(Phen)。该配合物晶体属正交晶系，空间群Pccn，晶胞参数：a=1.371 6(4) nm，b=1.336 8(4) nm，c=1.928 7(5) nm，V=3.536 4(17) nm3，Dc=1.360 g·cm-3，Z=4，μ(Mo Kα)=0.746 mm-1，F(000)=1 496，最终偏离因子R1=0.035 8，wR2=0.086 1。在标题配合物中，中心锌(Ⅱ)离子的配位数是4，处于变形的四面体配位环境中，这是不多见的。本工作还测定了标题配合物的电化学、磁性及荧光性能。结果表明：循环伏安过程中，配合物的电子转移是不可逆的，对应的电极反应是Zn(Ⅱ)/Zn(0)；在300~7 K，配合物有抗磁性；当激发波长为224 nm时，配合物在450和472 nm处有强的荧光发射峰。

English

  • 

    1. [1] Gushwa A F, Belabassi Y, Montchamp J L, et al. J. Chem. Cryst., 2009, 39:337-347[1] Gushwa A F, Belabassi Y, Montchamp J L, et al. J. Chem. Cryst., 2009, 39:337-347

    2. [2] Assey G E, Yisgedu T, Gultneh Y, et al. Acta Crystallog., Sect. E, 2009, 65:1007-1008[2] Assey G E, Yisgedu T, Gultneh Y, et al. Acta Crystallog., Sect. E, 2009, 65:1007-1008

    3. [3] ZHANG Yan-Ping (张艳萍), WANG Li-Li (王莉丽), LIU Lian-Li (刘连利), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2013, 29 (2):350-354[3] ZHANG Yan-Ping (张艳萍), WANG Li-Li (王莉丽), LIU Lian-Li (刘连利), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2013, 29 (2):350-354

    4. [4] KANG Wei (康伟), DENG Zhao-Peng (邓兆鹏), GAO Shan (高 山). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (4):655-658[4] KANG Wei (康伟), DENG Zhao-Peng (邓兆鹏), GAO Shan (高 山). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27 (4):655-658

    5. [5] Zhao Y J, Liu R W, Li X H. Acta Crystallogr., Sect. E, 2005, 61:535-537[5] Zhao Y J, Liu R W, Li X H. Acta Crystallogr., Sect. E, 2005, 61:535-537

    6. [6] Yang P, Wu J Z, Yu Y. Inorg. Chim. Acta, 2009, 362:1907-1912[6] Yang P, Wu J Z, Yu Y. Inorg. Chim. Acta, 2009, 362:1907-1912

    7. [7] Chandrasekhar V, Thilagar P, Steiner A, et al. Chem.-Eur. J., 2006, 12:8847-8861[7] Chandrasekhar V, Thilagar P, Steiner A, et al. Chem.-Eur. J., 2006, 12:8847-8861

    8. [8] Srinivasan B R, Sawant J V, Nather C, et al. J. Chem. Sci. (Bangalore, India), 2007, 119:243-252[8] Srinivasan B R, Sawant J V, Nather C, et al. J. Chem. Sci. (Bangalore, India), 2007, 119:243-252

    9. [9] GAO Hong-Ling (高洪苓), HU Cong-Cong (胡丛丛), ZHANG Hong (张虹), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (3):632-636[9] GAO Hong-Ling (高洪苓), HU Cong-Cong (胡丛丛), ZHANG Hong (张虹), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (3):632-636

    10. [10] WANG Peng (王鹏), LI Ying (李莹), YANG Wen-Bin (杨文 斌), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (11):2301-2305[10] WANG Peng (王鹏), LI Ying (李莹), YANG Wen-Bin (杨文 斌), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (11):2301-2305

    11. [11] Wang R H, Hong M C, Liang Y C, et al. Acta Crystallogr., Sect. E, 2001, 57:277-279[11] Wang R H, Hong M C, Liang Y C, et al. Acta Crystallogr., Sect. E, 2001, 57:277-279

    12. [12] Li X J, Cao R, Sun D F, et al. Cryst. Growth Des., 2004, 4: 775-780[12] Li X J, Cao R, Sun D F, et al. Cryst. Growth Des., 2004, 4: 775-780

    13. [13] Yang E, Song X C, Wang L H, et al. Acta Crystallogr., Sect. C, 2007, 63:481-483[13] Yang E, Song X C, Wang L H, et al. Acta Crystallogr., Sect. C, 2007, 63:481-483

    14. [14] WANG Qian-Qian (王倩倩), LIU Chun-Bo (刘春波), LI Xiu-Ying (李秀颖), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (3):619-625[14] WANG Qian-Qian (王倩倩), LIU Chun-Bo (刘春波), LI Xiu-Ying (李秀颖), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (3):619-625

    15. [15] TAO Zhao-Lin (陶兆林), CUI Jie-Hu (崔节虎), QIN Lin (覃 玲), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (12):2633-2637[15] TAO Zhao-Lin (陶兆林), CUI Jie-Hu (崔节虎), QIN Lin (覃 玲), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (12):2633-2637

    16. [16] Kang W L, Wu X Y, Huang J B. J. Organomet. Chem., 2009, 694:2402-2408[16] Kang W L, Wu X Y, Huang J B. J. Organomet. Chem., 2009, 694:2402-2408

    17. [17] LI Wei (李薇), LI Chang-Hong (李昶红), YANG Ying-Qun (杨 颖群), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (1):166-170[17] LI Wei (李薇), LI Chang-Hong (李昶红), YANG Ying-Qun (杨 颖群), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (1):166-170

    18. [18] Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Gottingen, Germany, 2002. 19] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Gottingen, Germany, 1997.[18] Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Gottingen, Germany, 2002. 19] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Gottingen, Germany, 1997.

    19. [20] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Gottingen, Germany, 1997.[20] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Gottingen, Germany, 1997.

    20. [21] GU Chang-Sheng (谷长生), GAO Shan (高山), ZHAO Jing-Gui (赵经贵), et al. Chinese J. Struct. Chem. (Jiegou Huaxue), 2004, 23 (9):1073-1076[21] GU Chang-Sheng (谷长生), GAO Shan (高山), ZHAO Jing-Gui (赵经贵), et al. Chinese J. Struct. Chem. (Jiegou Huaxue), 2004, 23 (9):1073-1076

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  • 收稿日期:  2013-03-05
  • 网络出版日期:  2013-06-11
通讯作者: 陈斌, bchen63@163.com
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