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含碳硼烷膦氧配体镍、铱化合物的合成与表征

蒋其柏 ,  季一飞 ,  沈旭杰 ,  燕红

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引用本文: 蒋其柏, 季一飞, 沈旭杰, 燕红. 含碳硼烷膦氧配体镍、铱化合物的合成与表征[J]. 无机化学学报, 2013, 29(5): 910-914. doi: 10.3969/j.issn.1001-4861.2013.00.168 shu
Citation:  JIANG Qi-Bai, JI Yi-Fei, SHEN Xu-Jie, YAN Hong. Synthesis and Characterization of Ni(Ⅱ) and Ir(Ⅰ) Complex with o-Carborane [O,P] or [O,O] Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(5): 910-914. doi: 10.3969/j.issn.1001-4861.2013.00.168 shu

含碳硼烷膦氧配体镍、铱化合物的合成与表征

    通讯作者: 燕红,E-mail:hyan1965@nju.edu.cn
  • 基金项目:

    国家自然科学基金(No.20925104,21271102,21021062)资助项目。 (No.20925104,21271102,21021062)

摘要: 碳硼烷双膦配体L1分别与三苯基膦氯化镍(NiCl2(PPh3)2)和1,5-环辛二烯氯化铱(IrCl(COD))在空气中反应生成含巢式碳硼烷膦氧配体的镍、铱化合物1和2。本文对此两个化合物进行了核磁、质谱、红外及单晶衍射等表征。化合物1中溶剂分子氯仿与主体结构存在着常见的Cl…H氢键作用和较少见的CH…π作用,化合物2是首例以膦氧配体形成的Ir(Ⅰ)配合物,同时由于金属的差别导致了碳硼烷双膦配体被氧化程度的不同形成了新颖的碳硼烷[P,O]和[O,O]配体。

English

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  • 收稿日期:  2013-01-04
  • 网络出版日期:  2013-03-12
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