叔丁基亚胺四氯合钽(Ⅴ)阴离子配合物[IPrH]+[tBuN=TaCl4(py)]-的合成与表征

引用本文: 张冬腾, 祝英英, 罗光明, 蔡琥. 叔丁基亚胺四氯合钽(Ⅴ)阴离子配合物[IPrH]⁺[^tBuN=TaCl₄(py)]^-的合成与表征[J]. 无机化学学报, 2013, 29(5): 953-957. doi: 10.3969/j.issn.1001-4861.2013.00.162 shu

Citation: ZHANG Dong-Teng, ZHU Ying-Ying, LUO Guang-Ming, CAI Hu. Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]⁺[^tBuN=TaCl₄(py)]^-[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(5): 953-957. doi: 10.3969/j.issn.1001-4861.2013.00.162 shu

叔丁基亚胺四氯合钽(Ⅴ)阴离子配合物[IPrH]⁺[^tBuN=TaCl₄(py)]^-的合成与表征

基金项目:
国家自然科学基金(No.20861007) (No.20861007)

江西省教育厅基金(No.GJJ08026)资助项目。 (No.GJJ08026)

摘要: [^tBuN=TaCl₃(py)₂]和氮杂环卡宾(IPr=1,3-bis(2,6-diisoproylphenyl)imidazol-2-ylidene)的反应得到预料之外的叔丁基亚胺四氯合钽(Ⅴ)阴离子配合物[IPrH]⁺[^tBuN=TaCl₄(py)]^- (1)。利用核磁共振波谱,红外吸收光谱,荧光光谱,元素分析和X-Ray单晶衍射对配合物1的结构进行了表征。X-射线单晶衍射分析表明,Ta(V)中心与4个氯和2个分别来自亚胺和吡啶配体的氮原子以八面体构型配位。

关键词:

亚胺;氮杂环卡宾;钽化合物;荧光

English

1. [1] Nugent W A, Mayer J M. Metal-Ligand Multiple Bonds. New York: Wiley, 1988.[1] Nugent W A, Mayer J M. Metal-Ligand Multiple Bonds. New York: Wiley, 1988.
2. [2] Wigley D E. Progress in Inorganic Chemistry: Vol.42. New York: Wiley, 1994:239-482[2] Wigley D E. Progress in Inorganic Chemistry: Vol.42. New York: Wiley, 1994:239-482
3. [3] Miguel G, Carlos G, Mannuel G, et al. Dalton Trans., 2011, 40:2797-2804[3] Miguel G, Carlos G, Mannuel G, et al. Dalton Trans., 2011, 40:2797-2804
4. [4] Ragone F, Poater A, Cavallo L, J. Am. Chem. Soc., 2010, 132:4249-4258[4] Ragone F, Poater A, Cavallo L, J. Am. Chem. Soc., 2010, 132:4249-4258
5. [5] Gonzalez D C, Savariar E N, Thayumanavan S. J. Am. Chem. Soc., 2009,131:7708-7716[5] Gonzalez D C, Savariar E N, Thayumanavan S. J. Am. Chem. Soc., 2009,131:7708-7716
6. [6] Marion N, Nolan S P. Acc. Chem. Res., 2008,41:1440-1449[6] Marion N, Nolan S P. Acc. Chem. Res., 2008,41:1440-1449
7. [7] Würtz S, Glorius F. Acc. Chem. Res., 2008,41:1523-1533[7] Würtz S, Glorius F. Acc. Chem. Res., 2008,41:1523-1533
8. [8] Xi Z, Liu B, Chen W. J. Org. Chem., 2008,73:3954-3957[8] Xi Z, Liu B, Chen W. J. Org. Chem., 2008,73:3954-3957
9. [9] Arrowsmith M, Hill M S, Kociok-Kohn G. Organometallics, 2009,28:1730-1738[9] Arrowsmith M, Hill M S, Kociok-Kohn G. Organometallics, 2009,28:1730-1738
10. [10] John A, Ghosh P. Dalton Trans., 2010,39:7183-7260[10] John A, Ghosh P. Dalton Trans., 2010,39:7183-7260
11. [11] WANG Zhi-Guo(王志国), BIAN Qing-Quan(边清泉), HUANG Bao-Mei(黄宝美), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:191-194[11] WANG Zhi-Guo(王志国), BIAN Qing-Quan(边清泉), HUANG Bao-Mei(黄宝美), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:191-194
12. [12] CHEN Chao(陈超), QIU Hua-Yu(邱化玉), LIU Ai-Ling(刘爱玲), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:1423-1430[12] CHEN Chao(陈超), QIU Hua-Yu(邱化玉), LIU Ai-Ling(刘爱玲), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:1423-1430
13. [13] Melaimi M, Soleilhavoup M, Bertrand G. Angew. Chem., Int. Ed., 2010,49:8810-8849[13] Melaimi M, Soleilhavoup M, Bertrand G. Angew. Chem., Int. Ed., 2010,49:8810-8849
14. [14] Markó I E, Stérin S, Buisine O, et al. Science, 2002,298: 204-206[14] Markó I E, Stérin S, Buisine O, et al. Science, 2002,298: 204-206
15. [15] Markó I E, Michaud G, Berthon-Gelloz G, et al. Adv. Synth. Catal., 2004,346:1429-1434[15] Markó I E, Michaud G, Berthon-Gelloz G, et al. Adv. Synth. Catal., 2004,346:1429-1434
16. [16] Mas-Marza E, Sanau M, Peris E. Inorg. Chem., 2005,44: 9961-9967[16] Mas-Marza E, Sanau M, Peris E. Inorg. Chem., 2005,44: 9961-9967
17. [17] Dragutan V, Dragutan I, Delaude L, et al. Coord. Chem. Rev., 2007,251:765-794[17] Dragutan V, Dragutan I, Delaude L, et al. Coord. Chem. Rev., 2007,251:765-794
18. [18] Kandepi V V K M, Cardoso J M S, Peris E, et al. Organo- metallics, 2010,29:2777-2782[18] Kandepi V V K M, Cardoso J M S, Peris E, et al. Organo- metallics, 2010,29:2777-2782
19. [19] Jain K R, Herrmann W A, Kühn F E. Curr. Org. Chem., 2008,12:1468-1478[19] Jain K R, Herrmann W A, Kühn F E. Curr. Org. Chem., 2008,12:1468-1478
20. [20] Herrmann W Α, Öfele K, Elison M, et al. J. Organomet. Chem., 1994,480:C7-C9[20] Herrmann W Α, Öfele K, Elison M, et al. J. Organomet. Chem., 1994,480:C7-C9
21. [21] Kuhn N, Kratz T, Bläser D, et al. Inorg. Chim. Acta, 1995, 238:179-181[21] Kuhn N, Kratz T, Bläser D, et al. Inorg. Chim. Acta, 1995, 238:179-181
22. [22] Abernethy C D, Codd G M, Spicer M D, et al. J. Am. Chem. Soc., 2003,125:1128-1129[22] Abernethy C D, Codd G M, Spicer M D, et al. J. Am. Chem. Soc., 2003,125:1128-1129
23. [23] Shukla P, Johnson J Α, Vidovic D, et al. Chem. Commun., 2004:360-361[23] Shukla P, Johnson J Α, Vidovic D, et al. Chem. Commun., 2004:360-361
24. [24] Lorber C, Vendier L. Dalton Trans., 2009,35:6972-6984[24] Lorber C, Vendier L. Dalton Trans., 2009,35:6972-6984
25. [25] Romain C, Miqueu K, Sotiropoulos J M, et al. Angew. Chem. Inter. Ed., 2010,49:2198-2201[25] Romain C, Miqueu K, Sotiropoulos J M, et al. Angew. Chem. Inter. Ed., 2010,49:2198-2201
26. [26] Spencer L P, Beddle C, Hall M B, et al. J. Am. Chem. Soc., 2006,128:12531-12543[26] Spencer L P, Beddle C, Hall M B, et al. J. Am. Chem. Soc., 2006,128:12531-12543
27. [27] Willams D S, Korolev A V. Inorg. Chem., 1998,37:3809- 3819[27] Willams D S, Korolev A V. Inorg. Chem., 1998,37:3809- 3819
28. [28] Hintermann L, Beilstein J. Organomet. Chem., 2007,3:1-5[28] Hintermann L, Beilstein J. Organomet. Chem., 2007,3:1-5
29. [29] Jafarpour L, Stevens E D, Nolan S P. J. Organomet. Chem., 2000,606:49-54[29] Jafarpour L, Stevens E D, Nolan S P. J. Organomet. Chem., 2000,606:49-54
30. [30] Chiu H T, Chuang S H, Tsai C E, et al. Polyhedron, 1998, 17:2187-2190[30] Chiu H T, Chuang S H, Tsai C E, et al. Polyhedron, 1998, 17:2187-2190

扫一扫看文章

计量

PDF下载量: 310
文章访问数: 1142
HTML全文浏览量: 84

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

叔丁基亚胺四氯合钽(Ⅴ)阴离子配合物[IPrH]⁺[^tBuN=TaCl₄(py)]^-的合成与表征

English

Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]⁺[^tBuN=TaCl₄(py)]^-

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处