纳米氧化镍浓度对磁性准固态染料敏化太阳能电池的影响

引用本文: 杨英, 崔嘉瑞, 易鹏飞, 肖思, 郭学益. 纳米氧化镍浓度对磁性准固态染料敏化太阳能电池的影响[J]. 无机化学学报, 2013, 29(5): 1007-1012. doi: 10.3969/j.issn.1001-4861.2013.00.076 shu

Citation: YANG Ying, CUI Jia-Rui, YI Peng-Fei, XIAO Si, GUO Xue-Yi. Effect of NiO Nanoparticles on Magnetic Quasi-Solid Dye-Sensitized Solar Cells[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(5): 1007-1012. doi: 10.3969/j.issn.1001-4861.2013.00.076 shu

纳米氧化镍浓度对磁性准固态染料敏化太阳能电池的影响

杨英 ^1, ,
崔嘉瑞 ^1, ,
易鹏飞 ^1, ,
肖思 ^2, ,
郭学益 ^{1,
,}

通讯作者: 郭学益,E-mail:xyguo@mail.csu.edu.cn,Tel:+86-731-8887863

基金项目:
国家自然科学基金(No.61006047

No.11104356)资助项目。

摘要: 以琼脂糖为聚合物基质,N-甲基-2-吡咯烷酮(NMP)为溶剂,磁性纳米氧化镍颗粒作为添加剂用于制备染料敏化太阳能电池(DSSC)的磁性聚合物电解质。通过SEM与离子电导率测试研究不同纳米氧化镍掺杂浓度对磁性聚合物电解质的影响,并对相应的染料敏化太阳能电池进行光电性能测试与电化学交流组抗谱(EIS)测试,结果表明:1.0wt%的纳米氧化镍掺杂浓度为最优掺杂浓度,在此浓度下聚合物电解质的表面形貌较为平整,同时电解质具备最高离子电导率(2.43×10^-3 S·cm^-1);染料敏化太阳能电池的光电效率与电子寿命均随着纳米氧化镍掺杂浓度的增加而先增加后降低,并都在纳米氧化镍掺杂浓度为1.0wt%达到最大,此时电池的光电效率为1.63%、开路电压为0.57 V、短路电流密度为5.8 mA·cm^-2、填充因子为0.53。

关键词:

磁性聚合物电解质;染料敏化太阳能电池;纳米氧化镍;离子电导率;光电效率

English

Effect of NiO Nanoparticles on Magnetic Quasi-Solid Dye-Sensitized Solar Cells

1.
1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;

Corresponding author: 郭学益,E-mail:xyguo@mail.csu.edu.cn,Tel:+86-731-8887863

Received Date: 14 September 2012
Fund Project:
国家自然科学基金(No.61006047

No.11104356)资助项目。

Abstract: A magnetic polymer electrolyte using agarose as polymer matrix, NMP as solvent and NiO nanoparticles as modifier was investigated and employed in the dye-sensitized solar cell (DSSC) in this paper. The influence of NiO nanoparticles content on magnetic polymer electrolyte was characterized by SEM and ionic conductivity test. The photovoltaic properties of the corresponding DSSCs with different concentrations of NiO nanoparticles were studied by photovoltaic performance tests and electrochemical impedance spectra (EIS). The results showed that the optimal concentration of NiO nanoparticles was 1.0wt%, in which concentration the surface morphology of the polymer electrolyte was smooth and this magnetic polymer electrolyte showed the maximum conductivity (2.43×10^-3 S·cm^-1). The photoelectric efficiency and electron lifetime of DSSCs increased initially and then decreased with the increasing of the NiO nanoparticles content, the optimal photoelectric efficiency as well as the longest electron lifetime were achieved at the NiO nanoparticles content of 1.0wt%. At this optimal content, the photoelectric efficiency of DSSC was 1.63%, the voltage, current density and the filling factor of the DSSC was 0.57 V, 5.8 mA·cm^-2 and 0.53, respectively.

Key words:

magnetic polymer electrolyte;dye-sensitized solar cell;NiO nanoparticles;ionic conductivity;electrochemical impedance

1. [1] ORegan B, Grtzel M. Nature 1991,353:737-740[1] ORegan B, Grtzel M. Nature 1991,353:737-740
2. [2] Nazeeruddin M K, Kay A, Rodicio I, et al. Chem. Soc., 1993,115(14):6382-6390[2] Nazeeruddin M K, Kay A, Rodicio I, et al. Chem. Soc., 1993,115(14):6382-6390
3. [3] YANG Shu-Ming(杨术明). Dye-sensitized Nanocrystalline Solar Cells(染料敏化纳米晶太阳能电池). Zhengzhou: Zhengzhou University Press, 2007.[3] YANG Shu-Ming(杨术明). Dye-sensitized Nanocrystalline Solar Cells(染料敏化纳米晶太阳能电池). Zhengzhou: Zhengzhou University Press, 2007.
4. [4] Yella A, Lee H W, Tsao H N, et al. Science, 2011,334 (6056):629-634[4] Yella A, Lee H W, Tsao H N, et al. Science, 2011,334 (6056):629-634
5. [5] WANG Wei-Jia(王惟嘉), YANG Ying(杨英), GUO Xue-Yi (郭学益), et al. Chemistry (Huaxue Tongbao), 2011,74(2): 144-149[5] WANG Wei-Jia(王惟嘉), YANG Ying(杨英), GUO Xue-Yi (郭学益), et al. Chemistry (Huaxue Tongbao), 2011,74(2): 144-149
6. [6] Kumara R A G, Kancko S, Okuya M, et al. Langmuir, 2002,18(26):10493-10495[6] Kumara R A G, Kancko S, Okuya M, et al. Langmuir, 2002,18(26):10493-10495
7. [7] Meng Q B, Takahashi K, Zhang X T, et al. Langmuir, 2003, 19(9):3572-3574[7] Meng Q B, Takahashi K, Zhang X T, et al. Langmuir, 2003, 19(9):3572-3574
8. [8] Bach U, Lupo D, Comte P, et al. Nature, 1998,395:583-585[8] Bach U, Lupo D, Comte P, et al. Nature, 1998,395:583-585
9. [9] Nogueria A F, Durrant J R, Depaoli M A, et al. Adv. Mater., 2001,13(11):826-830[9] Nogueria A F, Durrant J R, Depaoli M A, et al. Adv. Mater., 2001,13(11):826-830
10. [10] Wang P, Zakeeruddin S M, Grtzel M. J. Fluorine Chem., 2004,125(8):1241-1245[10] Wang P, Zakeeruddin S M, Grtzel M. J. Fluorine Chem., 2004,125(8):1241-1245
11. [11] Wang H X, Li H, Xue B F, et al. J. Am. Chem. Soc., 2005, 127(17):6394-6401[11] Wang H X, Li H, Xue B F, et al. J. Am. Chem. Soc., 2005, 127(17):6394-6401
12. [12] Xue B F, Wang H X, Hu Y S, et al. Photochem. Photobiol. Sci., 2004,3(10):918-919[12] Xue B F, Wang H X, Hu Y S, et al. Photochem. Photobiol. Sci., 2004,3(10):918-919
13. [13] Yang M R, Teng T H, Wu S H. J. Power Sources, 2006,159 (1):307-311[13] Yang M R, Teng T H, Wu S H. J. Power Sources, 2006,159 (1):307-311
14. [14] Yang Y , Zhou C H , Xu S, et al. Nanotechnology, 2009,20 (10):105204(9pp)[14] Yang Y , Zhou C H , Xu S, et al. Nanotechnology, 2009,20 (10):105204(9pp)
15. [15] SHI Yan-Tao(史彦涛), SUN Xiao-Dan(孙晓丹), WENG Duan(翁端), et al. World SCI-Tech R&D(Shijie Keji Yanjiu Yu Fazhan), 2006,28(3):45-50[15] SHI Yan-Tao(史彦涛), SUN Xiao-Dan(孙晓丹), WENG Duan(翁端), et al. World SCI-Tech R&D(Shijie Keji Yanjiu Yu Fazhan), 2006,28(3):45-50
16. [16] QIU Wei-Li(邱玮丽), YANG Qing-He(杨清河), MA Xiao- Hua(马晓华), et al. Chin. J. Power Sources(Dianyuan Jishu), 2004,28(7):440-448[16] QIU Wei-Li(邱玮丽), YANG Qing-He(杨清河), MA Xiao- Hua(马晓华), et al. Chin. J. Power Sources(Dianyuan Jishu), 2004,28(7):440-448
17. [17] DU Hong-Yan(杜洪彦), CHENG Hu(程琥), YANG Yong (杨勇). Electrochemistry (Dianhuaxue), 2004,10(2):215-221[17] DU Hong-Yan(杜洪彦), CHENG Hu(程琥), YANG Yong (杨勇). Electrochemistry (Dianhuaxue), 2004,10(2):215-221
18. [18] Han H W, Liu W, Zhang J, et al. Adv. Funct. Mater., 2005, 15(12):1940-1944[18] Han H W, Liu W, Zhang J, et al. Adv. Funct. Mater., 2005, 15(12):1940-1944
19. [19] Khan S A, Baker G L, Colson S. Chem. Mater., 1994,6(12): 2359-2363[19] Khan S A, Baker G L, Colson S. Chem. Mater., 1994,6(12): 2359-2363
20. [20] Croce F, Appetecchi G B, Persi L, et al. Nature, 1998,394 (28818):456-458[20] Croce F, Appetecchi G B, Persi L, et al. Nature, 1998,394 (28818):456-458
21. [21] Wang Y P, Zhu J W, Yang X J, et al. Thermochmica Acta, 2005,437(1):106-109[21] Wang Y P, Zhu J W, Yang X J, et al. Thermochmica Acta, 2005,437(1):106-109
22. [22] Golodnitsky D, Livshits E, Kovarsky R, et al. Electrochem. Solid-State Lett., 2004,7(11):412-415[22] Golodnitsky D, Livshits E, Kovarsky R, et al. Electrochem. Solid-State Lett., 2004,7(11):412-415
23. [23] Livshits E, Kovarsky R, Lavie N, et al. Electrochim. Acta, 2005,50(19):3805-3814[23] Livshits E, Kovarsky R, Lavie N, et al. Electrochim. Acta, 2005,50(19):3805-3814
24. [24] Ash B J, Schadler L S, Siegel R W. Mater. Lett., 2002,55 (1):83-87[24] Ash B J, Schadler L S, Siegel R W. Mater. Lett., 2002,55 (1):83-87
25. [25] Choi B K, Kim Y W, Shin K H. J. Power Sources, 1997,68 (2):357-360[25] Choi B K, Kim Y W, Shin K H. J. Power Sources, 1997,68 (2):357-360
26. [26] Fuke N, Fukui A, Komiya R, et al. Chem. Mater., 2008,20 (15):4974-4979[26] Fuke N, Fukui A, Komiya R, et al. Chem. Mater., 2008,20 (15):4974-4979
27. [27] Wang M, Lin Y, Zhou X W, et al. Mater. Chem. Phys., 2008,107(1):61-66[27] Wang M, Lin Y, Zhou X W, et al. Mater. Chem. Phys., 2008,107(1):61-66
28. [28] Wang W J, Guo X Y, Yang Y. Electrochim. Acta, 2011,56 (21):7347-7351[28] Wang W J, Guo X Y, Yang Y. Electrochim. Acta, 2011,56 (21):7347-7351
29. [29] Kern R, Sastrawan R, Ferber J, et al. Electrochim. Acta, 2002,47(26):4213-4225[29] Kern R, Sastrawan R, Ferber J, et al. Electrochim. Acta, 2002,47(26):4213-4225
30. [30] LIANG Lin-Yun(梁林云), DAI Song-Yuan(戴松元), HU Lin-Hua(胡林华), et al. Acta Phys. Sin.(Wuli Xuebao), 2009,58(2):1338-1343[30] LIANG Lin-Yun(梁林云), DAI Song-Yuan(戴松元), HU Lin-Hua(胡林华), et al. Acta Phys. Sin.(Wuli Xuebao), 2009,58(2):1338-1343
31. [31] Nakade S, Saito Y, Kubo W, et al. J. Phys. Chem. B, 2003, 107(33):8607-8611[31] Nakade S, Saito Y, Kubo W, et al. J. Phys. Chem. B, 2003, 107(33):8607-8611
32. [32] FU Ping-Feng(傅平丰), ZHANG Peng-Yi(张彭义). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(11):2026-2030[32] FU Ping-Feng(傅平丰), ZHANG Peng-Yi(张彭义). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(11):2026-2030
33. [33] WANG Zhong-Chang(王中长), LIU Tian-Mou(刘天模), LI Jia-Ming(李家鸣). J. Chongqing Univ. (Chongqing Daxue Xuebao), 2003,26(11):52-55[33] WANG Zhong-Chang(王中长), LIU Tian-Mou(刘天模), LI Jia-Ming(李家鸣). J. Chongqing Univ. (Chongqing Daxue Xuebao), 2003,26(11):52-55
34. [34] He J J, Benk G, Korodi F, et al. J. Am. Chem. Soc., 2002, 124(17):4922-4932[34] He J J, Benk G, Korodi F, et al. J. Am. Chem. Soc., 2002, 124(17):4922-4932
35. [35] Zhang Z P, Zakeeruddin S M, O'Regan B, et al. J. Phys. Chem. B 2005,109(46):21818-21824[35] Zhang Z P, Zakeeruddin S M, O'Regan B, et al. J. Phys. Chem. B 2005,109(46):21818-21824

扫一扫看文章

计量

PDF下载量: 559
文章访问数: 1401
HTML全文浏览量: 69

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

纳米氧化镍浓度对磁性准固态染料敏化太阳能电池的影响

通讯作者: 郭学益,E-mail:xyguo@mail.csu.edu.cn,Tel:+86-731-8887863

English

Effect of NiO Nanoparticles on Magnetic Quasi-Solid Dye-Sensitized Solar Cells

Corresponding author: 郭学益,E-mail:xyguo@mail.csu.edu.cn,Tel:+86-731-8887863

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

纳米氧化镍浓度对磁性准固态染料敏化太阳能电池的影响

通讯作者: 郭学益,E-mail:xyguo@mail.csu.edu.cn,Tel:+86-731-8887863

English

Effect of NiO Nanoparticles on Magnetic Quasi-Solid Dye-Sensitized Solar Cells

Corresponding author: 郭学益,E-mail:xyguo@mail.csu.edu.cn,Tel:+86-731-8887863

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs