溶胶-喷雾干燥法制备纳米Li3V2(PO4)3/C及其电化学性能

引用本文: 唐艳, 方为茂, 钟本和, 刘恒, 郭孝东. 溶胶-喷雾干燥法制备纳米Li₃V₂(PO₄)₃/C及其电化学性能[J]. 无机化学学报, 2013, 29(5): 915-921. doi: 10.3969/j.issn.1001-4861.2013.00.070 shu

Citation: TANG Yan, FANG Wei-Mao, ZHONG Ben-He, LIU Heng, GUO Xiao-Dong. Synthesis and Electrochemical Performance of Nano-Structure Li₃V₂(PO₄)₃/C by Sol-Spray Drying Method[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(5): 915-921. doi: 10.3969/j.issn.1001-4861.2013.00.070 shu

溶胶-喷雾干燥法制备纳米Li₃V₂(PO₄)₃/C及其电化学性能

唐艳 ^1, ,
方为茂 ^1, ,
钟本和 ^1, ,
刘恒 ^2, ,
郭孝东 ^{1,
,}

通讯作者: 郭孝东,E-mail:xiaodong2009@163.com

基金项目:
国家科技支撑计划(No.2007BAQ01055) (No.2007BAQ01055)

四川大学青年基金(No.2011SCU11081)资助项目。 (No.2011SCU11081)

摘要: 本文以LiOH·H₂O、NH₄VO₃、H₃PO₄和柠檬酸为原料,采用溶胶-喷雾干燥法制备Li₃V₂(PO₄)₃/C正极材料,对比了喷雾前驱体直接煅烧与机械活化后煅烧的样品的结构、形貌及其电化学性能。采用XRD、SEM、BET和振实密度测试等对样品的结构、形貌等进行了表征;采用恒流充放电、CV和EIS等手段考察了材料的电化学性能。结果表明,溶胶-喷雾干燥得到的样品为多孔球壳形,其壳体由厚度为100 nm左右的纳米片组成,经机械活化后煅烧保持保持了其纳米片结构,其结晶度与振实密度改善较明显,电化学性能较优异。0.1C放电比容量为123.6 mAh·g^-1,10C和20C高倍率放电比容量还高达107.8和106.0 mAh·g^-1。电化学阻抗结果表明,由该方法制备的样品具有较小的电荷转移阻抗。

关键词:

Li₃V₂(PO₄)₃/C;正极材料;溶胶-喷雾干燥;空心球壳;纳米片;机械活化

English

Synthesis and Electrochemical Performance of Nano-Structure Li₃V₂(PO₄)₃/C by Sol-Spray Drying Method

1.
1. College of Chemical Engineering, Sichuan University, Chengdu 610065, China;

Corresponding author: 郭孝东,E-mail:xiaodong2009@163.com

Received Date: 09 August 2012
Fund Project:
国家科技支撑计划(No.2007BAQ01055)

四川大学青年基金(No.2011SCU11081)资助项目。

Abstract: Li₃V₂(PO₄)₃/C samples were successfully synthesized by sol-spray drying method, with LiOH·H₂O, NH₄VO₃, H₃PO₄ and critic acid as raw materials, comparing the effect of mechamicalactivation before calcinations and direct calcination on the structure, morphology and electrochemical properties of the samples. The structure and morphology were characterized by XRD, SEM, BET and tap density test, and the electrochemical performance was studied by galvanostatic charge-discharge test, CV and EIS. The results show the samples are hollow spherical shell shape, which is composed of nano-sheet about 100nm and still keep the structure after mechamicalactivation. However, the crystallinity and tap density have improved a lot, so is the electrochemical performance. The discharge capacity is 123.6 mAh·g^-1 at 0.1C, maintaining 107.8 and 106.0 mAh·g^-1 even at high discharge rate of 10C and 20C. The EIS results indicate the samples prepared by the method have a smaller charge transfer resistance.

Key words:

Li₃V₂(PO₄)₃/C;cathode material;sol-spray drying method;hollow spherical shell;nano-sheet;mechamicalactivation

1. [1] ZHAO Hao-Chuan(赵浩川), SONG Yang(宋杨), GUO Xiao- Dong(郭孝东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(10):2347-2352[1] ZHAO Hao-Chuan(赵浩川), SONG Yang(宋杨), GUO Xiao- Dong(郭孝东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(10):2347-2352
2. [2] TANG Hong(唐红), GUO Xiao-Dong(郭孝东), TANG Yan(唐艳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(4):809-814[2] TANG Hong(唐红), GUO Xiao-Dong(郭孝东), TANG Yan(唐艳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(4):809-814
3. [3] WU Yu-Ling(武玉玲), PU Wei-Hua(蒲薇华), REN Jian-Guo (任建国), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2012, 27(4):422-426[3] WU Yu-Ling(武玉玲), PU Wei-Hua(蒲薇华), REN Jian-Guo (任建国), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2012, 27(4):422-426
4. [4] TAGN Yan(唐艳), ZHONG Ben-He(钟本和), GUO Xiao- Dong(郭孝东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(4):869-874[4] TAGN Yan(唐艳), ZHONG Ben-He(钟本和), GUO Xiao- Dong(郭孝东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(4):869-874
5. [5] Zhang B, Zheng J C. Electrochim. Acta, 2012,67(0):55-61[5] Zhang B, Zheng J C. Electrochim. Acta, 2012,67(0):55-61
6. [6] Ko Y N, Koo H Y, Kim J H, et al. J. Power Sources, 2011, 196(16):6682-6687[6] Ko Y N, Koo H Y, Kim J H, et al. J. Power Sources, 2011, 196(16):6682-6687
7. [7] Nagamine K, Honma T, Komatsu T. J. Power Sources, 2011, 196(22):9618-9624[7] Nagamine K, Honma T, Komatsu T. J. Power Sources, 2011, 196(22):9618-9624
8. [8] ZHAI Jing(翟静), ZHAO Min-Shou(赵敏寿), SHA Ou(沙鸥), et al. Rare Metal Mater. Eng.(Xiyou Jinshu Cailiao Yu Gongcheng), 2010,39(7):1310-1316[8] ZHAI Jing(翟静), ZHAO Min-Shou(赵敏寿), SHA Ou(沙鸥), et al. Rare Metal Mater. Eng.(Xiyou Jinshu Cailiao Yu Gongcheng), 2010,39(7):1310-1316
9. [9] Rui X H, Li C, Chen C H. Electrochim. Acta, 2009,54(12): 3374-3380[9] Rui X H, Li C, Chen C H. Electrochim. Acta, 2009,54(12): 3374-3380
10. [10] Qiao Y Q, Tu J P, Mai Y J, et al. J. Alloys Compd., 2011, 509(25):7181-7185[10] Qiao Y Q, Tu J P, Mai Y J, et al. J. Alloys Compd., 2011, 509(25):7181-7185
11. [11] Bini M, Ferrari S, Capsoni D, et al. Electrochim. Acta, 2011,56(6):2648-2655[11] Bini M, Ferrari S, Capsoni D, et al. Electrochim. Acta, 2011,56(6):2648-2655
12. [12] Xia Y, Zhang W K, Huang H, et al. Materials Science and Engineering B, 2011,176(8):633-639[12] Xia Y, Zhang W K, Huang H, et al. Materials Science and Engineering B, 2011,176(8):633-639
13. [13] Pan A Q, Liu J, Zhang J G, et al. Electrochem. Commun., 2010,12(12):1674-1677[13] Pan A Q, Liu J, Zhang J G, et al. Electrochem. Commun., 2010,12(12):1674-1677
14. [14] Liu H W, Cheng C X, Huang X T, et al. Electrochim. Acta, 2010,55(28):8461-8465[14] Liu H W, Cheng C X, Huang X T, et al. Electrochim. Acta, 2010,55(28):8461-8465
15. [15] Wang L J, Zhou X C, Guo Y L. J. Power Sources, 2010,195 (9):2844-2850[15] Wang L J, Zhou X C, Guo Y L. J. Power Sources, 2010,195 (9):2844-2850
16. [16] Fu P, Zhao Y M, Dong Y Z, et al. J. Phys. Chem. Solid, 2010,71(3):394-399[16] Fu P, Zhao Y M, Dong Y Z, et al. J. Phys. Chem. Solid, 2010,71(3):394-399
17. [17] CHEN Quan-Qi(陈权启), HE Wei-Chun(何伟春), WANG Jian-Ming(王建明), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(2):181-190[17] CHEN Quan-Qi(陈权启), HE Wei-Chun(何伟春), WANG Jian-Ming(王建明), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(2):181-190
18. [18] Wang L J, Tang Z Y, Ma L, et al. Electrochem. Commun., 2011,13(11):1233-1235[18] Wang L J, Tang Z Y, Ma L, et al. Electrochem. Commun., 2011,13(11):1233-1235
19. [19] YU Feng(于锋), ZHANG Jing-Jie(张敬杰), YANG Yan-Feng (杨岩峰), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2009, 24(2):349-352[19] YU Feng(于锋), ZHANG Jing-Jie(张敬杰), YANG Yan-Feng (杨岩峰), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2009, 24(2):349-352
20. [20] MA Ping-Ping(马平平), LIU Zhi-Jian(刘志坚), XIA Jian- Hua(夏建华), et al. Chin. J. Rare Metals(Xiyou Jinshu), 2012,36(1):104-108[20] MA Ping-Ping(马平平), LIU Zhi-Jian(刘志坚), XIA Jian- Hua(夏建华), et al. Chin. J. Rare Metals(Xiyou Jinshu), 2012,36(1):104-108
21. [21] Yin S C, Grondey H, Strobel P, et al. J. Am. Chem. Soc., 2003,125:10402-10411[21] Yin S C, Grondey H, Strobel P, et al. J. Am. Chem. Soc., 2003,125:10402-10411
22. [22] Ai D J, Liu K Y, Lu Z G, et al. J. Electrochim. Acta, 2011, 56(7):2823-2827[22] Ai D J, Liu K Y, Lu Z G, et al. J. Electrochim. Acta, 2011, 56(7):2823-2827
23. [23] Qiao Y Q, Tu J P, Wang X L, et al. J. Power Sources, 2011, 196(18):7715-7720[23] Qiao Y Q, Tu J P, Wang X L, et al. J. Power Sources, 2011, 196(18):7715-7720
24. [24] Qiao Y Q, Wang X L, Xiang J Y, et al. Electrochim. Acta, 2011,56(5):2269-2275[24] Qiao Y Q, Wang X L, Xiang J Y, et al. Electrochim. Acta, 2011,56(5):2269-2275
25. [25] Tang A P, Wang X Y, Xu G R, et al. Mater. Lett., 2009,63 (27):2396-2398[25] Tang A P, Wang X Y, Xu G R, et al. Mater. Lett., 2009,63 (27):2396-2398

扫一扫看文章

计量

PDF下载量: 403
文章访问数: 1258
HTML全文浏览量: 97

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

溶胶-喷雾干燥法制备纳米Li₃V₂(PO₄)₃/C及其电化学性能

通讯作者: 郭孝东,E-mail:xiaodong2009@163.com

English

Synthesis and Electrochemical Performance of Nano-Structure Li₃V₂(PO₄)₃/C by Sol-Spray Drying Method

Corresponding author: 郭孝东,E-mail:xiaodong2009@163.com

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处