Multiple Strategies for Controlled Synthesis of Atomically Precise Alloy Nanoclusters

Citation: ZHENG Youkun, JIANG Hui, WANG Xuemei. Multiple Strategies for Controlled Synthesis of Atomically Precise Alloy Nanoclusters[J]. Acta Physico-Chimica Sinica, 2018, 34(7): 740-754. doi: 10.3866/PKU.WHXB201712111 shu

多策略可控合成原子精度合金纳米团簇

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东南大学生物科学与医学工程学院，生物电子学国家重点实验室，生物医学工程国家级实验教学示范中心，南京 210096

作者简介:

WANG Xuemei is currently a full professor of Biomedical Engineering, Southeast University. She obtained her PhD in Chemistry from Nanjing University, China in 1994 and became a lecturer in Nanjing University in 1995. She was an Alexander von Humboldt Fellow in the Chemistry Department, University of Saarland, Germany, before she joined the State Key Laboratory of Bioelectronics, Southeast University in 1998. Her research focuses on bioelectronics and biosensors, biomaterials for multimode bioimaging and nanomedicine;

通讯作者: 王雪梅, xuewang@seu.edu.cn

基金项目:
国家自然科学基金 81325011

国家高技术与发展研究计划 2015AA020502

国家重点研发计划 2017YFA0205300

国家自然科学基金 21175020

国家高技术与发展研究计划(2015AA020502), 国家重点研发计划(2017YFA0205300)和国家自然科学基金(81325011, 21175020)资助项目

摘要: 合金纳米团簇作为一类新兴的多功能纳米材料已被广泛用于催化、光学传感以及生物医学成像等研究领域，而纳米团簇的可控合成和结构特征是调节纳米团簇性质并对其进一步利用的基础。尽管当前有关金属纳米团簇可控合成和结构特征的研究主要集中在单金属纳米团簇中，但有关合金纳米团簇原子精度的可控合成也取得了显著的进展。本文综述了配体保护的合金金属纳米团簇原子精度可控合成策略，包括一步合成法、金属交换、配体交换、化学刻蚀、簇间反应、原位两相配体交换以及最新的表面模体交换反应，并对相关合成策略的优缺点进行了详细的讨论和阐述。

关键词:

English

Multiple Strategies for Controlled Synthesis of Atomically Precise Alloy Nanoclusters

State Key Laboratory of Bioelectronics, National Demonstration Center for Experimental Biomedical Engineering Education, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, P. R. China

Author Bio: WANG Xuemei is currently a full professor of Biomedical Engineering, Southeast University. She obtained her PhD in Chemistry from Nanjing University, China in 1994 and became a lecturer in Nanjing University in 1995. She was an Alexander von Humboldt Fellow in the Chemistry Department, University of Saarland, Germany, before she joined the State Key Laboratory of Bioelectronics, Southeast University in 1998. Her research focuses on bioelectronics and biosensors, biomaterials for multimode bioimaging and nanomedicine;

Corresponding author: WANG Xuemei, xuewang@seu.edu.cn

Received Date: 09 November 2017
Accepted Date: 07 December 2017
Revised Date: 07 December 2017
Available Online: 15 July 2018
Fund Project:

The project was supported by the National High Technology Research and Development Program of China (2015AA020502), the National Key Research and Development Program of China (2017YFA0205300) and the National Natural Science Foundation of China (81325011, 21175020)

Abstract: Alloy metal nanoclusters (NCs), including bimetallic and multimetallic clusters, have recently emerged as a novel class of multifunctional nanomaterials. They are widely used in catalysis, optical sensing, and biological imaging due to their excellent physicochemical properties such as unique electronic structure, ultrasmall size, strong photoluminescence, and rich surface chemistry. Although much progress has been made in the development of NCs, a major challenge in the synthesis of the relevant multifunctional nanomaterial is to achieve the synthetic methodological breakthrough, especially for controlling the synthesis and structure of NCs with atomic precision. It is evident that by realizing controlled synthesis and structural regulation at the atomic scale, we can better understand and tune the fundamental properties of NCs for efficient use in various application areas; this could also shed light on the development of new functionalized nanomaterials. Most of the recent research on the controlled synthesis and structural characterization of metal clusters with atomic precision has focused on monometallic NCs, and significant progress has been realized with respect to alloy metal NCs. A number of synthetic strategies have been developed for synthesizing high-quality alloy NCs with well-defined compositions, sizes, and architectures. In this review, we have highlighted some recent advances in strategies for the precise synthesis of ligands-protected alloy metal NCs, especially thiolate-stabilized gold-based alloy NCs. We classified the synthetic strategies for alloy NCs into several strategies, which include one-pot synthesis, metal exchange, ligand exchange, chemical etching, intercluster reactions, surface motif exchange reaction, and in situ two-phase ligand exchange strategy. One-pot synthesis is facile and widely used as a synthetic strategy for monodisperse alloy NCs with well-defined compositions, sizes, architectures, and surface chemistries. However, the alloy NCs obtained through the one-pot strategy often exhibits a relatively somber fluorescence. Therefore, other synthesis strategies have been exploited that can fabricate alloy NCs exhibiting strong photoluminescence. Among them, the surface motif exchange reaction is expected to be extended to the fabrication of new binary alloy NCs with precise alloy sites to broaden the physicochemical properties of the NCs; intercluster reactions has been explored as an emerging and efficient strategy to fabricate atomically precise alloy NCs. It is noted that the two or multiple metal species incorporated in a single alloy NC usually show unexpected synergistic properties like adjustable electronic structures and strong photoluminescence. Such unique properties have rapidly motivated the research community to use alloy NCs in many applications such as catalysis, biosensors, and biomedicine.

Key words:

1. [1]
  Zhang, L.; Wang, E. Nano Today 2014, 9, 132. doi: 10.1016/j.nantod.2014.02.010
2. [2]
  Tao, Y.; Li, M.; Ren, J.; Qu, X.Chem. Soc. Rev. 2015, 44, 8636. doi: 10.1039/C5CS00607D
3. [3]
  Yang, X.; Yang, M.; Pang, B.; Vara, M.; Xia, Y. Chem. Rev. 2015, 115, 10410. doi: 10.1021/acs.chemrev.5b00193
4. [4]
  Zheng, Y.; Lai, L.; Liu, W.; Jiang, H.; Wang, X. Adv. Colloid Interface Sci. 2017, 242, 1. doi: 10.1016/j.cis.2017.02.005
5. [5]
  Liu, P.; Qin, R.; Fu, G.; Zheng, N. J. Am. Chem. Soc. 2017, 139, 2122. doi: 10.1021/jacs.6b10978
6. [6]
  Tian, Z.; Cheng, L. Nanoscale 2016, 8, 826. doi: 10.1039/C5NR05020K
7. [7]
  Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R. J. Am. Chem. Soc. 2008, 130, 5883. doi: 10.1021/ja801173r
8. [8]
  Zhu, M.; Aikens, C. M.; Hendrich, M. P.; Gupta, R.; Qian, H.; Schatz, G. C.; Jin, R. J. Am. Chem. Soc. 2009, 131, 2490. doi: 10.1021/ja809157f
9. [9]
  Luo, Z.; Yuan, X.; Yu, Y.; Zhang, Q.; Leong, D. T.; Lee, J. Y.; Xie, J. J. Am. Chem. Soc. 2012, 134, 16662. doi: 10.1021/ja306199p
10. [10]
  Xie, J.; Zheng, Y.; Ying, J. Y. J. Am. Chem. Soc. 2009, 131, 888. doi: 10.1021/ja806804u
11. [11]
  Jiang, H.; Su, X.; Zhang, Y.; Zhou, J.; Fang, D.; Wang, X. Anal. Chem. 2016, 88, 4766. doi: 10.1021/acs.analchem.6b00112
12. [12]
  Jiang, H.; Liu, L.; Wang, X. Nanoscale 2017, 9, 9792. doi: 10.1039/C7NR03382F
13. [13]
  Zhu, Y.; Qian, H.; Jin, R. J. Mater. Chem. 2011, 21, 6793. doi: 10.1039/C1JM10082C
14. [14]
  Wang, C.; Li, J.; Amatore, C.; Chen, Y.; Jiang, H.; Wang, X. Angew. Chem. Int. Ed. 2011, 50, 11644. doi: 10.1002/anie.201105573
15. [15]
  Zhang, Y.; Jiang, H.; Wang, X. Anal. Chim. Acta 2015, 870, 1. doi: 10.1016/j.aca.2015.01.016
16. [16]
  Su, X.; Jiang, H.; Wang, X. Anal. Chem. 2015, 87, 10230. doi: 10.1021/acs.analchem.5b02559
17. [17]
  Chen, Y. S.; Kamat, P. V. J. Am. Chem. Soc. 2014, 136, 6075. doi: 10.1021/ja5017365
18. [18]
  Jin, R.; Zeng, C.; Zhou, M.; Chen, Y. Chem. Rev. 2016, 116, 10346. doi: 10.1021/acs.chemrev.5b00703
19. [19]
  Wang, X.; Cai, X.; Hu, J.; Shao, N.; Wang, F.; Zhang, Q.; Xiao, J.; Cheng, Y. J. Am. Chem. Soc. 2013, 135, 9805. doi: 10.1021/ja402903h
20. [20]
  Chen, D.; Luo, Z.; Li, N.; Lee, J. Y.; Xie, J.; Lu, J. Adv. Funct. Mater. 2013, 23, 4324. doi: 10.1002/adfm.201300411
21. [21]
  Gottlieb, E.; Qian, H.; Jin, R. Chem. Eur. J. 2013, 19, 4238. doi: 10.1002/chem.201203158
22. [22]
  Li, Q.; Wang, S.; Kirschbaum, K.; Lambright, K. J.; Das, A.; Jin, R. Chem. Commun. 2016, 52, 5194. doi: 10.1039/C6CC01243D
23. [23]
  Kang, X.; Zhou, M.; Wang, S.; Jin, S.; Sun, G.; Zhu, M.; Jin, R. Chem. Sci. 2017, 8, 2581. doi: 10.1039/C6SC05104A
24. [24]
  Li, G., Jin, R. Catal. Today 2016, 278, 187. doi: 10.1016/j.cattod.2015.11.019
25. [25]
  Yan, J.; Su, H.; Yang, H.; Hu, C.; Malola, S.; Lin, S.; Teo, B. K.; H kkinen, H.; Zheng, N. J. Am. Chem. Soc. 2016, 138, 12751. doi: 10.1021/jacs.6b08100
26. [26]
  Zhang, Y.; Jiang, H.; Ge, W.; Li, Q.; Wang, X. Langmuir 2014, 30, 10910. doi: 10.1021/la5028702
27. [27]
  Huang, J.; Zhu, Y.; Lin, M.; Wang, Q.; Zhao, L.; Yang, Y.; Yao, K.; Han, Y. J. Am. Chem. Soc. 2013, 135, 8552. doi: 10.1021/ja4004602
28. [28]
  Wang, S.; Meng, X.; Das, A.; Li, T.; Song, Y.; Cao, T.; Zhu, X.; Zhu, M.; Jin, R. Angew. Chem. Int. Ed. 2014, 53, 2376. doi: 10.1002/anie.201307480
29. [29]
  Wang, D.; Li, Y. Adv. Mater.2011, 23, 1044. doi: 10.1002/adma.201003695
30. [30]
  Qian, H.; Jiang, D. E.; Li, G.; Gayathri, C.; Das, A.; Gil, R. R.; Jin, R. J. Am. Chem. Soc. 2012, 134, 16159. doi: 10.1021/ja307657a
31. [31]
  Jin, R.; Nobusada, K. Nano Res. 2014, 7, 285. doi: 10.1007/s12274-014-0403-5
32. [32]
  Jin, R.; Zhao, S.; Xing, Y.; Jin, R. CrystEngComm 2016, 18, 3996. doi: 10.1039/C5CE02494C
33. [33]
  Zhang, H.; Watanabe, T.; Okumura, M.; Haruta, M.; Toshima, N. Nat. Mater. 2012, 11, 49. doi: 10.1038/NMAT3143
34. [34]
  Yang, H.; Wang, Y.; Huang, H.; Gell, L.; Lehtovaara, L.; Malola, S.; H kkinen, H.; Zheng, N. Nat. Commun.2013, 4, 2422. doi: 10.1038/ncomms3422
35. [35]
  Chakraborty, I.; Pradeep, T. Chem. Rev. 2017, 117, 8208. doi: 10.1021/acs.chemrev.6b00769
36. [36]
  Kurashige, W.; Niihori, Y.; Sharma, S.; Negishi, Y. Coord. Chem. Rev. 2016, 320, 238. doi: 10.1016/j.ccr.2016.02.013
37. [37]
  孙国栋, 康熙, 金山, 李小武, 胡大乔, 汪恕欣, 朱满洲.物理化学学报, 2018, 34(7), 799. doi: 10.3866/PKU.WHXB201710124Sun, G.; Kang, X.; Jin, S.; Li, X.; Hu, D.; Wang, S.; Zhu, M. Acta Phys.-Chim. Sin. 2018, 34(7), 799. doi: 10.3866/PKU.WHXB201710124
38. [38]
  Kumara, C.; Dass, A. Nanoscale 2012, 4, 4084. doi: 10.1039/c2nr11781a
39. [39]
  Qian, H.; Barry, E.; Zhu, Y.; Jin, R. Acta Phys.-Chim. Sin. 2011, 27, 513. doi: 10.3866/PKU.WHXB20110304
40. [40]
  Wan, X. K.; Cheng, X. L.; Tang, Q.; Han, Y. Z.; Hu, G.; Jiang, D. E.; Wang, Q. M. J. Am. Chem. Soc. 2017, 139, 9451. doi: 10.1021/jacs.7b04622
41. [41]
  Bootharaju, M. S.; Kozlov, S. M.; Cao, Z.; Harb, M.; Maity, N.; Shkurenko, A.; Parida, M. R.; Hedhili, M. N.; Eddaoudi, M.; Mohammed, O. F.; et al. J. Am. Chem. Soc. 2017, 139, 1053. doi: 10.1021/jacs.6b11875
42. [42]
  Yamazoe, S.; Kurashige, W.; Nobusada, K.; Negishi, Y.; Tsukuda, T. J. Phys. Chem. C 2014, 118, 25284. doi: 10.1021/jp5085372
43. [43]
  Yang, S.; Wang, S.; Jin, S.; Chen, S.; Sheng, H.; Zhu, M. Nanoscale 2015, 7, 10005. doi: 10.1039/c5nr01965f
44. [44]
  Kwak, K.; Choi, W.; Tang, Q.; Kim, M.; Lee, Y.; Jiang, D. E.; Lee, D. Nat. Commun. 2017, 8, 14723. doi: 10.1038/ncomms14723
45. [45]
  Chai, J.; Lv, Y.; Yang, S.; Song, Y.; Zan, X.; Li, Q.; Yu, H.; Wu, M.; Zhu, M. J. Phys. Chem. C, 2017, 121, 21665. doi: 10.1021/acs.jpcc.7b05074
46. [46]
  Kumara, C.; Gagnon, K. J.; Dass, A. J. Phys. Chem. Lett. 2015, 6, 1223. doi: 10.1021/acs.jpclett.5b00270
47. [47]
  Kumara, C.; Dass, A. Nanoscale 2011, 3, 3064. doi: 10.1039/C1NR10429B
48. [48]
  Koivisto, J.; Malola, S.; Kumara, C.; Dass, A.; Häkkinen, H.; Pettersson, M. J. Phys. Chem. Lett.2012, 3, 3076. doi: 10.1021/jz301261x
49. [49]
  Sharma, S.; Kurashige, W.; Nobusada, K.; Negishi, Y. Nanoscale 2015, 7, 10606. doi: 10.1039/c5nr01491c
50. [50]
  Yan, J.; Su, H.; Yang, H.; Malola, S.; Lin, S.; Häkkinen, H.; Zheng, N. J. Am. Chem. Soc. 2015, 137, 11880. doi: 10.1021/jacs.5b07186
51. [51]
  Wang, Y.; Su, H.; Xu, C.; Li, G.; Gell, L.; Lin, S.; Tang, Z.; Häkkinen, H.; Zheng, N. J. Am. Chem. Soc. 2015, 137, 4324. doi: 10.1021/jacs.5b01232
52. [52]
  Bhat, S.; Baksi, A.; Mudedla, S. K.; Natarajan, G.; Subramanian, V.; Pradeep, T. J. Phys. Chem. Lett. 2017, 8, 2787. doi: 10.1021/acs.jpclett.7b01052
53. [53]
  Yan, N.; Liao, L.; Yuan, J.; Lin, Y. J.; Weng, L. H.; Yang, J.; Wu, Z. Chem. Mater. 2016, 28, 8240. doi: 10.1021/acs.chemmater.6b03132
54. [54]
  Zeng, J. L.; Guan, Z. J.; Du, Y.; Nan, Z. A.; Lin, Y. M.; Wang, Q. M. J. Am. Chem. Soc. 2016, 138, 7848. doi: 10.1021/jacs.6b04471
55. [55]
  Biltek, S. R.; Reber, A. C.; Khanna, S. N.; Sen, A. J. Phys. Chem. A 2017, 121, 5324. doi: 10.1021/acs.jpca.7b04669
56. [56]
  Yao, C.; Lin, Y. J.; Yuan, J.; Liao, L.; Zhu, M.; Weng, L.; Yang, J.; Wu, Z. J. Am. Chem. Soc. 2015, 137, 15350. doi: 10.1021/jacs.5b09627
57. [57]
  Tofanelli, M. A.; Ni, T. W.; Phillips, B. D.; Ackerson, C. J. Inorg. Chem. 2016, 55, 999. doi: 10.1021/acs.inorgchem.5b02106
58. [58]
  Fernández, E. J.; Laguna, A.; López-de-Luzuriaga, J. M.; Monge, M.; Olmos, M. E.; Puelles, R. C. J. Phys. Chem. B 2005, 109, 20652. doi: 10.1021/jp055007n
59. [59]
  Negishi, Y.; Iwai, T.; Ide, M. Chem. Commun. 2010, 46, 4713. doi: 10.1039/c0cc01021a
60. [60]
  Kauffman, D. R.; Alfonso, D.; Matranga, C.; Qian, H.; Jin, R. J. Phys. Chem. C 2013, 117, 7914. doi: 10.1021/jp4013224
61. [61]
  Dou, X.; Yuan, X.; Yao, Q.; Luo, Z.; Zheng, K.; Xie, J. Chem. Commun. 2014, 50, 7459. doi: 10.1039/C4CC02261K
62. [62]
  Yuan, X.; Zhang, B.; Luo, Z.; Yao, Q.; Leong, D. T.; Yan, N.; Xie, J. Angew. Chem. Int. Ed. 2014, 126, 4711. doi: 10.1002/ange.201311177
63. [63]
  Chen, T.; Yang, S.; Chai, J.; Song, Y.; Fan, J.; Rao, B.; Sheng, H.; Yu, H.; Zhu, M. Sci. Adv. 2017, 3, e1700956. doi: 10.1126/sciadv.1700956
64. [64]
  Wang, Z.; Senanayake, R.; Aikens, C. M.; Chen, W. M.; Tung, C. H.; Sun, D. Nanoscale 2016, 8, 18905. doi: 10.1039/c6nr06615a
65. [65]
  Wang, Y.; Wan, X. K.; Ren, L.; Su, H.; Li, G.; Malola, S.; Lin, S.; Tang, Z.; Häkkinen, H.; Teo, B. K.; et al. J. Am. Chem. Soc. 2016, 138, 3278. doi: 10.1021/jacs.5b12730
66. [66]
  Wang, S.; Jin, S.; Yang, S.; Chen, S.; Song, Y.; Zhang, J.; Zhu, M. Sci. Adv. 2015, 1, e1500441. doi: 10.1126/sciadv.1500441
67. [67]
  Ataee-Esfahani, H.; Wang, L.; Nemoto, Y.; Yamauchi, Y. Chem. Mater. 2010, 22, 6310. doi: 10.1021/cm102074w
68. [68]
  Crooks, R. M.; Zhao, M.; Sun, L.; Chechik, V.; Yeung, L. K. Acc. Chem. Res. 2011, 34, 181. doi: 10.1021/ar000110
69. [69]
  Formo, E.; Lee, E.; Campbell, D.; Xia, Y. Nano Lett. 2008, 8, 668. doi: 10.1021/nl073163v
70. [70]
  Christensen, S. L.; MacDonald, M. A.; Chatt, A.; Zhang, P.; Qian, H.; Jin, R. J. Phys. Chem. C 2012, 116, 26932. doi: 10.1021/jp310183x
71. [71]
  Kwak, K.; Tang, Q.; Kim, M.; Jiang, D. E.; Lee, D. J. Am. Chem. Soc. 2015, 137, 10833. doi: 10.1021/jacs.5b06946
72. [72]
  Zhao, Y.; Ye, C.; Liu, W.; Chen, R.; Jiang, X. Angew. Chem. Int. Ed. 2014, 53, 8127. doi: 10.1002/anie.201401035
73. [73]
  Zhou, M.; Qian, H.; Sfeir, M. Y.; Nobusada, K.; Jin, R. Nanoscale 2016, 8, 7163. doi: 10.1039/c6nr01008c
74. [74]
  Negishi, Y.; Kurashige, W.; Niihori, Y.; Iwasa, T.; Nobusada, K. Phys. Chem. Chem. Phys. 2010, 12, 6219. doi: 10.1039/b927175a
75. [75]
  Negishi, Y.; Kurashige, W.; Kobayashi, Y.; Yamazoe, S.; Kojima, N.; Seto, M.; Tsukuda, T. J. Phys. Chem. Lett. 2013, 4, 3579. doi: 10.1021/jz402030n
76. [76]
  Negishi, Y.; Igarashi, K.; Munakata, K.; Ohgake, W.; Nobusada, K. Chem. Commun. 2012, 48, 660. doi: 10.1039/c1cc15765e
77. [77]
  Kang, X.; Xiang, J.; Lv, Y.; Du, W.; Yu, H.; Wang, S.; Zhu, M. Chem. Mater. 2017, 29, 6856. doi: 10.1021/acs.chemmater.7b02015
78. [78]
  Kurashige, W.; Negishi, Y. J. Clust. Sci. 2012, 23, 365. doi: 10.1007/s10876-011-0437-8
79. [79]
  Baksi, A.; Pradeep, T. Nanoscale 2013, 5, 12245. doi: 10.1039/C3NR04257J
80. [80]
  Kurashige, W.; Munakata, K.; Nobusada, K.; Negishi, Y. Chem. Commun. 2013, 49, 5447. doi: 10.1039/C3CC41210E
81. [81]
  Dharmaratne, A. C.; Dass, A. Chem. Commun. 2014, 50, 1722. doi: 10.1039/c3cc47060a
82. [82]
  Negishi, Y.; Munakata, K.; Ohgake, W.; Nobusada, K. J. Phys. Chem. Lett. 2012, 3, 2209. doi: 10.1021/jz300892w
83. [83]
  Yang, H.; Wang, Y.; Lei, J.; Shi, L.; Wu, X.; Mäkinen, V.; Lin, S.; Tang, Z.; He, J.; Häkkinen, H.; et al. J. Am. Chem. Soc. 2013, 135, 9568. doi: 10.1021/ja402249s
84. [84]
  Yang, H.; Wang, Y.; Yan, J.; Chen, X.; Zhang, X.; Häkkinen, H.; Zheng, N. J. Am. Chem. Soc. 2014, 136, 7197. doi: 10.1021/ja501811j
85. [85]
  Shen, H.; Mizuta, T. Chem.-Asian J., 2017, doi: 10.1002/asia.201701337
86. [86]
  Biltek, S. R.; Mandal, S.; Sen, A.; Reber, A. C.; Pedicini, A. F.; Khanna, S. N. J. Am. Chem. Soc. 2012, 135, 26. doi: 10.1021/ja308884s
87. [87]
  Liu, X.; Astruc, D. Adv. Mater. 2017, 29, 1605305. doi: 10.1002/adma.201605305
88. [88]
  Oh, M. H.; Yu, T.; Yu, S. H.; Lim, B.; Ko, K. T.; Willinger, M. G.; Seo, D. H.; Kim, B. H.; Cho, M. G.; Park, J. H.; et al. Science 2013, 340, 964. doi: 10.1126/science.1234751
89. [89]
  Zhang, H.; Jin, M.; Wang, J.; Li, W.; Camargo, P. H.; Kim, M. J.; Yang, D.; Xie, Z.; Xia, Y. J. Am. Chem. Soc. 2011, 133, 6078. doi: 10.1021/ja201156s
90. [90]
  Murugadoss, A.; Kai, N.; Sakurai, H. Nanoscale 2012, 4, 1280. doi: 10.1039/c2nr11727d
91. [91]
  Mohanty, J. S.; Xavier, P. L.; Chaudhari, K.; Bootharaju, M. S.; Goswami, N.; Pal, S. K.; Pradeep, T. Nanoscale2012, 4, 4255. doi: 10.1039/c2nr30729d
92. [92]
  Bootharaju, M. S.; Joshi, C. P.; Parida, M. R.; Mohammed, O. F.; Bakr, O. M. Angew. Chem. Int. Ed. 2016, 55, 922. doi: 10.1002/anie.201509381
93. [93]
  Udayabhaskararao, T.; Sun, Y.; Goswami, N.; Pal, S. K.; Balasubramanian, K.; Pradeep, T. Angew. Chem. Int. Ed. 2012, 51, 2155. doi: 10.1002/anie.201107696
94. [94]
  Du, W.; Jin, S.; Xiong, L.; Chen, M.; Zhang, J.; Zou, X.; Pei, Y.; Wang, S.; Zhu, M. J. Am. Chem. Soc. 2017, 139, 1618. doi: 10.1021/jacs.6b11681
95. [95]
  Kang, X.; Xiong, L.; Wang, S.; Yu, H.; Jin, S.; Song, Y.; Chen, T.; Zheng, L.; Pan, C.; Pei, Y.; et al.Chem.-Eur. J. 2016, 22, 17145. doi: 10.1002/chem.201603893
96. [96]
  Choi, J. P.; Fields-Zinna, C. A.; Stiles, R. L.; Balasubramanian, R.; Douglas, A. D.; Crowe, M. C.; Murray, R. W. J. Phys. Chem. C 2010, 114, 15890. doi: 10.1021/jp9101114
97. [97]
  Wu, Z. Angew. Chem. Int. Ed. 2012, 51, 2934. doi: 10.1002/anie.201107822
98. [98]
  Wang, S.; Song, Y.; Jin, S.; Liu, X.; Zhang, J.; Pei, Y.; Meng, X.; Chen, M.; Li, P.; Zhu, M. J. Am. Chem. Soc. 2015, 137, 4018. doi: 10.1021/ja511635g
99. [99]
  Li, Q.; Luo, T. Y.; Taylor, M. G.; Wang, S.; Zhu, X.; Song, Y.; Mpourmpakis, G.; Rosi, N. L.; Jin, R. Sci. Adv. 2017, 3, e1603193. doi: 10.1126/sciadv.1603193
100. [100]
  Yang, S.; Chai, J.; Chen, T.; Rao, B.; Pan, Y.; Yu, H.; Zhu, M. Inorg. Chem. 2017, 56, 1771. doi: 10.1021/acs.inorgchem.6b02016
101. [101]
  Kang, X.; Silalai, C.; Lv, Y.; Sun, G.; Chen, S.; Yu, H.; Xu, F.; Zhu, M. Eur. J. Inorg. Chem. 2017, 2017, 1414. doi: 10.1002/ejic.201601513
102. [102]
  Wang, M.; Wu, Z.; Chu, Z.; Yang, J.; Yao, C. Chem.-Asian J. 2014, 9, 1006. doi: 10.1002/asia.201301562
103. [103]
  Tian, S.; Yao, C.; Liao, L.; Xia, N.; Wu, Z. Chem. Commun. 2015, 51, 11773. doi: 10.1039/c5cc03267a
104. [104]
  Lin, C. A. J.; Yang, T. Y.; Lee, C. H.; Huang, S. H.; Sperling, R. A.; Zanella, M.; Li, J. K.; Shen, J. L.; Wang, H. H.; Yeh, H. I.; et al. ACS Nano 2009, 3, 395. doi: 10.1021/nn800632j
105. [105]
  Shang, L.; Dong, S.; Nienhaus, G. Nano Today 2011, 6, 401. doi: 10.1016/j.nantod.2011.06.004
106. [106]
  Wu, Z.; Jin, R. Nano Lett.2010, 10, 2568. doi: 10.1021/nl101225f
107. [107]
  Xiang, J.; Li, P.; Song, Y.; Liu, X.; Chong, H.; Jin, S.; Pei, Y.; Yuan, X.; Zhu, M. Nanoscale 2015, 7, 18278. doi: 10.1039/c5nr05131b
108. [108]
  Fan, J.; Song, Y.; Chai, J.; Yang, S.; Chen, T.; Rao, B.; Yu, H.; Zhu, M. Nanoscale 2016, 8, 15317. doi: 10.1039/c6nr04255d
109. [109]
  Li, Q.; Taylor, M. G.; Kirschbaum, K.; Lambright, K. J.; Zhu, X.; Mpourmpakis, G.; Jin, R. J. Colloid Interface Sci. 2017, 505, 1202. doi: 10.1016/j.jcis.2017.06.049
110. [110]
  Sels, A.; Salassa, G.; Pollitt, S.; Guglieri, C.; Rupprechter, G.; Barrabés, N.; Bürgi, T. J. Phys. Chem. C 2017, 121, 10919. doi: 10.1021/acs.jpcc.6b12066
111. [111]
  Niihori, Y.; Kikuchi, Y.; Kato, A.; Matsuzaki, M.; Negishi, Y. ACS Nano 2015, 9, 9347. doi: 10.1021/acsnano.5b03435
112. [112]
  Kothalawala, N.; Kumara, C.; Ferrando, R.; Dass, A. Chem. Commun. 2013, 49, 10850. doi: 10.1039/c3cc45669b
113. [113]
  Jupally, V. R.; Dass, A. Phys. Chem. Chem. Phys. 2014, 16, 10473. doi: 10.1039/c3cp54343a
114. [114]
  Krishnadas, K. R.; Ghosh, A.; Baksi, A.; Chakraborty, I.; Natarajan, G.; Pradeep, T. J. Am. Chem. Soc.2015, 138, 140. doi: 10.1021/jacs.5b09401
115. [115]
  Krishnadas, K. R.; Baksi, A.; Ghosh, A.; Natarajan, G.; Pradeep, T. Nat. Commun. 2016, 7, 13447. doi: 10.1038/ncomms13447
116. [116]
  Krishnadas, K. R.; Baksi, A.; Ghosh, A.; Natarajan, G.; Pradeep, T. ACS Nano 2017, 11, 6015. doi: 10.1021/acsnano.7b01912
117. [117]
  Krishnadas, K. R.; Baksi, A.; Ghosh, A.; Natarajan, G.; Som, A.; Pradeep, T. Acc. Chem. Res. 2017, 50, 1988. doi: 10.1021/acs.accounts.7b00224
118. [118]
  Krishnadas, K. R.; Ghosh, D.; Ghosh, A.; Natarajan, G.; Pradeep, T. J. Phys. Chem. C 2017, 121, 23224. doi: 10.1021/acs.jpcc.7b07605
119. [119]
  Yang, S.; Chai, J.; Song, Y.; Fan, J.; Chen, T.; Wang, S.; Yu, H.; Li, X.; Zhu, M. J. Am. Chem. Soc. 2017, 139, 5668. doi: 10.1021/jacs.7b00668
120. [120]
  Chai, J.; Lv, Y.; Yang, S.; Song, Y.; Zan, X.; Li, Q.; Yu, H.; Wu, M.; Zhu, M. J. Phys. Chem. C 2017, 121, 21665. doi: 10.1021/acs.jpcc.7b05074
121. [121]
  Yao, Q.; Feng, Y.; Fung, V.; Yu, Y.; Jiang, D. E.; Yang, J.; Xie, J. Nat. Commun. 2017, 8, 1555. doi: 10.1038/s41467-017-01736-5

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沈阳化工大学材料科学与工程学院沈阳 110142

多策略可控合成原子精度合金纳米团簇

通讯作者: 王雪梅, xuewang@seu.edu.cn

English

Multiple Strategies for Controlled Synthesis of Atomically Precise Alloy Nanoclusters

Corresponding author: WANG Xuemei, xuewang@seu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

多策略可控合成原子精度合金纳米团簇

通讯作者: 王雪梅, xuewang@seu.edu.cn

English

Multiple Strategies for Controlled Synthesis of Atomically Precise Alloy Nanoclusters

Corresponding author: WANG Xuemei, xuewang@seu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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