无机非铅钙钛矿太阳能电池研究进展

引用本文: 顾津宇, 齐朋伟, 彭扬. 无机非铅钙钛矿太阳能电池研究进展[J]. 物理化学学报, 2017, 33(7): 1379-1389. doi: 10.3866/PKU.WHXB201704182 shu

Citation: GU Jin-Yu, QI Peng-Wei, PENG Yang. Progress on the Development of Inorganic Lead-Free Perovskite Solar Cells[J]. Acta Physico-Chimica Sinica, 2017, 33(7): 1379-1389. doi: 10.3866/PKU.WHXB201704182 shu

无机非铅钙钛矿太阳能电池研究进展

1.
苏州大学能源与材料创新研究院, 物理光电能源学部, 纳米科学与技术协同创新中心, 江苏苏州 215006;
2.
苏州大学, 江苏省先进碳材料与可穿戴能源重点实验室, 江苏苏州 215006
基金项目:
江苏省自然科学基金（BK20160323）资助项目

摘要: 钙钛矿太阳能电池因其光吸收效率高、载流子寿命长、晶格缺陷容忍度高、能带可调等优点得到迅速发展，在短短几年内其太阳能转化效率已经达到22.1%。然而，在人们看到钙钛矿太阳能电池广阔发展前景的同时，其铅毒性和不稳定性严重限制了它的应用推广。无机非铅钙钛矿太阳能电池（ABX₃、A₂BB'X₆等）利用Sn、Ge、Bi、Ag等金属取代铅，以Cs、Rb等取代甲胺有希望解决目前钙钛矿太阳能电池的毒性和稳定性问题。本文主要对近几年无机非铅钙钛矿太阳能电池的研究现状做一个分析总结，并对其发展前景进行展望。

关键词:

English

Progress on the Development of Inorganic Lead-Free Perovskite Solar Cells

1.
Soochow Institute for Energy and Materials Innovations, College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006, Jiangsu Province, P. R. China;
2.
Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, Jiangsu Province, P. R. China
Received Date: 15 December 2016
Revised Date: 15 December 2016
Available Online: 18 April 2017
Fund Project:
The project was supported by the Natural Science Foundation of Jiangsu Province, China (BK20160323).

Abstract: Perovskite solar cells have undergone rapid development because of their high solar absorption efficiencies, long carrier lifetime and diffusion length, high tolerance to lattice defects, and tunable bandgaps. In the past few years, the solar energy conversion efficiency of the perovskite solar cells has increased to 22.1%. However, despite their promising prospects, as demonstrated by the laboratory-fabricated prototypes, lead toxicity and instability of perovskite solar cells severely impeded their industrialization and applications. Recently, inorganic lead-free perovskite solar cells (such as ABX₃ and A₂BB'X₆), which use Sn, Ge, Bi, Ag, and other metals as replacements for Pb, and Cs and Rb as replacements for methylamine, have been pursued as potential solutions for the toxicity and stability issues. This review highlights the recent research efforts in the development of inorganic lead-free perovskite solar cells and provides a perspective on future developments.

Key words:

1. [1]
  (1) Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. J. Am. Chem. Soc.2009, 131, 6050. doi: 10.1021/ja809598r
2. [2]
  (2) Im, J. H.; Lee, C. R.; Lee, J. W.; Park, S. W.; Park, N. G. Nanoscale 2011, 3, 4088. doi: 10.1039/c1nr10867k
3. [3]
  (3) Green, M. A.; Ho-Baillie, A.; Snaith, H. J. Nat. Photonics 2014, 8, 506. doi: 10.1038/nphoton.2014.134
4. [4]
  (4) Kim, H. S.; Lee, C. R.; Im, J. H.; Lee, K. B.; Moehl, T.; Marchioro, A.; Moon, S. J.; Humphry-Baker, R.; Yum, J. H.; Moser, J. E.; Grätzel, M.; Park, N. G. Sci. Rep. 2012, 2, 591. doi: 10.1038/srep00591
5. [5]
  (5) Niu, G.; Guo, X.; Wang, L. J. Mater. Chem. A. 2015, 3, 8970. doi: 10.1039/C4TA04994B
6. [6]
  (6) Hao, F.; Stoumpos, C. C.; Cao, D. H.; Chang, R. P. H.; Kanatzidis, M.G. Nat. Photonics 2014, 8, 489. doi: 10.1038/nphoton.2014.82
7. [7]
  (7) Im, J.; Stoumpos, C. C.; Jin, H.; Freeman, A. J.; Kanatzidis, M. G. J. Phys. Chem. Lett. 2015, 6, 3503. doi: 10.1021/acs.jpclett.5b01738
8. [8]
  (8) Yamada, K.; Nakada, K.; Takeuchi, Y.; Nawa, K.; Yamane, Y. Bull. Chem. Soc. Jp. 2011, 84, 926. doi: 10.1246/bcsj.20110075
9. [9]
  (9) Chiarella, F.; Zappettini, A.; Licci, F.; Borriello, I.; Cantele, G.; Ninno, D.; Cassinese, A.; Vaglio, R. Phys. Rev. B 2008, 77, 045129. doi:10.1103/PhysRevB.77.045129
10. [10]
  (10) Yin, W. J.; Shi, T.; Yan, Y. Adv. Mater. 2014, 26, 4653. doi: 10.1002/adma.201306281
11. [11]
  (11) Yin, W. J.; Shi, T.; Yan, Y. Appl. Phys. Lett. 2014, 104, 063903. doi: 10.1063/1.4864778
12. [12]
  (12) Amat, A.; Mosconi, E.; Ronca, E.; Quarti, C.; Umari, P.; Nazeeruddin, M. K.; Grätzel, M.; De Angelis, F. Nano Lett. 2014, 14, 3608. doi: 10.1021/nl5012992
13. [13]
  (13) Huang, L. Y.; Lambrecht, W. R. L. Phys. Rev. B 2016, 93, 195211. doi: 10.1103/PhysRevB.93.195211
14. [14]
  (14) Hao, F.; Stoumpos, C. C.; Chang, R. P. H.; Kanatzidis, M. G. J. Am. Chem. Soc. 2014, 136, 8094. doi: 10.1021/ja5033259
15. [15]
  (15) Lin, G.; Lin, Y.; Huang, H.; Cui, R.; Guo, X.; Liu, B.; Dong, J.; Guo, X.; Sun, B. Nano Energy 2016, 27, 638. doi: 10.1016/j.nanoen.2016.08.015
16. [16]
  (16) Feng, J. Appl. Mater. 2014, 2, 081801. doi: 10.1063/1.4885256
17. [17]
  (17) Scaife, D. E.; Weller, P. F.; Fisher, W. G. J. Solid State Chem. 1974, 9, 308. doi: 10.1016/0022-4596(74)90088-7
18. [18]
  (18) Yamada, K.; Funabiki, S.; Horimoto, H.; Matsui, T.; Okuda, T.; Ichiba, S. Chem. Lett. 1991, 801. doi: 10.1246/cl.1991.801
19. [19]
  (19) Chung, I.; Song, J. H.; Im, J.; Androulakis, J.; Malliakas, C. D.; Li, H.; Freeman, A. J.; Kenney, J. T.; Kanatzidis, M. G. J. Am. Chem. Soc. 2012, 134, 8579. doi: 10.1021/ja301539s
20. [20]
  (20) Shum, K.; Chen, Z.; Qureshi, J.; Yu, C.; Wang, J. J.; Pfenninger, W.; Vockic, N.; Midgley, J.; Kenney, J. T. Appl. Phys. Lett. 2010, 96, 221903. doi: 10.1063/1.3442511
21. [21]
  (21) Chen, Z.; Yu, C.; Shum, K.; Wang, J. J.; Pfenninger, W. N.; Vockic;Midgley, J.; Kenney, J. T. J. Luminescence 2012, 132, 345. doi: 10.1016/j.jlumin.2011.09.006
22. [22]
  (22) Xing, G.; Kumar, M. H.; Chong, W. K.; Liu, X.; Cai, Y.; Ding, H.; Asta, M.; Grätzel, M.; Mhaisalkar, S.; Mathews, N.; Sum, T. C. Adv. Mater. 2016, 28, 8191. doi: 10.1002/adma.201601418
23. [23]
  (23) Wang, N.; Zhou, Y.; Ju, M. G.; Garcès, H. F.; Ding, T.; Pang, S.; Zeng, X. C.; Padture, N. P.; Sun, X. W. Adv. Energy Mater. 2016, 160, 1130. doi: 10.1002/aenm.201601130
24. [24]
  (24) Xu, P.; Chen, S.; Xiang, H. J.; Gong, X. G.; Wei, S. H. Chem. Mater. 2014, 26, 6068. doi: 10.1021/cm503122j
25. [25]
  (25) Kumar, M. H.; Dharani, S.; Leong, W. L.; Boix, P. P.; Prabhakar, R. R.; Baikie, T.; Shi, C.; Ding, H.; Ramesh, R.; Asta, M.; Grätzel, M.; Mhaisalkar, S. G.; Mathews, N. Adv. Mater. 2014, 26, 7122. doi: 10.1002/adma.201401991
26. [26]
  (26) Sabba, D.; Mulmudi, H. K.; Prabhakar, R. R.; Krishnamoorthy, T.; Baikie, T.; Boix, P. P.; Mhaisalkar, S.; Mathews, N. J. Phys. Chem.C.2015, 119, 1763. doi: 10.1021/jp5126624
27. [27]
  (27) Peedikakkandy, L.; Bhargava, P. RSC Adv. 2016, 6, 19857. doi: 10.1039/c5ra22317b
28. [28]
  (28) Seo, D. K.; Gupta, N.; Whangbo, M. H.; Hillebrecht, H.; Thiele, G. Inorg Chem. 1998, 37, 407. doi: 10.1021/ic970659e
29. [29]
  (29) Thiele, G.; Rotter, H. W.; Schmidt, K. D. Zeitschrift Fur Anorganische Und Allgemeine Chemie 1987, 545, 148. doi: 10.1002/zaac.19875450217
30. [30]
  (30) Stoumpos, C. C.; Frazer, L.; Clark, D. J.; Kim, Y. S.; Rhim, S. H.; Freeman, A. J.; Ketterson, J. B.; Jang, J. I.; Kanatzidis, M. G. J. Am. Chem. Soc. 2015, 137, 6804. doi: 10.1021/jacs.5b01025
31. [31]
  (31) Krishnamoorthy, T.; Ding, H.; Yan, C.; Leong, W. L.; Baikie, T.; Zhang, Z.; Sherburne, M.; Li, S.; Asta, M.; Mathews, N.; Mhaisalkar, S. G. J. Mater. Chem. A 2015, 3, 23829. doi: 10.1039/c5ta05741h
32. [32]
  (32) Ming, W.; Shi, H.; Du, M. H. J. Mater. Chem. A 2016, 4, 13852. doi: 10.1039/c6ta04685a
33. [33]
  (33) Chen, F. S. J. Appl. Phys. 1969, 40, 3389. doi: 10.1063/1.1658195
34. [34]
  (34) Choi, T.; Lee, S.; Choi, Y. J.; Kiryukhin, V.; Cheong, S. W. Science 2009, 324, 63. doi: 10.1126/science.1168636
35. [35]
  (35) Chakrabartty, J. P.; Nechache, R.; Harnagea, C.; Rosei, F. Opt. Exp. 2014, 22, 80. doi: 10.1364/oe.22.000a80
36. [36]
  (36) Yang, S. Y.; Martin, L. W.; Byrnes, S. J.; Conry, T. E.; Basu, S. R.; Paran, D.; Reichertz, L.; Ihlefeld, J.; Adamo, C.; Melville, A.; Chu, Y.H.; Yang, C. H.; Musfeldt, J. L.; Schlom, D. G.; Ager, J. W., III;Ramesh, R. Appl. Phys. Lett. 2009, 95, 062909. doi: 10.1063/1.3204695
37. [37]
  (37) Qu, T. L.; Zhao, Y. G.; Xie, D.; Shi, J. P.; Chen, Q. P.; Ren, T. L. Appl. Phys. Lett. 2011, 98, 173507. doi: 10.1063/1.3584031
38. [38]
  (38) Guo, Y.; Guo, B.; Dong, W.; Li, H.; Liu, H. Nanotechnology 2013, 24, 275201. doi: 10.1088/0957-4484/24/27/275201
39. [39]
  (39) Bhatnagar, A.; Chaudhuri, A. R.; Kim, Y. H.; Hesse, D.; Alexe, M. Nat. Commun. 2013, 4, 2835. doi: 10.1038/ncomms3835
40. [40]
  (40) Nechache, R.; Harnagea, C.; Li, S.; Cardenas, L.; Huang, W.; Chakrabartty, J.; F. Rosei. Nat. Photonics 2015, 9, 61. doi: 10.1038/nphoton.2014.255
41. [41]
  (41) Kamba, S.; Nuzhnyy, D.; Nechache, R.; Zaveta, K.; Niznansky, D.; Santava, E.C.; Harnagea; Pignolet, A. Phys. Rev. B 2008, 77, 104111. doi: 10.1103/PhysRevB.77.104111
42. [42]
  (42) Nechache, R.; Cojocaru, C. V.; Harnagea, C.; Nauenheim, C.; Nicklaus, M.; Ruediger, A.; Rosei, F.; Pignolet, A. Adv. Mater. 2011, 23, 1724. doi: 10.1002/adma.201004405
43. [43]
  (43) McClure, E. T.; Ball, M. R.; Windl, W.; Woodward, P. M. Chem. Mater.2016, 28, 1348. doi: 10.1021/acs.chemmater.5b04231
44. [44]
  (44) Volonakis, G.; Filip, M. R.; Haghighirad, A. A.; Sakai, N.; Wenger, B.; Snaith, H. J.; Giustino, F. J. Phys. Chem. Lett. 2016, 7, 1254. doi: 10.1021/acs.jpclett.6b00376
45. [45]
  (45) Xiao, Z.; Meng, W.; Wang, J.; Yan, Y. ChemSusChem 2016, 9, 2628. doi: 10.1002/cssc.201600771
46. [46]
  (46) Filip, M. R.; Hillman, S.; Haghighirad, A. A.; Snaith, H. J.; Giustino, F. J. Phys. Chem. Lett. 2016, 7, 2579. doi: 10.1021/acs.jpclett.6b01041
47. [47]
  (47) Slavney, A. H.; Hu, T.; Lindenberg, A. M.; Karunadasa, H. I. J. Am. Chem. Soc. 2016, 138, 2138. doi: 10.1021/jacs.5b13294
48. [48]
  (48) Gou, G.; Young, J.; Liu, X.; Rondinelli, J. M. Inorg. Chem. 2016, 56, 26. doi: 10.1021/acs.inorgchem.6b01701
49. [49]
  (49) Saparov, B.; Sun, J. P.; Meng, W.; Xiao, Z.; Duan, H. S.; Gunawan, O.; Shin, D.; Hill, I. G.; Yan, Y.; Mitzi, D. B. Chem. Mater. 2016, 28, 2315. doi: 10.1021/acs.chemmater.6b00433
50. [50]
  (50) Kaltzoglou, A.; Antoniadou, M.; Perganti, D.; Siranidi, E.; Raptis, V.; Trohidou, K.; Psycharis, V. A.; Kontos, G.; Falaras, P. Electrochim. Acta 2015, 184, 466. doi: 10.1016/j.electacta.2015.10.030
51. [51]
  (51) Lee, B.; Stoumpos, C. C.; Zhou, N.; Hao, F.; Malliakas, C.; Yeh, C. Y.; Marks, T. J.; Kanatzidis, M. G.; Chang, R. P. H. J. Am. Chem. Soc. 2014, 136, 15379. doi: 10.1021/ja508464w
52. [52]
  (52) Qiu, X.; Cao, B.; Yuan, S.; Chen, X.; Qiu, Z.; Jiang, Y.; Ye, Q.; Wang, H.; Zeng, H.; Liu, J.; Kanatzidis, M. G. Sol. Energy Mater. Sol. Cells 2017, 159, 227. doi: 10.1016/j.solmat.2016.09.022
53. [53]
  (53) Qiu, X.; Jiang, Y.; Zhang, H.; Qiu, Z.; Yuan, S.; Wang, P.; Cao, B. Phys. Status Solidi-Rapid Res. Lett. 2016, 10, 587. doi: 10.1002/pssr.201600166
54. [54]
  (54) Lehner, A. J.; Fabini, D. H.; Evans, H. A.; Hebert, C. A.; Smock, S. R.; Hu, J.; Wang, H.; Zwanziger, J. W.; Chabinyc, M. L.; Seshadri, R. Chem. Mater. 2015, 27, 7137. doi: 10.1021/acs.chemmater.5b03147
55. [55]
  (55) Park, B. W.; Philippe, B.; Zhang, X.; Rensmo, H.; Boschloo, G.; Johansson, E. M. J. Adv. Mater. 2015, 27, 6806. doi: 10.1002/adma.201501978
56. [56]
  (56) Saparov, B.; Hong, F.; Sun, J. P.; Duan, H. S.; Meng, W. W.; Cameron, S.; Hill, I. G.; Yan, Y. F.; Mitzi, D. B. Chem. Mater. 2015, 27, 5622. doi: 10.1021/acs.chemmater.5b01989
57. [57]
  (57) Kim, Y.; Yang, Z.; Jain, A.; Voznyy, O.; Kim, G. H.; Liu, M.; Quan, L.N.; de Arquer, F. P. G.; Comin, R.; Fan, J. Z.; Sargent, E. H. Angew. Chem. Int. Ed. 2016, 55, 9585. doi: 10.1002/anie.201603608
58. [58]
  (58) Xiao, Z.; Meng, W.; Mitzi, D. B.; Yan, Y. J. Phys. Chem. Lett. 2016, 7, 3903. doi: 10.1021/acs.jpclett.6b01834
59. [59]
  (59) Johansson, M. B.; Zhu, H.; Johansson, E. M. J. J. Phys. Chem. Lett. 2016, 7, 3467. doi: 10.1021/acs.jpclett.6b01452

扫一扫看文章

计量

PDF下载量: 12
文章访问数: 1073
HTML全文浏览量: 199

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

无机非铅钙钛矿太阳能电池研究进展

English

Progress on the Development of Inorganic Lead-Free Perovskite Solar Cells

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

无机非铅钙钛矿太阳能电池研究进展

English

Progress on the Development of Inorganic Lead-Free Perovskite Solar Cells

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs