钙钛矿结构荧光材料MZrO3:Eu3+,A (M=Ca2+, Ba2+; A=Li+, Na+, K+) 的制备及其发光性质

引用本文: MARÍ B., CEMBRERO-COCA P., SINGH K. C., KAUSHIK R. D., OM Hari. 钙钛矿结构荧光材料MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) 的制备及其发光性质[J]. 物理化学学报, 2013, 29(06): 1357-1362. doi: 10.3866/PKU.WHXB201304032 shu

Citation: MARÍ B., CEMBRERO-COCA P., SINGH K. C., KAUSHIK R. D., OM Hari. Preparation and Luminescence Properties of MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) Phosphors with Perovskite Structure[J]. Acta Physico-Chimica Sinica, 2013, 29(06): 1357-1362. doi: 10.3866/PKU.WHXB201304032 shu

钙钛矿结构荧光材料MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) 的制备及其发光性质

基金项目:
The project was supported by the Spanish vernment through MCINN (MAT2009-14625-C03-03) (MAT2009-14625-C03-03)

European Commission through Nano CISproject (FP7-PEOPLE-2010-IRSES ref. 269279). (FP7-PEOPLE-2010-IRSES ref. 269279)

摘要:

Calcium and barium zirconate powders based upon CaZrO₃:Eu³⁺,A and BaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) were prepared by combustion synthesis method and heating to ~1000℃ to improve crystallinity.The structure and morphology of materials were examined by X-ray diffraction (XRD) and scanningelectron microscopy (SEM). XRD results showed that CaZrO₃:Eu³⁺,A and BaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) perovskites possessed orthorhombic and cubic structures, respectively. The morphologies of all powderswere very similar consisting of small, coagulated, cubical particles with narrow size distributions andsmooth and regular surfaces. The characteristic luminescences of Eu³⁺ ions in CaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) lattices were present with strong emissions at 614 and 625 nm for ⁵D₀→⁷F₂ transitions with other weakeremissions observed at 575, 592, 655, and 701 nm corresponding to ⁵D₀→⁷F_n transitions (where n=0, 1, 3, 4 respectively). In BaZrO₃:Eu³⁺ both the ⁵D₀→⁷F₁ and ⁵D₀→⁷F₂ transitions at 595 and 613 nm were strong.Photoluminescence intensities of CaZrO₃:Eu³⁺ samples were higher than those of BaZrO₃:Eu³⁺ lattices. Thisremarkable increase of photoluminescence intensity (corresponding to ⁵D₀→⁷F_n transitions) was observedin CaZrO₃:Eu³⁺ and BaZrO₃:Eu³⁺ if co-doped with Li⁺ ions. An additional broad band composed of manypeaks between 440 to 575 nm was observed in BaZrO₃:Eu³⁺,,A samples. The intensity of this band wasgreatest in Li⁺ co-doped samples and lowest for K⁺ doped samples.

关键词:

CaZrO₃:Eu³⁺, A and BaZrO₃:Eu³⁺, A (A=Li⁺, Na⁺, K⁺)
/ Charge compensator
/ Combustionsynthesis
/ Photoluminescence

English

Preparation and Luminescence Properties of MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) Phosphors with Perovskite Structure

1.
1 Institut de Disseny per la Fabricació Automatitzada (IDF)-Departament de Física Aplicada, Universitat Politècnica de València, Camí de Vera s/n, 46022 València, Spain;
2 Department of Chemistry, Maharshi Dayanand University, Rohtak 124001, Haryana, India;
3 Department of Chemistry, Gurukul Kangari University, Haridwar-249404, Uttarakhand, India
Received Date: 27 December 2012
Available Online: 17 May 2013
Fund Project:
The project was supported by the Spanish vernment through MCINN (MAT2009-14625-C03-03)

European Commission through Nano CISproject (FP7-PEOPLE-2010-IRSES ref. 269279).

Abstract:

Calcium and barium zirconate powders based upon CaZrO₃:Eu³⁺,A and BaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) were prepared by combustion synthesis method and heating to ~1000℃ to improve crystallinity. The structure and morphology of materials were examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD results showed that CaZrO₃:Eu³⁺,A and BaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) perovskites possessed orthorhombic and cubic structures, respectively. The morphologies of all powders were very similar consisting of small, coagulated, cubical particles with narrow size distributions and smooth and regular surfaces. The characteristic luminescences of Eu³⁺ ions in CaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) lattices were present with strong emissions at 614 and 625 nm for ⁵D₀→⁷F₂ transitions with other weaker emissions observed at 575, 592, 655, and 701 nm corresponding to ⁵D₀→⁷F_n transitions (where n=0, 1, 3, 4 respectively). In BaZrO₃:Eu³⁺ both the ⁵D₀→⁷F₁ and ⁵D₀→⁷F₂ transitions at 595 and 613 nm were strong. Photoluminescence intensities of CaZrO₃:Eu³⁺ samples were higher than those of BaZrO₃:Eu³⁺ lattices. This remarkable increase of photoluminescence intensity (corresponding to ⁵D₀→⁷F_n transitions) was observed in CaZrO₃:Eu³⁺ and BaZrO₃:Eu³⁺ if co-doped with Li⁺ ions. An additional broad band composed of many peaks between 440 to 575 nm was observed in BaZrO₃:Eu³⁺,,A samples. The intensity of this band was greatest in Li⁺ co-doped samples and lowest for K⁺ doped samples.

Key words:

CaZrO₃:Eu³⁺, A and BaZrO₃:Eu³⁺, A (A=Li⁺, Na⁺, K⁺)
/ Charge compensator
/ Combustion synthesis
/ Photoluminescence

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

钙钛矿结构荧光材料MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) 的制备及其发光性质

English

Preparation and Luminescence Properties of MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) Phosphors with Perovskite Structure

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