CNTs表面改性与TiO<sub>2</sub>-CNTs异质结光催化性能

引用本文: 杨汉培, 张颖超, 傅小飞, 宋双双, 吴俊明. CNTs表面改性与TiO₂-CNTs异质结光催化性能[J]. 物理化学学报, 2013, 29(06): 1327-1335. doi: 10.3866/PKU.WHXB201303212 shu

Citation: YANG Han-Pei, ZHANG Ying-Chao, FU Xiao-Fei, SONG Shuang-Shuang, WU Jun-Ming. Surface Modification of CNTs and Improved Photocatalytic Activity of TiO₂-CNTs Heterojunction[J]. Acta Physico-Chimica Sinica, 2013, 29(06): 1327-1335. doi: 10.3866/PKU.WHXB201303212 shu

CNTs表面改性与TiO₂-CNTs异质结光催化性能

基金项目:
教育部留学归国人员基金(20071256)资助项目 (20071256)

摘要:

碳纳米管(CNTs)混酸(H₂SO₄/HNO₃, 体积比为3:1)超声辅助纯化及氧化植入活性基团－COOH, 进一步借助其转化为酰氯基团, 分别于CNTs 表面共价嫁接亲水性赖氨酸及亲脂性正十八胺基团, 赋予赖氨酸表面改性CNTs 显著水溶(6.85 mg·mL-1)和十八胺表面改性CNTs 显著醇溶(10.15 mg·mL^-1)性能. 运用低温水热法以亲水性CNTs 复合TiO₂, 溶胶-凝胶法以亲脂性CNTs 复合TiO₂, 观察到复合催化剂光催化性能随CNTs 溶剂分散性能增加而明显提升. 运用傅里叶变换红外(FTIR)、激光拉曼、X射线衍射(XRD)、Brunauer-Emmett-Teller 低温氮气吸附、透射电镜(TEM)及X光电子能谱(XPS)等手段表征, 系统探讨CNTs 的表面改性机制及CNTs 溶解分散性能与复合催化剂的光活性的关联. 认为表面改性CNTs 借助Ti－O－C键合促进其与纳米TiO₂的异质结合, 从而充分利用CNTs的大比表面积及电荷传输性能促进催化剂的污染物光催化降解.

关键词:

English

Surface Modification of CNTs and Improved Photocatalytic Activity of TiO₂-CNTs Heterojunction

1.
Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098, P.R.China
Received Date: 25 January 2013
Available Online: 17 May 2013
Fund Project:
教育部留学归国人员基金(20071256)资助项目

Abstract:

Carbon nanotubes (CNTs) have been ultrasonically treated with the mixed acid (H₂SO₄/HNO₃, 3:1, volume ratio), embedding the active －COOH groups onto the surface of the CNTs. As a result, the acid-treated CNTs serve as chemical reactors for subsequent grafting of L-lysine or octadecylamine (ODA). It was revealed that L-lysine and ODA covalently bond to the surface of the oxidized CNTs through amidation of carboxylic acid groups (CNTs-COOH) and lysine or ODA via intermediate acyl chlorides (CNTs-COCl). The hydrophilic and lipophilic CNTs have high aquatic and ethanol solubility, and the solubility of the surface modified CNTs in water and ethanol were measured to be as high as 6.85 and 10.15 mg·mL^-1, respectively. The surface nature of modified CNTs and the properties of TiO₂-CNTs composite photocatalysts, which were prepared through sol-gel or low temperature hydrothermal synthesis, were investigated by Fourier transform infrared (FTIR), laser Raman, X-ray diffraction (XRD), Brunauer-Emmett-Teller N2 adsorption, transmission electron microscopy (TEM), and X-ray photoelectron spectrum (XPS). Improved photocatalytic performance was observed for TiO₂ coupled by hydrophilic or lipophilic CNT, which were obtained by low temperature hydrothermal and sol-gel synthesis, respectively, and it was revealed that there is an affinity between the photocatalytic performance of TiO₂-CNTs hybrids and the dispersibility of CNTs. It is proposed that the improved photocatalytic activity of CNT-TiO₂ compared with pure TiO₂ photocatalysts can be mainly attributed to the homogeneous and dense dispersion of TiO₂ on the modified CNTs and the intimate contact between TiO₂ and CNTs, which results in dense heterojunctions at the interface of TiO₂ and CNTs through the Ti－O－C structure.

Key words:

1. [1]
  
  (1) Hu, L. B.; Hecht, D. S.; Gruner, G. Chem. Rev. 2010, 110, 5790.doi: 10.1021/cr9002962
  (1) Hu, L. B.; Hecht, D. S.; Gruner, G. Chem. Rev. 2010, 110, 5790.doi: 10.1021/cr9002962
2. [2]
  (2) Wu, Y. C.; Liu, X. L.; Ye, M.; Xie, T.; Huang, X. M. Acta Phys. - Chim. Sin. 2008, 24, 97. [吴玉程, 刘晓璐, 叶敏, 解挺,黄新民. 物理化学学报, 2008, 24, 97.] doi: 10.3866/PKU.WHXB20080117(2) Wu, Y. C.; Liu, X. L.; Ye, M.; Xie, T.; Huang, X. M. Acta Phys. - Chim. Sin. 2008, 24, 97. [吴玉程, 刘晓璐, 叶敏, 解挺,黄新民. 物理化学学报, 2008, 24, 97.] doi: 10.3866/PKU.WHXB20080117
3. [3]
  (3) Zhang, K.; Zhang, F.; Chen, M.; Oh,W. Ultrason. Sonochem.2011, 18, 765. doi: 10.1016/j.ultsonch.2010.11.008(3) Zhang, K.; Zhang, F.; Chen, M.; Oh,W. Ultrason. Sonochem.2011, 18, 765. doi: 10.1016/j.ultsonch.2010.11.008
4. [4]
  (4) Barkauskasa, J.; Stankeviciene, I.; Selskis, A. Sep. Purif. Technol. 2010, 71, 331. doi: 10.1016/j.seppur.2009.12.019(4) Barkauskasa, J.; Stankeviciene, I.; Selskis, A. Sep. Purif. Technol. 2010, 71, 331. doi: 10.1016/j.seppur.2009.12.019
5. [5]
  (5) Stobinski, L.; Lesiak, B.; Kövér, L. J. Alloy. Compd. 2010, 501,77. doi: 10.1016/j.jallcom.2010.04.032(5) Stobinski, L.; Lesiak, B.; Kövér, L. J. Alloy. Compd. 2010, 501,77. doi: 10.1016/j.jallcom.2010.04.032
6. [6]
  (6) Tian, R.;Wang, X.; Li, M.; Hu, H. Appl. Surf. Sci. 2008, 255,3294. doi: 10.1016/j.apsusc.2008.09.040(6) Tian, R.;Wang, X.; Li, M.; Hu, H. Appl. Surf. Sci. 2008, 255,3294. doi: 10.1016/j.apsusc.2008.09.040
7. [7]
  (7) Dyke, C. A.; Stewart, M. P.; Tour, J. M. J. Am. Chem. Soc. 2005,127, 4497. doi: 10.21/ja042828h(7) Dyke, C. A.; Stewart, M. P.; Tour, J. M. J. Am. Chem. Soc. 2005,127, 4497. doi: 10.21/ja042828h
8. [8]
  (8) Zeng, L.; Zhang, L.; Barron, A. R. Nano Lett. 2005, 5, 2001.doi: 10.1021/nl0514994(8) Zeng, L.; Zhang, L.; Barron, A. R. Nano Lett. 2005, 5, 2001.doi: 10.1021/nl0514994
9. [9]
  (9) Balasubramanian, K.; Burghard, M. Small 2005, 1, 180.(9) Balasubramanian, K.; Burghard, M. Small 2005, 1, 180.
10. [10]
  (10) Ye, Q.; Zhang, Y.; Li, M.; Shi, Y. Acta Phys. -Chim. Sin. 2012,28, 1223. [叶青, 张瑜, 李茗, 施耀. 物理化学学报,2012, 28, 1223.] doi: 10.3866/PKU.WHXB201202234(10) Ye, Q.; Zhang, Y.; Li, M.; Shi, Y. Acta Phys. -Chim. Sin. 2012,28, 1223. [叶青, 张瑜, 李茗, 施耀. 物理化学学报,2012, 28, 1223.] doi: 10.3866/PKU.WHXB201202234
11. [11]
  (11) Mugadza, T.; Nyokong, T. Electrochim. Acta 2010, 55, 2606.doi: 10.1016/j.electacta.2009.12.051(11) Mugadza, T.; Nyokong, T. Electrochim. Acta 2010, 55, 2606.doi: 10.1016/j.electacta.2009.12.051
12. [12]
  (12) Mugadza, T.; Nyokong, T. Synth. Met. 2010, 160, 2089.doi: 10.1016/j.synthmet.2010.07.036(12) Mugadza, T.; Nyokong, T. Synth. Met. 2010, 160, 2089.doi: 10.1016/j.synthmet.2010.07.036
13. [13]
  (13) Wei, T.; Fan, Z.; Luo, G.;Wei, F. Mater. Lett. 2008, 62, 64.(13) Wei, T.; Fan, Z.; Luo, G.;Wei, F. Mater. Lett. 2008, 62, 64.
14. [14]
  (14) Chen, Y.; Zhang, Y. Q.; Zhang, T. H. Carbon 2006, 44, 37.doi: 10.1016/j.carbon.2005.07.011(14) Chen, Y.; Zhang, Y. Q.; Zhang, T. H. Carbon 2006, 44, 37.doi: 10.1016/j.carbon.2005.07.011
15. [15]
  (15) Mills, A.; Hunte, S. L. J. Photochem. Photobiol. A: Chem. 1997,108, l.(15) Mills, A.; Hunte, S. L. J. Photochem. Photobiol. A: Chem. 1997,108, l.
16. [16]
  (16) Qiu,W.; Ren, C. J.; ng, M. C.; Hou, Y. Z.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2011, 27, 1487. [仇伟, 任成军, 龚茂初,侯云泽, 陈耀强. 物理化学学报, 2011, 27, 1487.] doi: 10.3866/PKU.WHXB20110621(16) Qiu,W.; Ren, C. J.; ng, M. C.; Hou, Y. Z.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2011, 27, 1487. [仇伟, 任成军, 龚茂初,侯云泽, 陈耀强. 物理化学学报, 2011, 27, 1487.] doi: 10.3866/PKU.WHXB20110621
17. [17]
  (17) Wang, H.;Wang, H. L.; Jiang,W. F.; Li, Z. Q. Water Res. 2009,43, 204. doi: 10.1016/j.watres.2008.10.003(17) Wang, H.;Wang, H. L.; Jiang,W. F.; Li, Z. Q. Water Res. 2009,43, 204. doi: 10.1016/j.watres.2008.10.003
18. [18]
  (18) Wang,W.; Serp, P.; Kalck, P.; Faria, J. L. Appl. Catal. B: Environ. 2005, 56, 305. doi: 10.1016/j.apcatb.2004.09.018(18) Wang,W.; Serp, P.; Kalck, P.; Faria, J. L. Appl. Catal. B: Environ. 2005, 56, 305. doi: 10.1016/j.apcatb.2004.09.018
19. [19]
  (19) Suzuki, Y.; Yoshikawa, S. J. Mater. Res. 2004, 19, 982.doi: 10.1557/JMR.2004.0128(19) Suzuki, Y.; Yoshikawa, S. J. Mater. Res. 2004, 19, 982.doi: 10.1557/JMR.2004.0128
20. [20]
  (20) Yang, H. P.; Shi, Z. M.; Dai, K. J.; Duan, Y. P.;Wu, J. M. Acta Chim. Sin. 2011, 69, 536. [杨汉培, 石泽敏, 戴开静, 段云平,吴俊明. 化学学报, 2011, 69, 536.](20) Yang, H. P.; Shi, Z. M.; Dai, K. J.; Duan, Y. P.;Wu, J. M. Acta Chim. Sin. 2011, 69, 536. [杨汉培, 石泽敏, 戴开静, 段云平,吴俊明. 化学学报, 2011, 69, 536.]
21. [21]
  (21) Sun, J. H.; Qiao, L. P.; Sun, S. P.;Wang, G. L. J. Hazard Mater.2008, 155, 312. doi: 10.1016/j.jhazmat.2007.11.062(21) Sun, J. H.; Qiao, L. P.; Sun, S. P.;Wang, G. L. J. Hazard Mater.2008, 155, 312. doi: 10.1016/j.jhazmat.2007.11.062
22. [22]
  (22) Maiyalagan, T.; Viswanathan, B. Mater. Chem. Phys. 2005, 93,291. doi: 10.1016/j.matchemphys.2005.03.039(22) Maiyalagan, T.; Viswanathan, B. Mater. Chem. Phys. 2005, 93,291. doi: 10.1016/j.matchemphys.2005.03.039
23. [23]
  (23) Kim, S. D.; Kim, J.W.; Im, J. S. J. Fluorine Chem. 2007, 128,60. doi: 10.1016/j.jfluchem.2006.10.010(23) Kim, S. D.; Kim, J.W.; Im, J. S. J. Fluorine Chem. 2007, 128,60. doi: 10.1016/j.jfluchem.2006.10.010
24. [24]
  (24) Osorio, A. G.; Silveira, I. C. L.; Bueno, V. L. Appl. Surf. Sci.2008, 255, 2485. doi: 10.1016/j.apsusc.2008.07.144(24) Osorio, A. G.; Silveira, I. C. L.; Bueno, V. L. Appl. Surf. Sci.2008, 255, 2485. doi: 10.1016/j.apsusc.2008.07.144
25. [25]
  (25) Yang, Y. S.; Qi, G. R.; Qian, J.W.; Yang, S. L. J. Appl. Polym. Sci. 1998, 68, 665.(25) Yang, Y. S.; Qi, G. R.; Qian, J.W.; Yang, S. L. J. Appl. Polym. Sci. 1998, 68, 665.
26. [26]
  (26) Hannus, I.; Kollár, T.; Kónya, Z.; Kiricsi, I. Vib. Spectrosc.2000, 22, 29. doi: 10.1016/S0924-2031(99)00059-4(26) Hannus, I.; Kollár, T.; Kónya, Z.; Kiricsi, I. Vib. Spectrosc.2000, 22, 29. doi: 10.1016/S0924-2031(99)00059-4
27. [27]
  (27) Ba, C. Y.; Economy, J. J. Memb. Sci. 2010, 363, 140.doi: 10.1016/j.memsci.2010.07.019(27) Ba, C. Y.; Economy, J. J. Memb. Sci. 2010, 363, 140.doi: 10.1016/j.memsci.2010.07.019
28. [28]
  (28) Peter, J.; Khalyavina, A.; Kǐí?, J.; Bleha, M. Eur. Polym. J.2009, 45, 1716. doi: 10.1016/j.eurpolymj.2009.03.003(28) Peter, J.; Khalyavina, A.; Kǐí?, J.; Bleha, M. Eur. Polym. J.2009, 45, 1716. doi: 10.1016/j.eurpolymj.2009.03.003
29. [29]
  (29) Svatos, A.; Attygalle, A. B. Anal. Chem. 1997, 69, 1827.doi: 10.1021/ac960890u(29) Svatos, A.; Attygalle, A. B. Anal. Chem. 1997, 69, 1827.doi: 10.1021/ac960890u
30. [30]
  (30) Xu, M.; Huang, Q.; Chen, Q.; Guo, P.; Sun, Z. Chem. Phys. Lett.2003, 375, 598. doi: 10.1016/S0009-2614(03)00923-0(30) Xu, M.; Huang, Q.; Chen, Q.; Guo, P.; Sun, Z. Chem. Phys. Lett.2003, 375, 598. doi: 10.1016/S0009-2614(03)00923-0
31. [31]
  (31) Okabayashi, H.; Etori, H.; Yamada, Y.; Taga, K.; Yoshida, T.Vib. Spectrosc. 1996, 13, 51. doi: 10.1016/0924-2031(96)00034-3(31) Okabayashi, H.; Etori, H.; Yamada, Y.; Taga, K.; Yoshida, T.Vib. Spectrosc. 1996, 13, 51. doi: 10.1016/0924-2031(96)00034-3
32. [32]
  (32) Venkataraman, N. V.; Barman, S.; Vasudevan, S.; Seshadri, R.Chem. Phys. Lett. 2002, 358, 139. doi: 10.1016/S0009-2614(02)00604-8(32) Venkataraman, N. V.; Barman, S.; Vasudevan, S.; Seshadri, R.Chem. Phys. Lett. 2002, 358, 139. doi: 10.1016/S0009-2614(02)00604-8
33. [33]
  (33) Georgiev, A.; Karamancheva, I.; Dimov, D. J. Mol. Struct. 2008,888, 214. doi: 10.1016/j.molstruc.2007.12.006(33) Georgiev, A.; Karamancheva, I.; Dimov, D. J. Mol. Struct. 2008,888, 214. doi: 10.1016/j.molstruc.2007.12.006
34. [34]
  (34) Zhao, X. A.; Ong, C.W.; Tsang, Y. C. Appl. Phys. Lett. 1995,66, 2652. doi: 10.1063/1.113114(34) Zhao, X. A.; Ong, C.W.; Tsang, Y. C. Appl. Phys. Lett. 1995,66, 2652. doi: 10.1063/1.113114
35. [35]
  (35) Choi, S.; Park, K. H.; Lee, S.; Koh, K. H. J. Appl. Phys. 2002,92, 4007. doi: 10.1063/1.1499233(35) Choi, S.; Park, K. H.; Lee, S.; Koh, K. H. J. Appl. Phys. 2002,92, 4007. doi: 10.1063/1.1499233
36. [36]
  (36) Hou, P. X.; Liu, C.; Cheng, H. M. Carbon 2008, 46, 2003.doi: 10.1016/j.carbon.2008.09.009(36) Hou, P. X.; Liu, C.; Cheng, H. M. Carbon 2008, 46, 2003.doi: 10.1016/j.carbon.2008.09.009
37. [37]
  (37) Fernando, K. A. S.; Lin, Y.; Sun, Y. P. Langmuir 2004, 20, 4777.doi: 10.1021/la036217z(37) Fernando, K. A. S.; Lin, Y.; Sun, Y. P. Langmuir 2004, 20, 4777.doi: 10.1021/la036217z
38. [38]
  (38) Wang,W. D.; Serp, P.; Kalck, P.; Faria, J. L. J. Molec. Catal. A2005, 235, 194. doi: 10.1016/j.molcata.2005.02.027(38) Wang,W. D.; Serp, P.; Kalck, P.; Faria, J. L. J. Molec. Catal. A2005, 235, 194. doi: 10.1016/j.molcata.2005.02.027
39. [39]
  (39) Klug, H. P.; Alexander, L. E. X-ray Diffraction Procedures;Academic Press: New York, 1967; pp 132-136.(39) Klug, H. P.; Alexander, L. E. X-ray Diffraction Procedures;Academic Press: New York, 1967; pp 132-136.
40. [40]
  (40) Lee, S.W.; Sigmund,W. M. Chem. Commun. 2003, 6, 780.(40) Lee, S.W.; Sigmund,W. M. Chem. Commun. 2003, 6, 780.
41. [41]
  (41) Yu, Y.; Yu, J. C.; Yu, J. G.; Kwok, Y. C.; Che, Y. K.; Zhao, J. C.;Ding, L.; Ge,W. K.;Wong, P. K. Appl. Catal. A: Gen. 2005,289, 186. doi: 10.1016/j.apcata.2005.04.057(41) Yu, Y.; Yu, J. C.; Yu, J. G.; Kwok, Y. C.; Che, Y. K.; Zhao, J. C.;Ding, L.; Ge,W. K.;Wong, P. K. Appl. Catal. A: Gen. 2005,289, 186. doi: 10.1016/j.apcata.2005.04.057
42. [42]
  (42) Yu, H.; Quan, X.; Chen, S.; Zhao, H. J. Phys. Chem. C 2007,111, 12987. doi: 10.1021/jp0728454(42) Yu, H.; Quan, X.; Chen, S.; Zhao, H. J. Phys. Chem. C 2007,111, 12987. doi: 10.1021/jp0728454
43. [43]
  (43) Akhavan, O.; Abdolahad, M.; Abdi, Y.; Mohajerzadeh, S.Carbon 2009, 47, 3280. doi: 10.1016/j.carbon.2009.07.046(43) Akhavan, O.; Abdolahad, M.; Abdi, Y.; Mohajerzadeh, S.Carbon 2009, 47, 3280. doi: 10.1016/j.carbon.2009.07.046
44. [44]
  (44) Tian, L. H.; Ye, L. Q.; Deng, K. J.; Zan, J. Solid State Chem.2011, 184, 1465. doi: 10.1016/j.jssc.2011.04.014(44) Tian, L. H.; Ye, L. Q.; Deng, K. J.; Zan, J. Solid State Chem.2011, 184, 1465. doi: 10.1016/j.jssc.2011.04.014
45. [45]
  (45) Chen, L. C.; Ho, Y. C.; Guo,W. S.; Huang, C. M.; Pan, T. C.Electrochimica Acta 2009, 54, 3884. doi: 10.1016/j.electacta.2009.02.001(45) Chen, L. C.; Ho, Y. C.; Guo,W. S.; Huang, C. M.; Pan, T. C.Electrochimica Acta 2009, 54, 3884. doi: 10.1016/j.electacta.2009.02.001
46. [46]
  (46) Nahar, M. S.; Zhang, J.; Hasegawa, K. Mater. Sci. Semicond. Process 2009, 12, 168. doi: 10.1016/j.mssp.2009.09.011(46) Nahar, M. S.; Zhang, J.; Hasegawa, K. Mater. Sci. Semicond. Process 2009, 12, 168. doi: 10.1016/j.mssp.2009.09.011
47. [47]
  (47) Yang, J.; Bai, H.; Tan, X.; Lian, J. Appl. Sur. Sci. 2006, 253,1988. doi: 10.1016/j.apsusc.2006.03.078(47) Yang, J.; Bai, H.; Tan, X.; Lian, J. Appl. Sur. Sci. 2006, 253,1988. doi: 10.1016/j.apsusc.2006.03.078
48. [48]
  (48) Song, Z.; Hrbek, J.; Os od, R. Nano Lett. 2005, 5, 1327.doi: 10.1021/nl0505703(48) Song, Z.; Hrbek, J.; Os od, R. Nano Lett. 2005, 5, 1327.doi: 10.1021/nl0505703
49. [49]
  (49) Jitianu, A.; Cacciaguerra, T.; Benoit, R.; Delpeux, S.; Beguin,F.; Bonnamy S. Carbon 2004, 42, 1147.(49) Jitianu, A.; Cacciaguerra, T.; Benoit, R.; Delpeux, S.; Beguin,F.; Bonnamy S. Carbon 2004, 42, 1147.
50. [50]
  (50) Shanmugharaj, A. M.; Bae, J. H.; Lee, K. Y.; Noh,W. H.Compos. Sci. Technol. 2007, 67, 1813. doi: 10.1016/j.compscitech.2006.10.021(50) Shanmugharaj, A. M.; Bae, J. H.; Lee, K. Y.; Noh,W. H.Compos. Sci. Technol. 2007, 67, 1813. doi: 10.1016/j.compscitech.2006.10.021
51. [51]
  (51) Kim, S. D.; Kim, J.W.; Im, J. S.; Kim, Y. H.; Lee, Y. S.J. Fluorine Chem. 2007, 128, 60. doi: 10.1016/j.jfluchem.2006.10.010
  (51) Kim, S. D.; Kim, J.W.; Im, J. S.; Kim, Y. H.; Lee, Y. S.J. Fluorine Chem. 2007, 128, 60. doi: 10.1016/j.jfluchem.2006.10.010

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沈阳化工大学材料科学与工程学院沈阳 110142

CNTs表面改性与TiO₂-CNTs异质结光催化性能

English

Surface Modification of CNTs and Improved Photocatalytic Activity of TiO₂-CNTs Heterojunction

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CNTs表面改性与TiO2-CNTs异质结光催化性能

English

Surface Modification of CNTs and Improved Photocatalytic Activity of TiO2-CNTs Heterojunction

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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中国化学会秘书处

CNTs表面改性与TiO₂-CNTs异质结光催化性能

Surface Modification of CNTs and Improved Photocatalytic Activity of TiO₂-CNTs Heterojunction

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs