引用本文:
曹立新, 周保学, 史鹏飞, 邹立壮. KBPh4由水到系列水-醇混合溶剂的迁移自由能[J]. 物理化学学报,
2001, 17(06): 565-569.
doi:
10.3866/PKU.WHXB20010619
Citation: Cao Li-Xin, Zhou Bao-Xue, Shi Peng-Fei, Zhou Li-Zhuang. Systematic Study of the Standard Transfer Gibbs Energy of Potassium Tetrophenylb orate from Water to Water and Alcohol Mixtures[J]. Acta Physico-Chimica Sinica, 2001, 17(06): 565-569. doi: 10.3866/PKU.WHXB20010619
Citation: Cao Li-Xin, Zhou Bao-Xue, Shi Peng-Fei, Zhou Li-Zhuang. Systematic Study of the Standard Transfer Gibbs Energy of Potassium Tetrophenylb orate from Water to Water and Alcohol Mixtures[J]. Acta Physico-Chimica Sinica, 2001, 17(06): 565-569. doi: 10.3866/PKU.WHXB20010619
KBPh4由水到系列水-醇混合溶剂的迁移自由能
English
Systematic Study of the Standard Transfer Gibbs Energy of Potassium Tetrophenylb orate from Water to Water and Alcohol Mixtures
Abstract:
The standard transfer Gibbs energies (ΔtrG°)of KBPh4 from reference solvent of water to water/ethanol, water/propanol, water/2
propanol,water/ethylene glycol, water/glycerol mixtures in different proportional ratio have been studied. The interactions of KBPh4 with the above mixed solvents were analyzed. The standard transfer Gibbs energy of cavity(ΔtrG°cav) and the standard transfer Gibbs energy of interaction(ΔtrG° int) from water to water/2propanol mixtu res at 298.15 K were calculated by the Scaled Particle Theory (SPT).
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