引用本文:
石磊, 张小岗, 张喜丰, 杨冠英, 韩布兴, 闫海科. 混合超临界流体的密度及分子间相互作用[J]. 物理化学学报,
2000, 16(01): 31-35.
doi:
10.3866/PKU.WHXB20000107
Citation: Shi Lei, Zhang Xiao-Gang, Zhang Xi-Feng, Yang Guan-Ying, Han Bu-Xing, Yan Hai-Ke. Study of Molecular lnteraction in Mixed Supercritical Fluids by Molecular Simulation and Partial Molar Volume Measurement[J]. Acta Physico-Chimica Sinica, 2000, 16(01): 31-35. doi: 10.3866/PKU.WHXB20000107
Citation: Shi Lei, Zhang Xiao-Gang, Zhang Xi-Feng, Yang Guan-Ying, Han Bu-Xing, Yan Hai-Ke. Study of Molecular lnteraction in Mixed Supercritical Fluids by Molecular Simulation and Partial Molar Volume Measurement[J]. Acta Physico-Chimica Sinica, 2000, 16(01): 31-35. doi: 10.3866/PKU.WHXB20000107
混合超临界流体的密度及分子间相互作用
English
Study of Molecular lnteraction in Mixed Supercritical Fluids by Molecular Simulation and Partial Molar Volume Measurement
Abstract:
The densities of the mixtures of CO_2- n-pentane and CO_2- n-heptane were determined at 308.15 K under the pressure range from 7 to 12 MPa. The partial molar volumes of the solutes were calculated. Intermolecular interaction between CO_2 and the solutes was studied based on the partial molar volume data and Monte Carlo simulation.
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