Citation: Liu Tian-Qing, Guo Rong, Yu Wei-Li, Shen Ming. Diffusion Coefficient and Structure Properties of SDS/BA/H2O System[J]. Acta Physico-Chimica Sinica, 1997, 13(05): 401-406. doi: 10.3866/PKU.WHXB19970504
SDS/BA/H2O体系的扩散系数与结构特性
English
Diffusion Coefficient and Structure Properties of SDS/BA/H2O System
Micelle diffusion coefficient and diffusion activation energy of SDS/BA/H2O system are determined by electrochemical methods without any probe. The results show that L1 area is not a single O/W microemulsion, it consists of two small regions-O/W microemulsion and oil-water bicontinuous microemulsion,. The microemulsion exists in liquid drop in O/W microemulsion and in net-structure in oil-water bicontinuous microemulsion. The diffusion property is better and diffusion activation energy smaller in the former than in the latter.
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Key words:
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Cyclic voltammogram
- / Diffustion coefficient
- / Activation energy
- / Microemulsion
- / Micelle
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