引用本文:
黄荣彬, 刘朝阳, 赵剑虹, 林逢辰, 郑兰荪. 含IIIA或VA族杂原子的碳原子簇负离子的研究[J]. 物理化学学报,
1994, 10(04): 308-311.
doi:
10.3866/PKU.WHXB19940405
Citation: Huang Rong-Bin, Liu Zhao-Yang, Zhao Jian-Hong, Lin Feng-Chen, Zheng Lan-Sun. Studies of Carbon Cluster Anions with a Heteroatom of IIIA or VA Group[J]. Acta Physico-Chimica Sinica, 1994, 10(04): 308-311. doi: 10.3866/PKU.WHXB19940405
Citation: Huang Rong-Bin, Liu Zhao-Yang, Zhao Jian-Hong, Lin Feng-Chen, Zheng Lan-Sun. Studies of Carbon Cluster Anions with a Heteroatom of IIIA or VA Group[J]. Acta Physico-Chimica Sinica, 1994, 10(04): 308-311. doi: 10.3866/PKU.WHXB19940405
含IIIA或VA族杂原子的碳原子簇负离子的研究
English
Studies of Carbon Cluster Anions with a Heteroatom of IIIA or VA Group
Abstract:
A series of carbon cluster anions with a heteroatom have been generated on a home-made apparatus by laser abalation of appropriate samples. The heteroatom includes boron, aluminum, nitrogen, phosphorus or arsenic which is either a ⅢA or a VA group element. The recorded time-of-flight mass spectra show that stabilities of the cluster anions are affected by the composition of the heteroatom. The ⅢA group heteroatom tends to bind with even sizes of carbon atom and the VA group atom selects odd sizes. The even/odd alternation is attributed to the linear configuration of the cluster anions with the heteroatom at the end of the chain.
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Key words:
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Carbon cluster
- / Linear chain
- / Even/odd alternation
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