引用本文:
蒋湘顺, 梁春馀, 秦美洁. 邻苯二甲酸在异丙醇-水混合溶剂中电离热力学性质的研究[J]. 物理化学学报,
1991, 7(05): 627-631.
doi:
10.3866/PKU.WHXB19910523
Citation: Jiang Xiang-Shun, Liang Chun-Yu, Qin Mei-Jie. Study on Thermodynamics of the Dissociation of o-Phthalic Acid in Isopropanol-Water Solvent Mixtures[J]. Acta Physico-Chimica Sinica, 1991, 7(05): 627-631. doi: 10.3866/PKU.WHXB19910523
Citation: Jiang Xiang-Shun, Liang Chun-Yu, Qin Mei-Jie. Study on Thermodynamics of the Dissociation of o-Phthalic Acid in Isopropanol-Water Solvent Mixtures[J]. Acta Physico-Chimica Sinica, 1991, 7(05): 627-631. doi: 10.3866/PKU.WHXB19910523
邻苯二甲酸在异丙醇-水混合溶剂中电离热力学性质的研究
English
Study on Thermodynamics of the Dissociation of o-Phthalic Acid in Isopropanol-Water Solvent Mixtures
Abstract:
The first thermodynamic dissociation constants of o-phthalic acid were determined at five temperatures from 278.15 to 318.15 K in 10, 14.93 and 20 wt% isopropanol-water solvent mixtures, by precise e. m. f. measurements of hydrogen-silver chlorld electrodes in cells without liquid junction. On the basis of Pitzer's theory, the method of polynomial approximation was used to determine the dissociation constants of H_2P and the results obtained were compared with traditional extrapolation according to the extended Debye-Huckel equation Results obtained from both methods agree within experimental error. The dependence of the first thermodynamic dissociation constant on temperature was given as a function of the thermodynamic temperature T by the empirical equation: pK_1=A_0+A_1/T+A_2/T. The thermodynamic quantities of dissociation in the mixed solvents have been calculated, and the results have been discussed.
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