引用本文:
李海英, 郁章玉, 李春英, 顾登平. 用分光光度法研究[Fe(H2O)3(NCS)3](18-C-6)在微栅电极上的电化学性质[J]. 物理化学学报,
1990, 6(06): 735-738.
doi:
10.3866/PKU.WHXB19900619
Citation: Li Hai-Ying, Yu Zhang-Yu, Li Chun-Ying, Gu Deng-Ping. STUDIES ON THE ELECTROCHEMICAL BEHAVIORS OF [Fe(H2O)3(NCS)3] (18-C-6) ON MINIGRID ELECTRODE BY SPECTROPHOTOMETRY[J]. Acta Physico-Chimica Sinica, 1990, 6(06): 735-738. doi: 10.3866/PKU.WHXB19900619
Citation: Li Hai-Ying, Yu Zhang-Yu, Li Chun-Ying, Gu Deng-Ping. STUDIES ON THE ELECTROCHEMICAL BEHAVIORS OF [Fe(H2O)3(NCS)3] (18-C-6) ON MINIGRID ELECTRODE BY SPECTROPHOTOMETRY[J]. Acta Physico-Chimica Sinica, 1990, 6(06): 735-738. doi: 10.3866/PKU.WHXB19900619
用分光光度法研究[Fe(H2O)3(NCS)3](18-C-6)在微栅电极上的电化学性质
English
STUDIES ON THE ELECTROCHEMICAL BEHAVIORS OF [Fe(H2O)3(NCS)3] (18-C-6) ON MINIGRID ELECTRODE BY SPECTROPHOTOMETRY
Abstract:
The electrochemical reduction processes of [Fe(H_2O)_3(NCS)_3] (18-C-6) have been studied in nonaqueous media by method of cyclic voltammetry and spectroelec-trochemistry at an optical transparent thin layer electrode. The formal potential, E°′, electron transfer number, n, diffusion cofficient, D_O, formal heterogeneous electron transfer rate constant, k_S′, and electrochemical transfer coefficient, a, are deter-minated. Significant effect of solvents on the electrochemical behaviors has been observed. The higher the β, the higher the thermodynamic and kinetic stabilities of the coordination compound resulted.
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