引用本文:
刘树堂, 刘启旺, 吴秉芳, 索全伶, 胡襄, 王博义. Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2的合成和晶体结构[J]. 物理化学学报,
1990, 6(06): 730-734.
doi:
10.3866/PKU.WHXB19900618
Citation: Liu Shu-Tang, Liu Qi-Wang, Wu Bin-Fang, Suo Quan-Ling, Hu Xiang, Wang Be-Yi. SYNTHESIS AND CRYSTAL STRUCTURE OF Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2[J]. Acta Physico-Chimica Sinica, 1990, 6(06): 730-734. doi: 10.3866/PKU.WHXB19900618
Citation: Liu Shu-Tang, Liu Qi-Wang, Wu Bin-Fang, Suo Quan-Ling, Hu Xiang, Wang Be-Yi. SYNTHESIS AND CRYSTAL STRUCTURE OF Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2[J]. Acta Physico-Chimica Sinica, 1990, 6(06): 730-734. doi: 10.3866/PKU.WHXB19900618
Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2的合成和晶体结构
English
SYNTHESIS AND CRYSTAL STRUCTURE OF Fe3(CO)8[P[SC6H5)Cl2](μ3-S)2
Abstract:
The title compound Fe_3(CO)_8 (P(SC_6H_5) Cl_2) (μ_3′-S)_2 was synthesised by reacting Fe_3(CO)_9 (μ_3-S)_2 with P (SC_6H_5) Cl_2.
The crystal and molecular structure of the title compound has been determined by single crystal diffraction method. Crystal data: triclinic, space group P1, with a=0.7571(1), b=0.9097(1), c=1.7706(2) nm, α=95.03(1), β=101.79(1), γ=105.73(1)°, V =1.1359 nm, Z=2, Dc=1.935 g·cm~(-3). The structure was solved by direct method and difference Fourier synthesis, and refined by full-matrix least-squares with anisotropic thermal paramaters for non-hydrogen atoms, using 3724 observed reflections withI≥3σ(I). The final residual factor R=0.025, R_W=0.028.
Fe_(CO)_8(P(SC_6H_5)Cl_2)(μ_3-s)_2 has a face-bridged 4e donors and the monosubstituted ligand is on the apical Fe atom.
The crystal and molecular structure of the title compound has been determined by single crystal diffraction method. Crystal data: triclinic, space group P1, with a=0.7571(1), b=0.9097(1), c=1.7706(2) nm, α=95.03(1), β=101.79(1), γ=105.73(1)°, V =1.1359 nm, Z=2, Dc=1.935 g·cm~(-3). The structure was solved by direct method and difference Fourier synthesis, and refined by full-matrix least-squares with anisotropic thermal paramaters for non-hydrogen atoms, using 3724 observed reflections withI≥3σ(I). The final residual factor R=0.025, R_W=0.028.
Fe_(CO)_8(P(SC_6H_5)Cl_2)(μ_3-s)_2 has a face-bridged 4e donors and the monosubstituted ligand is on the apical Fe atom.
扫一扫看文章
计量
- PDF下载量: 1175
- 文章访问数: 2368
- HTML全文浏览量: 127
下载:
