引用本文:
程志华, 李涵, 张犁天, 杨家振, 梁春余. 在不同温度下Cu|CuSO4|Hg2SO4-Hg电池标准电动势的确定[J]. 物理化学学报,
1989, 5(05): 590-593.
doi:
10.3866/PKU.WHXB19890516
Citation: Cheng Zhihua*, Li Han, Zhang Litian, Yang Jiazhen, Liang Chunyu. THE DETERMINATION OF STANDARD ELECTROMOTIVE FORCE OF CELL Cu|CuSO4|Hg2SO4-Hg AT DIFFERENT TEMPERATURES[J]. Acta Physico-Chimica Sinica, 1989, 5(05): 590-593. doi: 10.3866/PKU.WHXB19890516
Citation: Cheng Zhihua*, Li Han, Zhang Litian, Yang Jiazhen, Liang Chunyu. THE DETERMINATION OF STANDARD ELECTROMOTIVE FORCE OF CELL Cu|CuSO4|Hg2SO4-Hg AT DIFFERENT TEMPERATURES[J]. Acta Physico-Chimica Sinica, 1989, 5(05): 590-593. doi: 10.3866/PKU.WHXB19890516
在不同温度下Cu|CuSO4|Hg2SO4-Hg电池标准电动势的确定
English
THE DETERMINATION OF STANDARD ELECTROMOTIVE FORCE OF CELL Cu|CuSO4|Hg2SO4-Hg AT DIFFERENT TEMPERATURES
Abstract:
The emfs of Cu|CuSO_4|Hg_2SO_4-Hg were determined at 5 temperature points from 278.15 K to 313.15 K. Based on the Pitzer' s Equation a polynomial approximation for the determination of standard emf, E_m, was proposed. The values of E_m obtained by author's method agree with values of E_m obtained by the extended Debye-Huckel equation within experimental errors. Compared with the extrapolation result of extended Debye-Huckel equation, the uncertainty by the selecting of parameter of ion size was avoided. By the use of polynomial approximation method the standard emf's for different type cells in the literature were also determinded. The results were more satisfactary.
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