<i>α</i>(<i>β</i>)-四苯氧基酞菁锌的合成、表征和发光性能

引用本文: 白青龙, 张春花, 程传辉, 李万程, 杜国同. α(β)-四苯氧基酞菁锌的合成、表征和发光性能[J]. 应用化学, 2012, 29(6): 643-648. doi: 10.3724/SP.J.1095.2012.00271 shu

Citation: BAI Qinglong, ZHANG Chunhua, CHENG Chuanhui, LI Wancheng, DU Guotong. Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc[J]. Chinese Journal of Applied Chemistry, 2012, 29(6): 643-648. doi: 10.3724/SP.J.1095.2012.00271 shu

α(β)-四苯氧基酞菁锌的合成、表征和发光性能

1.
a 内蒙古民族大学化学化工学院通辽 028043;
2.
b 大连理工大学物理与光电工程学院大连 116024;
3.
c 吉林大学电子科学与工程学院长春 130012

通讯作者: 程传辉,副教授;Tel/Fax:0411-84707865;E-mail:chengch79@yahoo.cn;研究方向:有机电致发光器件、太阳能电池和有机晶体管等

基金项目:
国家自然科学基金(60807009)资助项目 (60807009)

摘要: 以3(4)-硝基邻苯二腈和苯酚为原料,经过两步反应合成了α(β)-四苯氧基酞菁锌,通过红外光谱、紫外光谱、核磁共振谱、质谱和元素分析表征了其结构,比较研究其光谱性质。并以旋涂发光层的方法制备了电致发光器件,研究其电致发光性质。固态酞菁材料的光致发光波长红移到866~930 nm范围内的近红外波段,β-位取代酞菁发光波长红移的程度比α-位取代酞菁大。2种器件电致发光波长和酞菁固体材料的光致发光波长较接近,分别在880和885 nm处。

关键词:

English

Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc

1.
a College of Chemistry and Chemical Engineering, Inner Mongglia University for Nationalities, Tongliao 028043, China;
2.
b School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, China;
3.
c College of Electronic Science and Engineering, Jilin University, Changchun 130012, China

Corresponding author: 程传辉,副教授;Tel/Fax:0411-84707865;E-mail:chengch79@yahoo.cn;研究方向:有机电致发光器件、太阳能电池和有机晶体管等

Received Date: 22 June 2011
Fund Project:
国家自然科学基金(60807009)资助项目

Abstract: α(β)-tetra-phenoxy phthalocyaninato zinc complexes have been synthesized via a two-step process using 3(4)-nitrobenzene-1,2-dicarbonitrile and phenol as precursors.The products were characterized by means of IR spectrum,UV-Vis spectrum,¹H NMR spectrum,mass spectrum and elemental analysis.The UV-Vis spectra,photoluminescence spectra of spin-coated film and pressed solid pellet were compared.The fluorescences of both compressed and spin-coated samples had red-shifts larger than 161 nm compared to that obtained from solution.In addition,their fluorescence peaks are broader than that in solution.The fluorescence of β-substituted phthalocyanines has a greater red-shift than that of α-substituted phthalocyanines.The two kinds of fabricated devices showed similar electroluminescent spectra around 880 nm.

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

α(β)-四苯氧基酞菁锌的合成、表征和发光性能

通讯作者: 程传辉,副教授;Tel/Fax:0411-84707865;E-mail:chengch79@yahoo.cn;研究方向:有机电致发光器件、太阳能电池和有机晶体管等

English

Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc

Corresponding author: 程传辉,副教授;Tel/Fax:0411-84707865;E-mail:chengch79@yahoo.cn;研究方向:有机电致发光器件、太阳能电池和有机晶体管等

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

α(β)-四苯氧基酞菁锌的合成、表征和发光性能

通讯作者: 程传辉,副教授;Tel/Fax:0411-84707865;E-mail:chengch79@yahoo.cn;研究方向:有机电致发光器件、太阳能电池和有机晶体管等

English

Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc

Corresponding author: 程传辉,副教授;Tel/Fax:0411-84707865;E-mail:chengch79@yahoo.cn;研究方向:有机电致发光器件、太阳能电池和有机晶体管等

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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