钙钛矿氧化物结构分析及其电催化析氢反应研究进展

引用本文: 程雅娣, 高建雄, 王焕磊, 黄明华. 钙钛矿氧化物结构分析及其电催化析氢反应研究进展[J]. 分析化学, 2021, 49(6): 952-962. doi: 10.19756/j.issn.0253-3820.210452 shu

Citation: CHENG Ya-Di, GAO Jian-Xiong, WANG Huan-Lei, HUANG Ming-Hua. Structure Analysis of Perovskite Oxides and Research Progress on Their Electrocatalytic Hydrogen Evolution Reaction[J]. Chinese Journal of Analytical Chemistry, 2021, 49(6): 952-962. doi: 10.19756/j.issn.0253-3820.210452 shu

钙钛矿氧化物结构分析及其电催化析氢反应研究进展

1.
中国海洋大学材料科学与工程学院, 青岛 266100;
2.
中国科学院青岛生物能源与过程研究所, 青岛 266101

通讯作者: 黄明华,E-mail:huangminghua@ouc.edu.cn

基金项目:
国家自然科学基金项目（No.21775142）和中国科学院青岛生物能源与过程研究所和大连清洁能源国家实验室项目（No.DICP&QIBEBT UN201809）资助。

摘要: 电解水制氢具有操作简单、高效环保等优点，被认为是最具发展潜力的制氢方式，但通常需要施加较大的过电位才能达到工业电解水所需的电流密度。为了降低过电位，减少非必要的能量损失，亟需开发高性能、低成本的析氢反应（HER）电催化剂。钙钛矿材料储量丰富、价格低廉、结构灵活多变，已成为一类用于HER的新型非贵金属基电催化剂。本文首先对HER的基本机理进行了介绍，重点论述了钙钛矿氧化物在电催化HER领域的研究进展，讨论并分析了提升HER性能的策略（离子掺杂、异质结构构筑、形貌结构调控等），最后提出了钙钛矿型HER电催化剂所面临的挑战，并展望了其研究前景。

关键词:

English

Structure Analysis of Perovskite Oxides and Research Progress on Their Electrocatalytic Hydrogen Evolution Reaction

1.
School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China;
2.
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China

Corresponding author: HUANG Ming-Hua, huangminghua@ouc.edu.cn

Received Date: 21 April 2021
Revised Date: 14 May 2021
Fund Project:
Supported by the National Natural Science Foundation of China (No.21775142) and the QIBEBT and Dalian National Laboratory for Clean Energy, CAS (No.DICP&QIBEBT UN201809).

Abstract: Electrochemical water splitting, a highly-efficient and environment-friendly technology has been considered as one of the most promising methods for hydrogen production. However, a large overpotential is generally required to achieve the current density for industrial water electrolysis. As a result, it is highly desirable to develop high-performance and cost-effective hydrogen evolution reaction (HER) electrocatalysts for the widespread application of water splitting. Perovskite oxides have emerged as a new category of nonprecious metal catalysts for electrocatalytic HER due to their low cost, abundant compositions and flexible structures. In this review, the HER mechanism in alkaline environment is briefly elaborated. Then, the research progress of perovskite oxides in HER is reviewed. Moreover, the strategies (ion doping, heterostructure engineering, morphology and structure regulation, etc.) for promoting HER performance are discussed and analyzed. Finally, the remaining challenges faced by perovskite HER electrocatalysts and the future prospects are put forward.

Key words:

1. [1]
  CHU S, MAJUMDAR A. Nature, 2012, 488(7411): 294-303.
2. [2]
  HUA W, SUN H H, XU F, W J G. Rare Met., 2020, 39(4): 335-351.
3. [3]
  DAI J, ZHU Y L, TAHINI H A, LIN Q, CHEN Y, GUAN D Q, ZHOU C, HU Z W, LIN H J, CHAN T S, CHEN C T, SMITH S C, WANG H T, ZHOU W, SHAO Z P. Nat. Commun., 2020, 11(1): 5657.
4. [4]
  SEH Z W, KIBSGAARD J, DICKENS C F, CHORKENDORFF I, NORSKOV J K, JARAMILLO T F. Science, 2017, 355(6321): eaad4998.
5. [5]
  LIU Ye-Feng, ZHOU Ming-Jie. Chin. J. Power Sources, 2013, 37(7): 1171-1173, 1187. 刘业凤, 周明杰. 电源技术, 2013, 37(7): 1171-1173, 1187.
6. [6]
  ZHU Y L, ZHOU W, ZHONG Y J, BU Y F, CHEN X Y, ZHONG Q, LIU M L, SHAO Z P. Adv. Energy Mater., 2017, 7(8): 1602122.
7. [7]
  SUEN N T, HUNG S F, QUAN Q, ZHANG N, XU Y J, CHEN H M. Chem. Soc. Rev., 2017, 46(2): 337-365.
8. [8]
  ZHU Jing-Yi, LIANG Feng, YAO Yao-Chun, MA Wen-Hui, YANG Bin, DAI Yong-Nian. Chin. J. Rare Met., 2019, 43(2): 186-200. 朱静怡, 梁风, 姚耀春, 马文会, 杨斌, 戴永年. 稀有金属, 2019, 43(2): 186-200.
9. [9]
  LI X M, HAO X G, ABUDULA A, GUAN G Q. J. Mater. Chem. A, 2016, 4(31): 11973-12000.
10. [10]
  LEDENDECKER M, KRICK CALDERON S, PAPP C, STEINRUCK H P, ANTONIETTI M, SHALOM M. Angew. Chem., Int. Ed., 2015, 54(42): 12361-12365.
11. [11]
  LING T, YAN D Y, WANG H, JIAO Y, HU Z P, ZHENG Y, ZHENG L, MAO J R, LIU H, DU X W, JARONIEC M, QIAO S Z. Nat. Commun., 2017, 8: 1509.
12. [12]
  CHEN P Z, ZHOU T P, ZHANG M X, TONG Y, ZHONG C, ZHANG N, ZHANG L D, WU C Z, XIE Y. Adv. Mater., 2017, 29(30): 1701584.
13. [13]
  ZHANG Zhen, SHAO Xin, HUANG Ming-Hua. Chin. J. Anal. Chem., 2020, 48(6): 721-726. 张震, 邵鑫, 黄明华. 分析化学, 2020, 48(6): 721-726.
14. [14]
  HWANG J, RAO R R, GIORDANO L, KATAYAMA Y, YU Y, SHAO-HORN Y. Science, 2017, 358(6364): 751-756.
15. [15]
  GRIMAUD A, MAY K J, CARLTON C E, LEE Y L, RISCH M, HONG W T, ZHOU J G, SHAO-HORN Y. Nat. Commun., 2013, 4: 2439.
16. [16]
  SUN Q, DAI Z Y, ZHANG Z B, CHEN Z L, LIN H Q, GAO Y, CHEN D J. J. Power Sources, 2019, 427: 194-200.
17. [17]
  LIU X Y, YANG L J, ZHOU Z Q, ZENG L L, LIU H, DENG Y Q, YU J Y, YANG C H, ZHOU W J. Chem. Eng. J., 2020, 399: 125779.
18. [18]
  GUAN D Q, ZHOU J, HU Z W, ZHOU W, XU X M, ZHONG Y J, LIU B, CHEN Y H, XU M G, LIN H J, CHEN C T, WANG J Q, SHAO Z P. Adv. Funct. Mater., 2019, 29(20): 1900704.
19. [19]
  SUN H N, DAI J, ZHOU W, SHAO Z P. Energy Fuels, 2020, 34(9): 10547-10567.
20. [20]
  SONG H J, YOON H, JU B, KIM D W. Adv. Energy Mater., 2020: 2002428.
21. [21]
  PENA M A, FIERRO J L G. Chem. Rev., 2001, 101(7): 1981-2018.
22. [22]
  XU X M, ZHONG Y J, SHAO Z P. Trends Chem., 2019, 1(4): 410-424.
23. [23]
  KING G, WOODWARD P M. J. Mater. Chem., 2010, 20(28): 5785-5796.
24. [24]
  TANG L N, CHEN Z, ZUO F, HUA B, ZHOU H, LI M, LI J H, SUN Y F. Chem. Eng. J., 2020, 401: 126082.
25. [25]
  WANG J, LIAO T, WEI Z Z, SUN J T, GUO J J, SUN Z Q. Small Methods, 2021, 5(4): 2000988
26. [26]
  ZHU Y L, LIN Q, ZHONG Y J, TAHINI H A, SHAO Z P, WANG H T. Energy Environ. Sci., 2020, 13(10): 3361-3392.
27. [27]
  VRUBEL H, HU X L. Angew. Chem., Int. Ed., 2012, 51(51): 12703-12706.
28. [28]
  SUNTIVICH J, MAY K J, GASTEIGER H A, GOODENOUGH J B, SHAO-HORN Y. Science, 2011, 334(6061): 1383-1385.
29. [29]
  RISCH M, GRIMAUD A, MAY K J, STOERZINGER K A, CHEN T J, MANSOUR A N, SHAO-HORN Y. J. Phys. Chem. C, 2013, 117(17): 8628-8635.
30. [30]
  XU X M, CHEN Y B, ZHOU W, ZHU Z H, SU C, LIU M L, SHAO Z P. Adv. Mater., 2016, 28(30): 6442-6448.
31. [31]
  XU X M, PAN Y L, ZHONG Y J, GE L, JIANG S P, SHAO Z P. Composites, Part B, 2020, 198: 108214.
32. [32]
  YU J, WU X H, GUAN D Q, HU Z W, WENG S C, SUN H N, SONG Y F, RAN R, ZHOU W, NI M, SHAO Z P. Chem. Mater., 2020, 32(11): 4509-4517.
33. [33]
  WANG J, GAO Y, CHEN D J, LIU J P, ZHANG Z B, SHAO Z P, CIUCCI F. ACS Catal., 2018, 8(1): 364-371.
34. [34]
  ZHANG Z B, CHEN Y B, DAI Z Y, TAN S Z, CHEN D J. Electrochim. Acta, 2019, 312: 128-136.
35. [35]
  LIANG X, SHI L, LIU Y P, CHEN H, SI R, YAN W S, ZHANG Q, LI G D, YANG L, ZOU X X. Angew. Chem., Int. Ed., 2019, 58(23): 7631-7635.
36. [36]
  DONG F F, LI L, KONG Z Q, XU X M, ZHANG Y P, GAO Z H, DONGYANG B K, NI M, LIU Q B, LIN Z. Small, 2021, 17(2): 2006638.
37. [37]
  ZHANG Z B, ZHOU W L, YANG Z W, JIANG J H, CHEN D J, SHAO Z P. Int. J. Hydrogen Energy, 2020, 45(46): 24859-24869.
38. [38]
  GAO J X, ZHANG Y J, WANG X K, JIA L J, JIANG H Q, HUANG M H, TOGHAN A. Mater. Today Energy, 2021, 20: 100695.
39. [39]
  WU X H, YU J, YANG G M, LIU H, ZHOU W, SHAO Z P. Electrochim. Acta, 2018, 286: 47-54.
40. [40]
  AKBASHEV A R, ZHANG L, MEFFORD J T, PARK J, BUTZ B, LUFTMAN H, CHUEH W C, VOJVODIC A. Energy Environ. Sci., 2018, 11(7): 1762-1769.
41. [41]
  TSEKOURAS G, NEAGU D, IRVINE J T S. Energy Environ. Sci., 2013, 6(1): 256-266.
42. [42]
  OH N K, KIM C, LEE J, KWON O, CHOI Y, JUNG G Y, LIM H Y, KWAK S K, KIM G, PARK H. Nat. Commun., 2019, 10: 1723.
43. [43]
  LI Q, WANG D W, LU Q Q, MENG T, YAN M X, FAN L B, XING Z C, YANG X R. Small, 2020, 16(7): e1906380.
44. [44]
  LEE J G, MYUNG J H, NADEN A B, JEON O S, SHUL Y G, IRVINE J T S. Adv. Energy Mater., 2020, 10(10): 1903693.
45. [45]
  GUI L Q, PAN G H, MA X, YOU M S, HE B B, YANG Z H, SUN J, ZHOU W, XU J M, ZHAO L. Appl. Surf. Sci., 2021, 543: 148817.
46. [46]
  ZHU Y L, DAI J, ZHOU W, ZHONG Y J, WANG H T, SHAO Z P. J. Mater. Chem. A, 2018, 6(28): 13582-13587.
47. [47]
  ISLAM Q A, MAJEE R, BHATTACHARYYA S. J. Mater. Chem. A, 2019, 7(33): 19453-19464.
48. [48]
  ZHANG Y Q, TAO H B, CHEN Z, LI M, SUN Y F, HUA B, LUO J L. J. Mater. Chem. A, 2019, 7(46): 26607-26617.
49. [49]
  WANG Y R, WANG Z J, JIN C, LI C, LI X W, LI Y F, YANG R Z, LIU M L. Electrochim. Acta, 2019, 318: 120-129.
50. [50]
  WANG X Y, PAN Z Y, CHU X F, HUANG K K, CONG Y G, CAO R, SARANGI R, LI L P, LI G S, FENG S H. Angew. Chem., Int. Ed., 2019, 131(34): 11846-11851.
51. [51]
  ZHANG Z H, HE B B, CHEN L J, WANG H W, WANG R, ZHAO L, GONG Y S. ACS Appl. Mater. Interfaces, 2018, 10(44): 38032-38041.
52. [52]
  HE B B, TAN K, GONG Y S, WANG R, WANG H W, ZHAO L. Nanoscale, 2020, 12(16): 9048-9057.
53. [53]
  HUA B, LI M, SUN Y F, ZHANG Y Q, YAN N, CHEN J, THUNDAT T, LI J, LUO J L. Nano Energy, 2017, 32: 247-254.
54. [54]
  DAI J, ZHU Y L, ZHONG Y J, MIAO J, LIN B W, ZHOU W, SHAO Z P. Adv. Mater. Interfaces, 2019, 6(1): 1801317.
55. [55]
  GUAN D Q, ZHOU J, HUANG Y C, DONG C L, WANG J Q, ZHOU W, SHAO Z P. Nat. Commun., 2019, 10: 3755.
56. [56]
  TOGANO H, ASAI K, ODA S, IKENO H, KAWAGUCHI S, OKA K, WADA K, YAGI S, YAMADA I. Mater. Chem. Front., 2020, 4(5): 1519-1529.
57. [57]
  HONA R K, KARKI S B, RAMEZANIPOUR F. ACS Sustainable Chem. Eng., 2020, 8(31): 11549-11557.
58. [58]
  LI X N, HE L Q, ZHONG X W, ZHANG J, LUO S J, YI W D, ZHANG L Z, HU M M, TANG J, ZHOU X Y, ZHAO X Z, XU B M. Scanning, 2018, 2018: 1341608.
59. [59]
  HUA B, LI M, ZHANG Y Q, SUN Y F, LUO J L. Adv. Energy Mater., 2017,7(20): 1700666.
60. [60]
  HUA B, LI M, PANG W Y, TANG W Q, ZHAO S L, JIN Z H, ZENG Y M, SHALCHI AMIRKHIZ B, LUO J L. Chem, 2018, 4(12): 2902-2916.
61. [61]
  CHEN G, HU Z W, ZHU Y P, GU B B, ZHONG Y J, LIN H J, CHEN C T, ZHOU W, SHAO Z P. Adv. Mater., 2018, 30(43): 1804333.
62. [62]
  HU C, HONG J H, HUANG J, CHEN W, SEGRE C U, SUENAGA K, ZHAO W, HUANG F Q, WANG J C. Energy Environ. Sci., 2020, 13(11): 4249-4257.

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

钙钛矿氧化物结构分析及其电催化析氢反应研究进展

通讯作者: 黄明华,E-mail:huangminghua@ouc.edu.cn

English

Structure Analysis of Perovskite Oxides and Research Progress on Their Electrocatalytic Hydrogen Evolution Reaction

Corresponding author: HUANG Ming-Hua, huangminghua@ouc.edu.cn

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

钙钛矿氧化物结构分析及其电催化析氢反应研究进展

通讯作者: 黄明华,E-mail:huangminghua@ouc.edu.cn

English

Structure Analysis of Perovskite Oxides and Research Progress on Their Electrocatalytic Hydrogen Evolution Reaction

Corresponding author: HUANG Ming-Hua, huangminghua@ouc.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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