三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析

引用本文: 王林玉, 洪莎莎, 黎艳艳, 宋永海, 汪莉. 三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析[J]. 分析化学, 2021, 49(6): 1053-1060. doi: 10.19756/j.issn.0253-3820.210418 shu

Citation: WANG Lin-Yu, HONG Sha-Sha, LI Yan-Yan, SONG Yong-Hai, WANG Li. Dopamine Electrochemical Sensor Based on Three-Dimensional Macroporous Carbon/Covalent Organic Framework Integrated Electrode[J]. Chinese Journal of Analytical Chemistry, 2021, 49(6): 1053-1060. doi: 10.19756/j.issn.0253-3820.210418 shu

三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析

江西师范大学化学化工学院, 南昌 330022

通讯作者: 汪莉,E-mail:lwang@jxnu.edu.cn

基金项目:
国家自然科学基金项目（Nos.21765009，21964010，21465014，21665012）资助。

摘要: 通过简单的水热法使二苯甲酸二肼和1，3，5-三（对甲酰基苯基）苯发生氨醛缩合反应，合成了一种新的共价有机框架材料（COF_TFPB-TDF）。将COF_TFPB-TDF生长到三维多孔碳（3D-KSC）上，得到3D-KSC/COF_TFPB-TDF自支撑电极，采用扫描电子显微镜进行结构表征，结果表明，3D-KSC/COF_TFPB-TDF具有片层结构，同时含有很多孔洞，可以固载其它的材料。采用循环伏安法研究了3D-KSC/COF_TFPB-TDF自支撑电极对多巴胺的检测性能。结果表明，此传感器对多巴胺表现出良好的传感性能，具有低的检出限（0.045 μmol/L）、宽的线性范围（0.13 μmol/L~0.06 mmol/L）和高灵敏度（369 μA/（mmol/L）/cm²），这主要归因于COF_TFPB-TDF较大的比表面积和较多的孔洞结构。因此，此材料具有良好的应用前景。

关键词:

English

Dopamine Electrochemical Sensor Based on Three-Dimensional Macroporous Carbon/Covalent Organic Framework Integrated Electrode

Key Laboratory of Functional Small Organic Molecule, Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: WANG Li, lwang@jxnu.edu.cn

Received Date: 07 April 2021
Revised Date: 21 April 2021
Fund Project:
Supported by the National Natural Science Foundation of China (Nos.21765009, 21964010, 21465014, 21665012).

Abstract: A novel covalent organic framework (COF_TFPB-TDF) was firstly synthesized by ammonaldehyde condensation reaction between 1,3,5-tris(p-formylphenyl) benzene and 1,4-benzenedicarbohydrazide. Then, three-dimensional macroporous carbon derived from kenaf stem (3D-KSC)/COF_TFPB-TDF integrated electrode was obtained by growing COF_TFPB-TDF on 3D-KSC. Scanning electron microscopy was used to characterize the structure of 3D-KSC/COF_TFPB-TDF. The results showed that 3D-KSC/COF_TF_PB-TDF had lamellar structure and there were many holes to support other materials. The performance of 3D-KSC/COF_TFPB-TDF electrode for detection of dopamine was studied by cyclic voltammetry. The results showed that the sensor had good performance for detecting dopamine, with low detection limit (0.045 μmol/L), wide linear range (0.134 μmol/L-0.06 mmol/L) and high sensitivity (369 μA/(mmol/L)/cm²). These excellent properties were mainly attributed to the larger specific surface area and pore structure of 3D-KSC/COF_TFPB-TDF, which also made the material had a good application prospect in other aspects.

Key words:

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析

通讯作者: 汪莉,E-mail:lwang@jxnu.edu.cn

English

Dopamine Electrochemical Sensor Based on Three-Dimensional Macroporous Carbon/Covalent Organic Framework Integrated Electrode

Corresponding author: WANG Li, lwang@jxnu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

三维多孔碳/共价有机框架材料自支撑电极用于多巴胺电化学传感分析

通讯作者: 汪莉,E-mail:lwang@jxnu.edu.cn

English

Dopamine Electrochemical Sensor Based on Three-Dimensional Macroporous Carbon/Covalent Organic Framework Integrated Electrode

Corresponding author: WANG Li, lwang@jxnu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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