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Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a Cd(II) Compound with (4,6)-Connected Topology

ZHANG Xin ,  SUN Ming-Ling ,  QIN Ye-Yan ,  YAO Yuan-Gen

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Citation:  ZHANG Xin, SUN Ming-Ling, QIN Ye-Yan, YAO Yuan-Gen. Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a Cd(II) Compound with (4,6)-Connected Topology[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 914-920. doi: 10.14102/j.cnki.0254-5861.2011-1001 shu

Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a Cd(II) Compound with (4,6)-Connected Topology

  • a.

    a. Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;

  • b.

    b. University of Chinese Academy of Sciences, Beijing 100039, China

    • 通讯作者: YAO Yuan-Gen,
  • 基金项目:

    Supported by the 973 Program of China (2011CBA00505) (2011CBA00505)

    the "Strategic Priority Research Program" of the Chinese Academy of Sciences (XDA07070200, XDA09030102) (XDA07070200, XDA09030102)

    the Science Foundation of Fujian Province (2006L2005) (2006L2005)

摘要: A new Cd(II) coordination polymer, namely {Cd2(L)(biimpy)(H2O)}n (1, H4L = 3-(3',5'-dicarboxylphenoxy)phthalic acid, biimpy = 2,6-bis(1-imdazoly)pyridine), has been success- fully synthesized via the hydrothermal reactions of Cd(II) ions, H4L and biimpy. The crystal structure is of triclinic, space group P with a = 7.7874(5), b = 9.9716(5), c = 18.5278(6) Å, α = 91.327(4), β = 96.689(4), γ = 111.896(5)°, V = 1322.39(12) Å3, C27H17Cd2N5O10, Mr = 796.26, Z = 2, Dc = 2.000 g/cm3, F(000) = 780, μ = 1.679 mm-1, R = 0.0345 and wR = 0.0767 for 3890 observed reflections (I > 2s(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional (3D) framework based on two different dinuclear [Cd2(COO)2] building subunits, and topological analysis shows that it can be simplified into a binodal (4,6)-connected topological network with the point symbol of {3.42.52.6}{32.42.52.64.74.8}. Moreover, the thermal stability and luminescent property of compound 1 were also studied.

English

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  • 收稿日期:  2015-09-09
  • 网络出版日期:  2015-10-28
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