Syntheses, Crystal Structures and Luminescent Properties of Two Schiff Base Complexes

YUAN Shuai ,  ZHANG Yue-Jia ,  HOU Jin-Yan ,  LIU Qing-Lin ,  LI Dong-Ping ,  LI Yong-Xiu

Citation:  YUAN Shuai, ZHANG Yue-Jia, HOU Jin-Yan, LIU Qing-Lin, LI Dong-Ping, LI Yong-Xiu. Syntheses, Crystal Structures and Luminescent Properties of Two Schiff Base Complexes[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 965-972. doi: 10.14102/j.cnki.0254-5861.2011-0992 shu

Syntheses, Crystal Structures and Luminescent Properties of Two Schiff Base Complexes

    通讯作者: LI Dong-Ping,
    LI Yong-Xiu,
  • 基金项目:

    the Natural Science Foundation of Jiangxi Province (20114BAB213001)  (20114BAB213001)

    the Education Department of Jiangxi Province (GJJ12041) (GJJ12041)

摘要: Two new transition metal complexes based on chiral Schiff base ligand, namely Zn(L1)2 (1) and Cd(L2)2 (2) (L1 = (R,E)-3-(2-hydroxy-3-methoxybenzylideneamino)propane-1,2-diol, L2= (R,E)-2-((2-hydroxy-1-phenylethylimino)methyl)-6-methoxyphenol), have been synthesized and characterized. Single-crystal X-ray diffractions reveal that both 1 and 2 crystallize in the same monoclinic space group C2. 1 is four-coordinated, while 2 is six-coordinated. Complexes 1 and 2 show fluorescent emission at 479 and 580 nm, respectively. Moreover, 1 and 2 exhibit selective and sensitive recognition toward Zn2+/Cd2+ ions in the methanol solution.

English

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  • 收稿日期:  2015-09-29
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