Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)

Citation: ZHAO Qiang, SHEN Zhi, LIU Wen-Min, SONG Hui-Zhen, HE Ze-Ying. Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 939-945. doi: 10.14102/j.cnki.0254-5861.2011-0988 shu

Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)

1.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, China
基金项目:
This work was supported by the NNSFC (21301100) (21301100)

the Education Department Fund of Henan (13A150819) (13A150819)

Special fund of Nanyang Normal University (ZX2013029) (ZX2013029)

摘要: Two high coordination crystals were obtained by the interaction of Ce³⁺ and Nd³⁺ with polypyridyl quinoxaline ligand 2,3,6,7,10,11-hexakis(2-pyridyl)dipyrazino[2,3-f:20,30-h]qui- noxaline (HPDQ), and they were characterized. Complex 1 exhibits a 0 dimensional three-nuclear structure, with the three Ce(III) atoms being ten-, eleven- and twelve-coordinated. Complex 2 is a 0 dimensional dual-core structure and the Nd(III) atom is ten-coordinated. Complex 1 is of mono- clinic system, space group P2/c with a = 16.850(3), b = 16.617(3), c = 24.017(5) Å, β = 100.94(3)^o, V = 6602(2) Å³, Z = 4, S = 1.062, F(000) = 3372, R= 0.0504 and wR= 0.1463 (I> 2σ(I)). Complex 2 adopts a monoclinic system, space group C2/c with a = 25.795(5), b = 20.166(4), c = 13.059(3) Å, β = 112.29(3)^o, V = 6286(2) Å³, Z = 4, S = 1.004, F(000) = 2664, R= 0.0663 and wR= 0.1821 (I > 2σ(I)). Furthermore, the behaviors of HPDQ with Ce³⁺ and Nd³⁺in the solution are also investigated. After the Ce³⁺ is added, the ultraviolet absorption of the solution is enhanced with a red shift compared with that of the HPDQ ligand. While after adding Nd³⁺, the ultraviolet absorption of the solution is weakened, and it has a red shift which is the same as Ce³⁺. However, after the respective addition of metal ions, the emission of all solutions is quenched and has a red shift compared with that of the HPDQ ligand.

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English

Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)

1.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, China
Received Date: 28 September 2015
Fund Project:

Abstract: Two high coordination crystals were obtained by the interaction of Ce³⁺ and Nd³⁺ with polypyridyl quinoxaline ligand 2,3,6,7,10,11-hexakis(2-pyridyl)dipyrazino[2,3-f:20,30-h]qui- noxaline (HPDQ), and they were characterized. Complex 1 exhibits a 0 dimensional three-nuclear structure, with the three Ce(III) atoms being ten-, eleven- and twelve-coordinated. Complex 2 is a 0 dimensional dual-core structure and the Nd(III) atom is ten-coordinated. Complex 1 is of mono- clinic system, space group P2/c with a = 16.850(3), b = 16.617(3), c = 24.017(5) Å, β = 100.94(3)^o, V = 6602(2) Å³, Z = 4, S = 1.062, F(000) = 3372, R= 0.0504 and wR= 0.1463 (I> 2σ(I)). Complex 2 adopts a monoclinic system, space group C2/c with a = 25.795(5), b = 20.166(4), c = 13.059(3) Å, β = 112.29(3)^o, V = 6286(2) Å³, Z = 4, S = 1.004, F(000) = 2664, R= 0.0663 and wR= 0.1821 (I > 2σ(I)). Furthermore, the behaviors of HPDQ with Ce³⁺ and Nd³⁺in the solution are also investigated. After the Ce³⁺ is added, the ultraviolet absorption of the solution is enhanced with a red shift compared with that of the HPDQ ligand. While after adding Nd³⁺, the ultraviolet absorption of the solution is weakened, and it has a red shift which is the same as Ce³⁺. However, after the respective addition of metal ions, the emission of all solutions is quenched and has a red shift compared with that of the HPDQ ligand.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)

English

Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)

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中国化学会秘书处

Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)

English

Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)

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