Syntheses, Structures and Properties <i>of Two Mn(II) Clusters Based on</i> <i>1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand</i>

Citation: MIAO Yan-Li, WANG Hong-Bo, GU Chang-Sheng, LI Yong. Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand[J]. Chinese Journal of Structural Chemistry, 2016, 35(6): 973-979. doi: 10.14102/j.cnki.0254-5861.2011-0966 shu

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

a.
a. College of Science, Guangdong Ocean University, Zhanjiang 524088, China;
b.
b. School of Navigation, Wuhan University of Technology, Wuhan 430063, China
基金项目:
This work was supported by Guangdong Ocean University with doctor start-up fund (1112263) (1112263)

Technology Plan Projects of Zhanjiang City (No. 2013B01073) (No. 2013B01073)

摘要: Two novel clusters [Mn^III₃(m₃-O)(phendox)₃]X·13H₂O (X = Cl (1), Br (2]) have been obtained from the solvothermal reactions of 1,10-phenanthroline-2,9-dicarbaldehyde dioxime (H₂phendox) with MnCl₂·4H₂O or anhydrous MnBr₂, and their structures were characterized by elemental analysis, FT-IR, XRD, TGA, MS and single-crystal X-ray diffraction. It crystallizes in trigonal, space group P3₁/c. X-ray analysis reveals that the neighbouring [Mn₃(m₃-O)(phendox)₃]⁺ cores are linked by C–H…Cl hydrogen bonds and form an infinite supramolecular chain along the c-axis. Neighbouring chains are packed with each other by off-set p-p interactions of the aromatic rings on phenox^2-. A 3D supramolecular architecture in a honeycomb topology is formed with 1D hexagonal channel in the dimensions of 13Å × 13Å along the c-axis. The gas adsorption studies show that compound 1·13H₂O is stable upon the removal of guest molecules and the desolvated compound absorbed considerable amount of CO₂.

关键词:

clusters
/ 1,10-phenanthroline-2,9-dicarbaldehyde dioxime
/ crystal structure
/ gas adsorption

English

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

a.
a. College of Science, Guangdong Ocean University, Zhanjiang 524088, China;
b.
b. School of Navigation, Wuhan University of Technology, Wuhan 430063, China
Received Date: 02 September 2015
Fund Project:

Abstract: Two novel clusters [Mn^III₃(m₃-O)(phendox)₃]X·13H₂O (X = Cl (1), Br (2]) have been obtained from the solvothermal reactions of 1,10-phenanthroline-2,9-dicarbaldehyde dioxime (H₂phendox) with MnCl₂·4H₂O or anhydrous MnBr₂, and their structures were characterized by elemental analysis, FT-IR, XRD, TGA, MS and single-crystal X-ray diffraction. It crystallizes in trigonal, space group P3₁/c. X-ray analysis reveals that the neighbouring [Mn₃(m₃-O)(phendox)₃]⁺ cores are linked by C–H…Cl hydrogen bonds and form an infinite supramolecular chain along the c-axis. Neighbouring chains are packed with each other by off-set p-p interactions of the aromatic rings on phenox^2-. A 3D supramolecular architecture in a honeycomb topology is formed with 1D hexagonal channel in the dimensions of 13Å × 13Å along the c-axis. The gas adsorption studies show that compound 1·13H₂O is stable upon the removal of guest molecules and the desolvated compound absorbed considerable amount of CO₂.

Key words:

clusters
/ 1,10-phenanthroline-2,9-dicarbaldehyde dioxime
/ crystal structure
/ gas adsorption

1. [1]
  (1) Mukhopadhyay, S.; Mandal, S. K.; Bhaduri, S.; Armstrong, W. H. Manganese clusters with relevance to photosystem II. Chem. Rev. 2004, 104, 3981-4026.(1) Mukhopadhyay, S.; Mandal, S. K.; Bhaduri, S.; Armstrong, W. H. Manganese clusters with relevance to photosystem II. Chem. Rev. 2004, 104, 3981-4026.
2. [2]
  (2) Aromi, G.; Brechin, E. K. Synthesis of 3d metallic single-molecule magnets. Struct. Bonding 2006, 122, 1-67.(2) Aromi, G.; Brechin, E. K. Synthesis of 3d metallic single-molecule magnets. Struct. Bonding 2006, 122, 1-67.
3. [3]
  (3) Gatteschi, D.; Sessoli, R. Quantum tunneling of magnetization and related phenomena in molecular materials. Angew. Chem. Int. Ed. 2003, 42, 268-297.(3) Gatteschi, D.; Sessoli, R. Quantum tunneling of magnetization and related phenomena in molecular materials. Angew. Chem. Int. Ed. 2003, 42, 268-297.
4. [4]
  (4) Christou, G. Single-molecule magnets: a molecular approach to nanoscale magnetic materials original. Polyhedron 2005, 24, 2065–2075.(4) Christou, G. Single-molecule magnets: a molecular approach to nanoscale magnetic materials original. Polyhedron 2005, 24, 2065–2075.
5. [5]
  (5) (a) Liu, J. L.; Huang, G. Z.; Tong, M. L. Field-induced dynamic magnetic behavior of a canted weak ferromagnetic chain material. Inorg. Chem. Front. 2015, 2, 403-408. (b) Liu, J. L.; Liu, W.; Huang, G. Z.; Tong, M. L. A breathing chiral molecular solid for enantioselective separation via crystal-to-crystal transformation. Sci. Bull. 2015, 60, 447-452. (c) Wang, W. G.; Zhou, A. J.; Zhang, W. X.; Tong, M. L.; Chen, X. M.; Nakano, M.; Beedle, C. C.; Hendrickson, D. N. Giant heterometallic Cu₁₇Mn₂₈ cluster with Td symmetry and high-spin ground state. J. Am. Chem. Soc. 2007, 129, 1014-1015. (d) Zhou, A. J.; Qin, L. J.; Beedle, C. C.; Ding, S.; Nakano, M.; Leng, J. D.; Tong, M. L.; Hendrickson, D. N. New Mn₁₂ clusters with tunable oxidation states via the use of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine. Inorg. Chem. 2007, 46, 8111-8113. (e) Zheng, Y. Z.; Xie, W.; Zhang, W. X.; Tong, M. L.; Chen, X. M. From pseudo to true C₃-symmetry: magnetic anisotropy enhanced by site-specific ligand substitution in two Mn₁₅-carboxylate clusters. Inorg. Chem. 2007, 46, 6437-6443. (f) Zhou, A. J.; Liu, J. L.; Herchel, R.; Leng, J. D.; Tong, M. L. High-spin tetranuclear Mn^II₂Mn^IV₂ clusters with unique Mn(II)-Mn(IV) magnetic exchange. Synthesis, structures and magnetic properties of Mn₄ and Fe₄ clusters with tetrakis(2-hydroxyethyl)ethylenediamine. Dalton Trans. 2009, 3182-3192.(5) (a) Liu, J. L.; Huang, G. Z.; Tong, M. L. Field-induced dynamic magnetic behavior of a canted weak ferromagnetic chain material. Inorg. Chem. Front. 2015, 2, 403-408. (b) Liu, J. L.; Liu, W.; Huang, G. Z.; Tong, M. L. A breathing chiral molecular solid for enantioselective separation via crystal-to-crystal transformation. Sci. Bull. 2015, 60, 447-452. (c) Wang, W. G.; Zhou, A. J.; Zhang, W. X.; Tong, M. L.; Chen, X. M.; Nakano, M.; Beedle, C. C.; Hendrickson, D. N. Giant heterometallic Cu₁₇Mn₂₈ cluster with Td symmetry and high-spin ground state. J. Am. Chem. Soc. 2007, 129, 1014-1015. (d) Zhou, A. J.; Qin, L. J.; Beedle, C. C.; Ding, S.; Nakano, M.; Leng, J. D.; Tong, M. L.; Hendrickson, D. N. New Mn₁₂ clusters with tunable oxidation states via the use of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine. Inorg. Chem. 2007, 46, 8111-8113. (e) Zheng, Y. Z.; Xie, W.; Zhang, W. X.; Tong, M. L.; Chen, X. M. From pseudo to true C₃-symmetry: magnetic anisotropy enhanced by site-specific ligand substitution in two Mn₁₅-carboxylate clusters. Inorg. Chem. 2007, 46, 6437-6443. (f) Zhou, A. J.; Liu, J. L.; Herchel, R.; Leng, J. D.; Tong, M. L. High-spin tetranuclear Mn^II₂Mn^IV₂ clusters with unique Mn(II)-Mn(IV) magnetic exchange. Synthesis, structures and magnetic properties of Mn₄ and Fe₄ clusters with tetrakis(2-hydroxyethyl)ethylenediamine. Dalton Trans. 2009, 3182-3192.
6. [6]
  (6) Kaes, C.; Katz, A.; Hosseini, M. W. The most widely used ligand. A review of molecules comprising at least two 2,2'-bipyridine units. Chem. Rev. 2000, 100, 3553-3590.(6) Kaes, C.; Katz, A.; Hosseini, M. W. The most widely used ligand. A review of molecules comprising at least two 2,2'-bipyridine units. Chem. Rev. 2000, 100, 3553-3590.
7. [7]
  (7) (a) Angeloff, A.; Daran, J. C.; Bernadou, J.; Meunier, B. The ligand 1,10-phenanthroline-2,9-dicarbaldehyde dioxime can act both as a tridentate and as a tetradentate ligand - synthesis, characterization and crystal structures of its transition metal complexes. Eur. J. Inorg. Chem. 2000, 1985-1996; (b) Fan, L. L.; Li, C. J.; Meng, Z. S.; Tong, M. L. Metal-mediated one-step in situ oxidation of 2,9-dimethyl-1,10-phenanthroline and formation of transition-metal and lanthanoid complexes. Eur. J. Inorg. Chem. 2008, 3905-3909.(7) (a) Angeloff, A.; Daran, J. C.; Bernadou, J.; Meunier, B. The ligand 1,10-phenanthroline-2,9-dicarbaldehyde dioxime can act both as a tridentate and as a tetradentate ligand - synthesis, characterization and crystal structures of its transition metal complexes. Eur. J. Inorg. Chem. 2000, 1985-1996; (b) Fan, L. L.; Li, C. J.; Meng, Z. S.; Tong, M. L. Metal-mediated one-step in situ oxidation of 2,9-dimethyl-1,10-phenanthroline and formation of transition-metal and lanthanoid complexes. Eur. J. Inorg. Chem. 2008, 3905-3909.
8. [8]
  (8) Alborés, P.; Rentschler, E. A. A. T-shaped m₃-oxido trinuclear iron cluster with high easy-plane anisotropy: structural and magnetic characterization. Eur. J. Inorg. Chem. 2008, 4004-4011.(8) Alborés, P.; Rentschler, E. A. A. T-shaped m₃-oxido trinuclear iron cluster with high easy-plane anisotropy: structural and magnetic characterization. Eur. J. Inorg. Chem. 2008, 4004-4011.
9. [9]
  (9) (a) Sreerama, S. G.; Pal, S. A triiron complex containing the carboxylate-free {Fe₃(m₃-O)}⁷⁺ core and distorted pentagonal-bipyramidal metal centers. Eur. J. Inorg. Chem. 2004, 4718-4723; (b) Sreerama, S. G.; Pal, S. A novel carboxylate-free ferromagnetic trinuclear μ₃-oxo-manganese(III) complex with distorted pentagonal-bipyramidal metal centers. Inorg. Chem. 2002, 41, 4843-4845.(9) (a) Sreerama, S. G.; Pal, S. A triiron complex containing the carboxylate-free {Fe₃(m₃-O)}⁷⁺ core and distorted pentagonal-bipyramidal metal centers. Eur. J. Inorg. Chem. 2004, 4718-4723; (b) Sreerama, S. G.; Pal, S. A novel carboxylate-free ferromagnetic trinuclear μ₃-oxo-manganese(III) complex with distorted pentagonal-bipyramidal metal centers. Inorg. Chem. 2002, 41, 4843-4845.
10. [10]
  (10) (a) Miao, Y. L.; Liu, J. L.; Lin, Z. J.; Ou, Y. C.; Leng, J. D.; Tong, M. L. Synthesis, structures, adsorption behavior and magnetic properties of a new family of polynuclear iron clusters. Dalton Trans. 2010, 39, 4893-4902. (b) Miao, Y. L.; Liu, J. L.; Leng, J. D.; Lin, Z. J.; Tong, M. L. Chloride templated formation of {Dy₁₂(OH)₁₆}²⁰⁺ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate. CrystEngComm. 2011, 13, 3345-3348. (c) Miao, Y. L.; Liu, J. L.; Li, J. Y.; Leng, J. D.; Ou, Y. C.; Tong, M. L. Two novel Dy₈ and Dy₁₁ clusters with cubane [Dy₄(m₃-OH)₄]⁸⁺ units exhibiting slow magnetic relaxation behavior. Dalton Trans. 2011, 40, 10229-10236. (d) Miao, Y. L.; Liu, J. L.; Guo, F. S.; Tong, M. L. Synthesis, structures and magnetic properties of octahedral clusters of [M^II₆(m₆-Cl)(phenda)₆]^- (M = Mn, Co and Ni; phenda = 1,10-phenanthroline-2,9-dicarboxylate). Inorg. Chem. Comm. 2015, 52, 77-79.(10) (a) Miao, Y. L.; Liu, J. L.; Lin, Z. J.; Ou, Y. C.; Leng, J. D.; Tong, M. L. Synthesis, structures, adsorption behavior and magnetic properties of a new family of polynuclear iron clusters. Dalton Trans. 2010, 39, 4893-4902. (b) Miao, Y. L.; Liu, J. L.; Leng, J. D.; Lin, Z. J.; Tong, M. L. Chloride templated formation of {Dy₁₂(OH)₁₆}²⁰⁺ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate. CrystEngComm. 2011, 13, 3345-3348. (c) Miao, Y. L.; Liu, J. L.; Li, J. Y.; Leng, J. D.; Ou, Y. C.; Tong, M. L. Two novel Dy₈ and Dy₁₁ clusters with cubane [Dy₄(m₃-OH)₄]⁸⁺ units exhibiting slow magnetic relaxation behavior. Dalton Trans. 2011, 40, 10229-10236. (d) Miao, Y. L.; Liu, J. L.; Guo, F. S.; Tong, M. L. Synthesis, structures and magnetic properties of octahedral clusters of [M^II₆(m₆-Cl)(phenda)₆]^- (M = Mn, Co and Ni; phenda = 1,10-phenanthroline-2,9-dicarboxylate). Inorg. Chem. Comm. 2015, 52, 77-79.
11. [11]
  (11) Chandler, C. J.; Deady, L. W.; Reiss, J. A. Synthesis of some 2,9-disubstituted-1,10-phenanthrolines. J. Heterocycl. Chem. 1981, 18, 599-601.(11) Chandler, C. J.; Deady, L. W.; Reiss, J. A. Synthesis of some 2,9-disubstituted-1,10-phenanthrolines. J. Heterocycl. Chem. 1981, 18, 599-601.
12. [12]
  (12) (a) Blessing, R. H. An empirical correction for absorption anisotropy. Acta Cryst. 1995, A51, 33-38; (b) Sheldrick, G. M. SADABS 2.05, Area-detector Absorption Correction. University of Göttingen, Germany 1996.(12) (a) Blessing, R. H. An empirical correction for absorption anisotropy. Acta Cryst. 1995, A51, 33-38; (b) Sheldrick, G. M. SADABS 2.05, Area-detector Absorption Correction. University of Göttingen, Germany 1996.
13. [13]
  (13) SHELXTL 6.10, Bruker Analytical Instrumentation, Madison, Wisconsin, USA 2000.(13) SHELXTL 6.10, Bruker Analytical Instrumentation, Madison, Wisconsin, USA 2000.
14. [14]
  (14) (a) Angeloff, A.; Daran, J. C.; Bernadou, J.; Meunier, B. The Ligand 1,10-phenanthroline-2,9-dicarbaldehyde dioxime can act both as a tridentate and as a tetradentate ligand. Synthesis, characterization and crystal structures of its transition metal complexes. Eur. J. Inorg. Chem. 2000, 1985-1996; (b) Sreerama, S. G.; Pal, S. A novel carboxylate-free ferromagnetic trinuclear m₃-oxo-manganese(III) complex with distorted pentagonal-bipyramidal metal centers. Inorg. Chem. 2002, 41, 4843-4849.(14) (a) Angeloff, A.; Daran, J. C.; Bernadou, J.; Meunier, B. The Ligand 1,10-phenanthroline-2,9-dicarbaldehyde dioxime can act both as a tridentate and as a tetradentate ligand. Synthesis, characterization and crystal structures of its transition metal complexes. Eur. J. Inorg. Chem. 2000, 1985-1996; (b) Sreerama, S. G.; Pal, S. A novel carboxylate-free ferromagnetic trinuclear m₃-oxo-manganese(III) complex with distorted pentagonal-bipyramidal metal centers. Inorg. Chem. 2002, 41, 4843-4849.
15. [15]
  (15) Dalice, P.; Peter, B.; Roman, B.; Radovan, H.; Michael, K.; Raphael, G. R.; Franz, R.; Yiannis, S. A pyrazolate-supported Fe₃(m₃-O)-core; structural, spectroscopic, electrochemical and magnetic study. Inorg. Chem. 2007, 46, 10981-10989.(15) Dalice, P.; Peter, B.; Roman, B.; Radovan, H.; Michael, K.; Raphael, G. R.; Franz, R.; Yiannis, S. A pyrazolate-supported Fe₃(m₃-O)-core; structural, spectroscopic, electrochemical and magnetic study. Inorg. Chem. 2007, 46, 10981-10989.

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

English

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

English

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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