注册 English

双功能离子液体[A336][P507]在盐酸和硝酸介质中对Sc(Ⅲ)的萃取

沈璐 ,  陈继 ,  邓岳锋

downloadPDF
引用本文: 沈璐, 陈继, 邓岳锋. 双功能离子液体[A336][P507]在盐酸和硝酸介质中对Sc(Ⅲ)的萃取[J]. 应用化学, 2016, 33(3): 330-335. doi: 10.11944/j.issn.1000-0518.2016.03.150305 shu
Citation:  SHEN Lu, CHEN Ji, DENG Yuefeng. Extraction of Sc(Ⅲ) Using a Bifunctional Ionic Liquid [A336][P507][J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 330-335. doi: 10.11944/j.issn.1000-0518.2016.03.150305 shu

双功能离子液体[A336][P507]在盐酸和硝酸介质中对Sc(Ⅲ)的萃取

  • a.

    a. 中国科学院长春应用化学研究所稀土资源利用国家重点实验室 长春 130022;

  • b.

    b. 中国科学院大学 北京 100049

    • 通讯作者: 陈继,研究员;Tel/Fax:0431-85262646;E-mail:jchen@ciac.ac.cn;研究方向:离子液体在稀土绿色冶金过程中的基础及应用
  • 基金项目:

    国家自然科学基金（51174184） 

摘要: 利用双功能离子液体萃取剂三辛基甲基氯化铵2-乙基己基磷酸2-乙基己基酯盐（[A336][P507]）在HCl和HNO3介质中对Sc（Ⅲ）的萃取和分离。研究表明，萃取剂在低酸度条件下，对Sc（Ⅲ）有较好的萃取能力；但是当水相酸度从0.5 mol/L增加到4 mol/L，Sc（Ⅲ）的萃取率有较大程度的下降。并且讨论了在HCl介质和HNO3介质中，[A336][P507]萃取Sc（Ⅲ）的机理，由于Sc（Ⅲ）的半径最小，而且在萃取过程中存在P=O与P-O的竞争作用，使得其萃合物结构与轻稀土不同。水相中加入盐析剂NaCl或NaNO3对Sc（Ⅲ）的萃取有一定的促进作用；萃取过程的热力学参数的结果表明，萃取反应是放热反应。还研究了混合稀土中Sc（Ⅲ）和其它稀土离子的分离，在较低酸度的条件下萃取剂[A336][P507]对其它稀土离子的萃取可以忽略不计，因此该萃取体系对Sc（Ⅲ）和其它稀土离子有较好的分离效果，显示了本研究潜在的应用价值。

English

  • 

    1. [1] ZHANG Yuxue. Types of Sc Deposits and Research Prospects[J]. Geol-Geochem,1997,77(60):116-119(in Chinese).张玉学. 分散元素钪的矿床类型与研究前景[J]. 地质地球化学,1997,77(60):116-119.[1] ZHANG Yuxue. Types of Sc Deposits and Research Prospects[J]. Geol-Geochem,1997,77(60):116-119(in Chinese).张玉学. 分散元素钪的矿床类型与研究前景[J]. 地质地球化学,1997,77(60):116-119.

    2. [2] CHI Ru'an,WANG Dianzuo. Rare Earth Dressing and Extraction Technology[M]. Beijing:Science Press,1996:293(in Chinese).池汝安,王淀佐. 稀土选矿与提取技术[M]. 北京:科学出版社,1996:293.[2] CHI Ru'an,WANG Dianzuo. Rare Earth Dressing and Extraction Technology[M]. Beijing:Science Press,1996:293(in Chinese).池汝安,王淀佐. 稀土选矿与提取技术[M]. 北京:科学出版社,1996:293.

    3. [3] XIAO Jinkai. Distribution Characteristics of Industrial Waste Red Mud[J]. Geol-Geochem,1996,(2):82-86(in Chinese).肖金凯. 工业废渣赤泥中钪的分布特征[J]. 地质地球化学,1996,(2):82-86.[3] XIAO Jinkai. Distribution Characteristics of Industrial Waste Red Mud[J]. Geol-Geochem,1996,(2):82-86(in Chinese).肖金凯. 工业废渣赤泥中钪的分布特征[J]. 地质地球化学,1996,(2):82-86.

    4. [4] XIAO Jinkai,LEI Jianquan,XIA Xiang. Some Characteristics of Scandium in Bauxite from Central Guizhou as well as in Red Mud[J]. Acta Miner Sin,1994,14(4):388-393(in Chinese).肖金凯,雷剑泉,夏祥. 黔中铝土矿及赤泥中钪的某些特征[J]. 矿物学报,1994,14(4):388-393.[4] XIAO Jinkai,LEI Jianquan,XIA Xiang. Some Characteristics of Scandium in Bauxite from Central Guizhou as well as in Red Mud[J]. Acta Miner Sin,1994,14(4):388-393(in Chinese).肖金凯,雷剑泉,夏祥. 黔中铝土矿及赤泥中钪的某些特征[J]. 矿物学报,1994,14(4):388-393.

    5. [5] LIAO Chunsheng,Xu Gang,JIA Jiangtao. Recovery and Applicaion of Scandium-A Strategic Resource of New Centry[J]. J Chinese Rare Earth Soc,2001,19(1):289-297(in Chinese).廖春生,徐刚,贾江涛. 新世纪的战略资源-钪的提取与应用[J]. 中国稀土学报,2001,19(4):289-297.[5] LIAO Chunsheng,Xu Gang,JIA Jiangtao. Recovery and Applicaion of Scandium-A Strategic Resource of New Centry[J]. J Chinese Rare Earth Soc,2001,19(1):289-297(in Chinese).廖春生,徐刚,贾江涛. 新世纪的战略资源-钪的提取与应用[J]. 中国稀土学报,2001,19(4):289-297.

    6. [6] WANG Xiquan. The Separation and Enrichment of Sc by P204 Solvent Extraction[J]. Liaoning Chem Ind,1998,27(6):320-322(in Chinese).王喜全. 用P204作萃取剂分离富集钪[J]. 辽宁化工,1998,27(6):320-322.[6] WANG Xiquan. The Separation and Enrichment of Sc by P204 Solvent Extraction[J]. Liaoning Chem Ind,1998,27(6):320-322(in Chinese).王喜全. 用P204作萃取剂分离富集钪[J]. 辽宁化工,1998,27(6):320-322.

    7. [7] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences. Rare Earth Chemical Proceedings[M]. Beijing:Science Press,1982(in Chinese).中国科学院长春应用化学研究所. 稀土化学论文集[M]. 北京:科学出版社,1982.[7] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences. Rare Earth Chemical Proceedings[M]. Beijing:Science Press,1982(in Chinese).中国科学院长春应用化学研究所. 稀土化学论文集[M]. 北京:科学出版社,1982.

    8. [8] Li D Q,Wang C. Solvent Extraction of Scandium(Ⅲ) by Cyanex 923 and Cyanex 925[J]. Hydrometallurgy,1998,48(3):301-312.[8] Li D Q,Wang C. Solvent Extraction of Scandium(Ⅲ) by Cyanex 923 and Cyanex 925[J]. Hydrometallurgy,1998,48(3):301-312.

    9. [9] Whitehead J A,Lawrance G A,McCluskey A. ‘Green’ Leaching: Recyclable and Selective Leaching of Gold-Bearing Ore in An Ionic Liquid[J]. Green Chem,2004,6(7):313-315.[9] Whitehead J A,Lawrance G A,McCluskey A. ‘Green’ Leaching: Recyclable and Selective Leaching of Gold-Bearing Ore in An Ionic Liquid[J]. Green Chem,2004,6(7):313-315.

    10. [10] Nakashima K,Kubota F,Maruyama T,et al. Ionic liquids as a Novel Solvent for Lanthanide Extraction[J]. Anal Sci,2003,19(8):1097-1098.[10] Nakashima K,Kubota F,Maruyama T,et al. Ionic liquids as a Novel Solvent for Lanthanide Extraction[J]. Anal Sci,2003,19(8):1097-1098.

    11. [11] Sun X Q,Ji Y,Liu Y,et al. An Engineering-Purpose Preparation Strategy for Ammonium-Type Ionic Liquid with High Purity[J]. AlChE J,2010,56(4):989-996.[11] Sun X Q,Ji Y,Liu Y,et al. An Engineering-Purpose Preparation Strategy for Ammonium-Type Ionic Liquid with High Purity[J]. AlChE J,2010,56(4):989-996.

    12. [12] Guo L,Chen J,Shen L,et al. Highly Selective Extraction and Separation of Rare Earths(Ⅲ) Using Bifunctional Ionic Liquid Extractant[J]. ACS Sustain Chem Eng,2014,2(8):1968-1975.[12] Guo L,Chen J,Shen L,et al. Highly Selective Extraction and Separation of Rare Earths(Ⅲ) Using Bifunctional Ionic Liquid Extractant[J]. ACS Sustain Chem Eng,2014,2(8):1968-1975.

    13. [13] Zhang D L,Wang W,Deng Y F,et al. Extraction and Recovery of Cerium(Ⅳ) and Fluorine(Ⅰ) from Sulfuric Solutions Using Bifunctional Ionic Liquid Extractants[J]. Chem Eng J,2012,179(1):19-25.[13] Zhang D L,Wang W,Deng Y F,et al. Extraction and Recovery of Cerium(Ⅳ) and Fluorine(Ⅰ) from Sulfuric Solutions Using Bifunctional Ionic Liquid Extractants[J]. Chem Eng J,2012,179(1):19-25.

    14. [14] Wang W,Yang H L,Cui H M,et al. Application of Bifunctional Ionic Liquid Extractants [A336][CA-12] and [A336][CA-100] to the Lanthanum Extraction and Separation from Rare Earths in the Chloride Medium[J]. Ind Eng Chem Res,2011,50(12):7534-7541.[14] Wang W,Yang H L,Cui H M,et al. Application of Bifunctional Ionic Liquid Extractants [A336][CA-12] and [A336][CA-100] to the Lanthanum Extraction and Separation from Rare Earths in the Chloride Medium[J]. Ind Eng Chem Res,2011,50(12):7534-7541.

    15. [15] Sun X Q,Ji Y,Hu F C,et al. The Inner Synergistic Effect of Bifunctional Ionic Liquid Extractant for Solvent Extraction[J]. Talanta,2010,81(4/5):1877-1883.[15] Sun X Q,Ji Y,Hu F C,et al. The Inner Synergistic Effect of Bifunctional Ionic Liquid Extractant for Solvent Extraction[J]. Talanta,2010,81(4/5):1877-1883.

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  628
  • HTML全文浏览量:  60
文章相关
  • 收稿日期:  2015-08-24
  • 网络出版日期:  2015-10-21
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net