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过硼酸钠结晶介稳区的测定

叶雪芳 ,  衣守志 ,  肖清贵 ,  孙苒荻 ,  田颖 ,  徐红彬 ,  张懿

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引用本文: 叶雪芳, 衣守志, 肖清贵, 孙苒荻, 田颖, 徐红彬, 张懿. 过硼酸钠结晶介稳区的测定[J]. 应用化学, 2016, 33(3): 350-356. doi: 10.11944/j.issn.1000-0518.2016.03.150242 shu
Citation:  YE Xuefang, YI Shouzhi, XIAO Qinggui, SUN Randi, TIAN Ying, XU Hongbin, ZHANG Yi. Measurement of the Metastable Zone of Sodium Perborate Tetrahydrate[J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 350-356. doi: 10.11944/j.issn.1000-0518.2016.03.150242 shu

过硼酸钠结晶介稳区的测定

  • a.

    a. 天津科技大学材料科学与化学工程学院 天津 300457;

  • b.

    b. 中国科学院过程工程研究所湿法冶金清洁生产技术国家工程实验室 北京 100190;

  • c.

    c. 中国科学院绿色过程与工程重点实验室 北京 100190

    • 通讯作者: 肖清贵,副研究员;Tel:010-82544808;Fax:010-82544810;E-mail:qgxiao@ipe.ac.cn;研究方向:晶体生长与设计
  • 基金项目:

    国家自然科学基金资助项目（21376251，21406233）；国家高技术研究发展计划（863计划）资助项目（2011AA060702）；国家重点基础研究计划（973计划）资助项目（2013CB632600） 

摘要: 采用激光测定装置测定了过硼酸钠的溶解度和超溶解度，重点研究了过硼酸钠的溶解度、超溶解度以及结晶介稳区的变化规律，获得了过硼酸钠溶液的结晶介稳区，并用Apelblat方程对过硼酸钠的溶解度数据进行了关联。研究了降温速率、搅拌速率、六偏磷酸钠及聚丙烯酸钠添加量对过硼酸钠介稳区宽度的影响规律。研究结果表明，过硼酸钠溶解度随温度升高而增大，过硼酸钠的介稳区宽度在高温区较小而在低温区较大；降温速率的增大使过硼酸钠介稳区宽度变大，搅拌速率的增大使介稳区宽度变小；加入0.065%六偏磷酸钠和0.045%聚丙烯酸钠时获得的介稳区宽度最大。

English

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  • 收稿日期:  2015-07-10
  • 网络出版日期:  2015-08-17
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