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基于半刚性三角形羧酸配体构筑的配位聚合物的合成,结构及其荧光性质

周莲 ,  铁生年 ,  王志国

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引用本文: 周莲, 铁生年, 王志国. 基于半刚性三角形羧酸配体构筑的配位聚合物的合成,结构及其荧光性质[J]. 无机化学学报, 2015, 31(8): 1480-1488. doi: 10.11862/CJIC.2015.221 shu
Citation:  ZHOU Lian, TIE Sheng-Nian, WANG Zhi-Guo. Syntheses, Crystal Structures and Properties of Coordination Polymers Built from a Semi-rigid Tripod Carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1480-1488. doi: 10.11862/CJIC.2015.221 shu

基于半刚性三角形羧酸配体构筑的配位聚合物的合成,结构及其荧光性质

  • 1.

    青海大学新能源光伏产业研究中心, 西宁 810016

    • 通讯作者: 周莲,E-mail:zhoulianminai@126.com
  • 基金项目:

    国家自然科学基金项目(No.51463019) (No.51463019)

    青海省重点实验室发展专项资金(No.2014-Z-Y31) (No.2014-Z-Y31)

    青海大学综合实力提升工程"人才培养和创新 团队建设"项目资助。 

摘要: 通过使用一个半刚性的多齿羧酸配体3,3',3"-(((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(oxy))tribenzoic acid (H3L),在溶剂热条件下合成了4个配位聚合物{[Cd3(L)2(H2O)2]·5DMF·6H2O}n (1),{[Co3(L)2(H2O)2]·2DMF·6H2O}n (2),{[Mn3(L)2(H2O)2]·3DMF·6H2O}n (3),{[Zn3(L)2(H2O)2]·5DMA·5H2O}n (4),并通过X射线单晶衍射,热重分析对配合物结构进行了表征。4个化合物都是同构的,由沙漏型的M3簇和L3-配体作为次级结构单元,从而给出了一个金属-有机纳米笼的三维结构,从拓扑学的观点看,4个配合物的结构可以看作是三节点的(3,3,6)-连接的网络。荧光光谱测试表明配合物1和4在激发波长为272 nm下,在385 nm处显示了强的宽发射峰。荧光传感测试结果表明,配合物1是一种潜在的硝基苯类化合物的传感材料。

English

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  • 收稿日期:  2015-03-26
  • 网络出版日期:  2015-06-09
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