Cd(Ⅱ)/Zn(Ⅱ)与三(2-巯吡啶基)甲烷配合物的合成、表征及配合物中C-S键的断裂机理

杨红 韩新利

引用本文: 杨红, 韩新利. Cd(Ⅱ)/Zn(Ⅱ)与三(2-巯吡啶基)甲烷配合物的合成、表征及配合物中C-S键的断裂机理[J]. 无机化学学报, 2015, 31(8): 1597-1602. doi: 10.11862/CJIC.2015.217 shu
Citation:  YANG Hong, HAN Xin-Li. Syntheses, Crystal Structures and Cleavage Mechanism of C-S Bond in Cd(Ⅱ) and Zn(Ⅱ) Complexes with Tris(2-mercaptopyridyl) methane[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1597-1602. doi: 10.11862/CJIC.2015.217 shu

Cd(Ⅱ)/Zn(Ⅱ)与三(2-巯吡啶基)甲烷配合物的合成、表征及配合物中C-S键的断裂机理

    通讯作者: 杨红,E-mail:hmily820805@163.com
摘要: 以三(2-巯吡啶基)甲烷(L)为配体合成了2个Cd(Ⅱ)和Zn(Ⅱ)的配合物:Cd(L)4(NO3)2和Zn(L)4(ClO4)2,发现在配合物中配体的C-S键发生了断裂,通过紫外、质谱手段研究并预测了其反应机理。单晶X-射线衍射的结果显示,配合物12中金属原子均处于扭曲的四面体配位环境中,分子间π-π堆积作用将配合物1的分子结构延伸为二维网状结构。

English

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  • 收稿日期:  2014-09-18
  • 网络出版日期:  2015-07-02
通讯作者: 陈斌, bchen63@163.com
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