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以吡嗪四甲酸为配体的配合物的合成及表征

高洪苓 ,  毕艳霞 ,  张琴琴 ,  崔建中

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引用本文: 高洪苓, 毕艳霞, 张琴琴, 崔建中. 以吡嗪四甲酸为配体的配合物的合成及表征[J]. 无机化学学报, 2015, 31(8): 1603-1608. doi: 10.11862/CJIC.2015.215 shu
Citation:  GAO Hong-Ling, BI Yan-Xia, ZHANG Qin-Qin, CUI Jian-Zhong. Syntheses and Characterizations of Two Complexes with Pyrazine-2,3,5,6-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1603-1608. doi: 10.11862/CJIC.2015.215 shu

以吡嗪四甲酸为配体的配合物的合成及表征

  • 1.

    天津大学理学院化学系, 天津 300072

    • 通讯作者: 崔建中,E-mail:cuijianzhong@tju.edu.cn
  • 基金项目:

    国家自然科学基金(No.21271137,21473121) (No.21271137,21473121)

    教育部先进能源材料化学重点实验室开放基金(南开大学)资助项目。 (南开大学)

摘要: 合成了两种金属配合物{[Cu2(pztc)(4,4'-bpy)(H2O)4]·6H2O}n (1),{(H2bpe)[Cd(pztc)(H2O)2]·2.5H2O}n (2)(H4pztc=吡嗪-2,3,5,6-四甲酸,bpy=4,4'-联吡啶,bpe=1,2-二(4-吡啶基)乙烯),测定了其晶体结构,并对其进行了红外光谱、荧光光谱和热重分析等表征。两种配合物均为二维层状结构,但其中吡嗪四酸的配位方式不同。配合物2具有蓝色的荧光,最大荧光发射峰在475 nm。测试了配合物1的电子顺磁共振谱,结果显示Cu2+的特征谱带。

English

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  • 收稿日期:  2015-03-19
  • 网络出版日期:  2015-05-19
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