一系列由柔性N,N'-双(3-吡啶甲基)胺构筑的螺旋配合物的合成、结构和性质

岳翠敏 高东昭 王修光

引用本文: 岳翠敏, 高东昭, 王修光. 一系列由柔性N,N'-双(3-吡啶甲基)胺构筑的螺旋配合物的合成、结构和性质[J]. 无机化学学报, 2015, 31(8): 1609-1618. doi: 10.11862/CJIC.2015.213 shu
Citation:  YUE Cui-Min, GAO Dong-Zhao, WANG Xiu-Guang. Syntheses, Crystal Structures and Properties of a Series of Helical Complexes Constructed by Flexible N,N'-Bis(3-pyridylmethyl)amine[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1609-1618. doi: 10.11862/CJIC.2015.213 shu

一系列由柔性N,N'-双(3-吡啶甲基)胺构筑的螺旋配合物的合成、结构和性质

    通讯作者: 高东昭,E-mail:tjgaodz@sina.com
摘要: 合成和表征了5个螺旋配位聚合物{[Cu(Hbpma)(H2O)4]2(SO4)3·3.5H2O}n (1)、{[Ni(Hbpma)(H2O)4]4(SO4)6·10.75H2O}n (2)、{[Mn(Hbpma)(H2O)4](SO4)1.5·3H2O}n (3)、{[Zn(Hbpma)(H2O)4]4(SO4)6·4H2O·4CH3OH}n (4)和{[Cu(Hbpma)2(H2O)2](SO4)2·9H2O}n (5),其中bpma代表N,N'-双(3-吡啶甲基)胺。晶体结构分析表明配合物1~4为一维链状结构,配合物5为二维层状结构,其中金属离子由质子化的bpma配体桥连。值得注意的是,采取反-反式构象的柔性bpma配体使得配合物12为假螺旋链结构,配合物34为螺旋链结构,配合物5为螺旋层结构。同时研究了配合物的磁性和热稳定性。

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  • 收稿日期:  2015-04-13
  • 网络出版日期:  2015-05-28
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