多级结构Mg3B2O6:Eu3+花状微球的制备、表征及其发光性能

引用本文: 陈爱民, 汪晶, 薄盈盈, 刘锐, 顾培, 潘再法, 胡军. 多级结构Mg₃B₂O₆:Eu³⁺花状微球的制备、表征及其发光性能[J]. 无机化学学报, 2015, 31(8): 1548-1554. doi: 10.11862/CJIC.2015.208 shu

Citation: CHEN Ai-Min, WANG Jing, BO Ying-Ying, LIU Rui, GU Pei, PAN Zai-Fa, HU Jun. Synthesis, Characterization and Photoluminescence Properties of Hierarchical Mg₃B₂O₆:Eu³⁺ Flower-Like Microspheres[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1548-1554. doi: 10.11862/CJIC.2015.208 shu

多级结构Mg₃B₂O₆:Eu³⁺花状微球的制备、表征及其发光性能

1.
浙江工业大学化学工程学院, 杭州 310014

通讯作者: 陈爱民,E-mail:amchen@zjut.edu.cn;胡军,E-mail:hjzjut@zjut.edu.cn; 陈爱民,E-mail:amchen@zjut.edu.cn;胡军,E-mail:hjzjut@zjut.edu.cn

基金项目:
国家自然科学基金(No.10804099,51002137) (No.10804099,51002137)

浙江省自然科学基金(No.Y4080382)资助项目。 (No.Y4080382)

摘要: 以硝酸镁(Mg(NO₃)₂·6H₂O)和硼砂(Na₂B₄O₇·10H₂O)为原料,稀土元素Eu³⁺为激活剂,采用聚乙烯吡咯烷酮(PVP)辅助共沉淀法得到前驱体,并通过焙烧制备了多级结构Mg₃B₂O₆:Eu³⁺花状微球。通过XRD、SEM、TEM以及荧光光谱等手段分别对前驱体煅烧产物的结构、形貌、组成和荧光特性进行了表征。实验表明,在波长为393 nm激发光的激发下,所得到的产品在612 nm处有明显的特征发射峰,对应于Eu³⁺的(⁵D₀→⁷F₂)特征跃迁发射。这一荧光性质使得该材料在荧光灯、显示系统和光电设备应用中具有广阔的前景。同时我们还探讨了微球的形态、Eu³⁺的掺杂量及焙烧温度对花状微球荧光性能的影响。

关键词:

Mg₃B₂O₆:Eu³⁺;多级微球;化学合成;发光性能

English

Synthesis, Characterization and Photoluminescence Properties of Hierarchical Mg₃B₂O₆:Eu³⁺ Flower-Like Microspheres

1.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: 陈爱民,E-mail:amchen@zjut.edu.cn;胡军,E-mail:hjzjut@zjut.edu.cn; 陈爱民,E-mail:amchen@zjut.edu.cn;胡军,E-mail:hjzjut@zjut.edu.cn

Received Date: 11 March 2015
Fund Project:
国家自然科学基金(No.10804099,51002137)

浙江省自然科学基金(No.Y4080382)资助项目。

Abstract: Flower-like Mg₃B₂O₆:Eu³⁺ hierarchical microspheres, with an average diameter of 2.0~2.5 μm, were successfully synthesized via a simple precipitation method using poly (vinyl pyrrolidone) as template and followed by a subsequent heat treatment. The structure, morphology, composition and photoluminescence (PL) properties of as-prepared and calcined samples were systematically characterized by XRD, SEM, TEM and PL spectra, respectively. The resultant products presented a strong characteristic of red emission at 612 nm corresponding to ⁵D₀→⁷F₂ of the Eu³⁺ transition under ultraviolet excitation at 393 nm, which may open a wide door for its applications especially in fluorescent lamps, display systems, and optoelectronic devices. Besides, we demonstrated the morphology, concentration of Eu³⁺ as well as calcination temperature had a great effect on the PL properties of the microspheres.

Key words:

Mg₃B₂O₆:Eu³⁺;hierarchical microspheres;chemical synthesis;photoluminescence

1. [1] Mu J S, Zhang L, Zhao M, et al. ACS Appl. Mater. Interfaces, 2014,6:7090-7098[1] Mu J S, Zhang L, Zhao M, et al. ACS Appl. Mater. Interfaces, 2014,6:7090-7098
2. [2] Hu J S, Zhong L S, Song W G, et al. J. Adv. Mater., 2008, 20:2977-2982[2] Hu J S, Zhong L S, Song W G, et al. J. Adv. Mater., 2008, 20:2977-2982
3. [3] Li C C, Yin X M, Wang T H, et al. Chem. Mater., 2009,21:4984-4992[3] Li C C, Yin X M, Wang T H, et al. Chem. Mater., 2009,21:4984-4992
4. [4] Chen A M, Li J, Gu P, et al. Powder Technol., 2014,267:54-60[4] Chen A M, Li J, Gu P, et al. Powder Technol., 2014,267:54-60
5. [5] Yin S Y, Zhang Y Y, Kong J H. ACS Nano, 2011,5:3831-3838[5] Yin S Y, Zhang Y Y, Kong J H. ACS Nano, 2011,5:3831-3838
6. [6] Kim P, Kreder M J, Alvarenga J, et al. Nano Lett., 2013,13:1793-1799[6] Kim P, Kreder M J, Alvarenga J, et al. Nano Lett., 2013,13:1793-1799
7. [7] Wei X W, Zhou X M, Wu K L, et al. CrystEngComm, 2011, 13:1328-1332[7] Wei X W, Zhou X M, Wu K L, et al. CrystEngComm, 2011, 13:1328-1332
8. [8] Sarkar S, Pradhan M, Sinha A K, et al. Inorg. Chem., 2010, 49(19):8813-8827[8] Sarkar S, Pradhan M, Sinha A K, et al. Inorg. Chem., 2010, 49(19):8813-8827
9. [9] Singh B P, Parchur A K, Ningthoujam R S, et al. Dalton Trans., 2014,43:4779-4789[9] Singh B P, Parchur A K, Ningthoujam R S, et al. Dalton Trans., 2014,43:4779-4789
10. [10] Zeuner M, Hintze F, Schnick W. Chem. Mater., 2009,21:336-342[10] Zeuner M, Hintze F, Schnick W. Chem. Mater., 2009,21:336-342
11. [11] Qin X P, Zhou G H, Yang H, et al. J. Alloys Compd., 2010, 493:672-677[11] Qin X P, Zhou G H, Yang H, et al. J. Alloys Compd., 2010, 493:672-677
12. [12] Di W H, Wang X J, Chen B J. Opt. Mater., 2005,27:1386-1390[12] Di W H, Wang X J, Chen B J. Opt. Mater., 2005,27:1386-1390
13. [13] Yang J, Quan Z W, Kong D Y, et al. Cryst. Growth Des., 2007,7:730-735[13] Yang J, Quan Z W, Kong D Y, et al. Cryst. Growth Des., 2007,7:730-735
14. [14] Pao R P. J. Electrochem. Soc., 1996,143(1):189-197[14] Pao R P. J. Electrochem. Soc., 1996,143(1):189-197
15. [15] Szczeszak A, Kubasiewicz K, Lis S. Opt. Mater., 2013,35:1297-1303[15] Szczeszak A, Kubasiewicz K, Lis S. Opt. Mater., 2013,35:1297-1303
16. [16] Szczeszak A, Grzyb T, Barszcz B, et al. Inorg. Chem., 2013, 52:4934-4940[16] Szczeszak A, Grzyb T, Barszcz B, et al. Inorg. Chem., 2013, 52:4934-4940
17. [17] Cai G M, Zheng F, Yi D Q, et al. J. Lumin., 2010,130:910-916[17] Cai G M, Zheng F, Yi D Q, et al. J. Lumin., 2010,130:910-916
18. [18] Yang J, Li C X, Zhang X M, et al. Chem. Eur. J., 2008,14:4336-4345[18] Yang J, Li C X, Zhang X M, et al. Chem. Eur. J., 2008,14:4336-4345
19. [19] Jiang X C, Sun L D, Feng W, et al. Cryst. Growth Des., 2004,4(3):517-520[19] Jiang X C, Sun L D, Feng W, et al. Cryst. Growth Des., 2004,4(3):517-520
20. [20] Jia G, Zhang C M, Wang C Z, et al. CrystEngComm, 2012, 14:579-584[20] Jia G, Zhang C M, Wang C Z, et al. CrystEngComm, 2012, 14:579-584
21. [21] Dwivedi Y, Rai D K, Rai S B. Opt. Mater., 2010,32:913-919[21] Dwivedi Y, Rai D K, Rai S B. Opt. Mater., 2010,32:913-919
22. [22] WU Yan-Li(吴燕利), XU Xian-Zhu(徐贤柱), WEN Jia(文佳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015, 31:1-6[22] WU Yan-Li(吴燕利), XU Xian-Zhu(徐贤柱), WEN Jia(文佳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015, 31:1-6
23. [23] Jiang X C, Yan C H, Sun L D, et al. J. Solid State Chem., 2003,175:245-251[23] Jiang X C, Yan C H, Sun L D, et al. J. Solid State Chem., 2003,175:245-251
24. [24] Jiang X C, Sun L D, Yan C H. J. Phys. Chem. B, 2004,108:3387-3390[24] Jiang X C, Sun L D, Yan C H. J. Phys. Chem. B, 2004,108:3387-3390
25. [25] Diaz A, Keszler D A. Chem. Mater., 1997,9:2071-2077[25] Diaz A, Keszler D A. Chem. Mater., 1997,9:2071-2077
26. [26] Furetta C, Kitis G, Weng P S, et al. Nucl. Instrum. Methods Phys. Res. Sect. A, 1999,420:441-445[26] Furetta C, Kitis G, Weng P S, et al. Nucl. Instrum. Methods Phys. Res. Sect. A, 1999,420:441-445
27. [27] Liu J P, Li Y, Huang X T, et al. Chem. Mater., 2008,20:250-257[27] Liu J P, Li Y, Huang X T, et al. Chem. Mater., 2008,20:250-257
28. [28] Zhang J, Li Z Q, Zhang B. Mater. Chem. Phys., 2006,98:195-197[28] Zhang J, Li Z Q, Zhang B. Mater. Chem. Phys., 2006,98:195-197
29. [29] Tao X Y, Li X D. Nano Lett., 2008,8(2):505-510[29] Tao X Y, Li X D. Nano Lett., 2008,8(2):505-510
30. [30] Xu B S, Li T B, Zhang Y, et al. Cryst. Growth Des., 2008,8(4):1218-1222[30] Xu B S, Li T B, Zhang Y, et al. Cryst. Growth Des., 2008,8(4):1218-1222
31. [31] Zhu W C, Zhang Q, Xiang L, et al. Cryst. Growth Des., 2008,8(8):2938-2944[31] Zhu W C, Zhang Q, Xiang L, et al. Cryst. Growth Des., 2008,8(8):2938-2944
32. [32] Nuansing W, Ninmuang S, Jarernboon W, et al. Mater. Sci. Eng. B, 2006,131:147-155[32] Nuansing W, Ninmuang S, Jarernboon W, et al. Mater. Sci. Eng. B, 2006,131:147-155
33. [33] Zhang Z Y, Li X H, Wang C H, et al. J. Phys. Chem. C, 2009,113:19397-19403[33] Zhang Z Y, Li X H, Wang C H, et al. J. Phys. Chem. C, 2009,113:19397-19403
34. [34] Maensiri S, Sangmanee M, Wiengmoon A. Nanoscale Res. Lett., 2009,4:221-228[34] Maensiri S, Sangmanee M, Wiengmoon A. Nanoscale Res. Lett., 2009,4:221-228
35. [35] Li C R, Cui M Y, Sun Q T, et al. J. Alloys Compd., 2010, 504:498-502[35] Li C R, Cui M Y, Sun Q T, et al. J. Alloys Compd., 2010, 504:498-502
36. [36] LI Shan-Shan(李珊珊), XIA Hai-Ping(夏海平), FU Li(符立), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2014,30(9):1752-1757[36] LI Shan-Shan(李珊珊), XIA Hai-Ping(夏海平), FU Li(符立), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2014,30(9):1752-1757
37. [37] Bao S P, Chen X Y, Li Z, et al. CrystEngComm, 2011,13:2511-2520[37] Bao S P, Chen X Y, Li Z, et al. CrystEngComm, 2011,13:2511-2520
38. [38] Levin E M, Roth R S, Martin J B. Am. Mineral., 1961,46:1030-1053[38] Levin E M, Roth R S, Martin J B. Am. Mineral., 1961,46:1030-1053
39. [39] Zhang L H, Jia G, You H P, et al. J. Inorg. Chem., 2010,49:3305-3309[39] Zhang L H, Jia G, You H P, et al. J. Inorg. Chem., 2010,49:3305-3309
40. [40] Pang H C, Ning G L, Gong W T, et al. New J. Chem., 2011, 35:1449-1452[40] Pang H C, Ning G L, Gong W T, et al. New J. Chem., 2011, 35:1449-1452
41. [41] Judd B R. Phys. Rev., 1962,127:750-761[41] Judd B R. Phys. Rev., 1962,127:750-761

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

多级结构Mg₃B₂O₆:Eu³⁺花状微球的制备、表征及其发光性能

通讯作者: 陈爱民,E-mail:amchen@zjut.edu.cn;胡军,E-mail:hjzjut@zjut.edu.cn; 陈爱民,E-mail:amchen@zjut.edu.cn;胡军,E-mail:hjzjut@zjut.edu.cn

English

Synthesis, Characterization and Photoluminescence Properties of Hierarchical Mg₃B₂O₆:Eu³⁺ Flower-Like Microspheres

Corresponding author: 陈爱民,E-mail:amchen@zjut.edu.cn;胡军,E-mail:hjzjut@zjut.edu.cn; 陈爱民,E-mail:amchen@zjut.edu.cn;胡军,E-mail:hjzjut@zjut.edu.cn

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