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CuO-nanoparticles modified carbon paste electrode for square wave voltammetric determination of lidocaine: Comparing classical and Box–Behnken optimization methodologies

Nadereh Rahbar ,  Zahra Ramezani ,  Jamalaldin Ghanavati

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引用本文: Nadereh Rahbar,  Zahra Ramezani,  Jamalaldin Ghanavati. CuO-nanoparticles modified carbon paste electrode for square wave voltammetric determination of lidocaine: Comparing classical and Box–Behnken optimization methodologies[J]. Chinese Chemical Letters, 2016, 27(6): 837-842. doi: 10.1016/j.cclet.2016.04.017 shu
Citation:  Nadereh Rahbar,  Zahra Ramezani,  Jamalaldin Ghanavati. CuO-nanoparticles modified carbon paste electrode for square wave voltammetric determination of lidocaine: Comparing classical and Box–Behnken optimization methodologies[J]. Chinese Chemical Letters, 2016, 27(6): 837-842. doi: 10.1016/j.cclet.2016.04.017 shu

CuO-nanoparticles modified carbon paste electrode for square wave voltammetric determination of lidocaine: Comparing classical and Box–Behnken optimization methodologies

  • a Nanotechnology Research Center, Faculty of Pharmacy, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran;

  • b Medicinal Chemistry Department, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran

  • 基金项目:

    The authors are thankful for the funding provided by Jundishapur University of Medical Sciences –Nanotechnology Research Center under grant No. N-11. This paper is issued from thesis of Jamalaldin Ghanavati.

摘要: In this research, copper oxide nanoparticles modified carbon paste electrode was developed for the voltammetric determination of lidocaine. The square wave voltammogram of lidocaine solution showed a well-defined peak between +0.5 and +1.5 V. Instrumental and chemical parameters influencing voltammetric response were optimized by both one at a time and Box-Behnken model of response surfacemethodology. The results revealed that there was no significant difference between twomethods of optimization. The linear range was 1-2500 mmol L-1(Ip = 0.11CLH + 17.38, R2 = 0.999). The LOD and LOQ based on three and ten times of the signal to noise (S/N) were 0.39 and 1.3 mmol L-1 (n = 10), respectively. The precision of the method was assessed for 10 replicate square wave voltammetry (SWV) determinations each of 0.05, 0.5 and 1 mmol L-1 of lidocaine showing relative standard deviations 4.1%, 3.7% and 2.1%, respectively. The reliability of the proposed method was established by application of the method for the determination of lidocaine in two pharmaceutical preparations, namely injection and gel.

English

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  • 收稿日期:  2015-08-17
  • 修回日期:  2015-12-25
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