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Synthesis of boron nitride nanotube films with a nanoparticle catalyst

Cui-Cui Zhuang ,  Jia Feng ,  Hong Xu ,  Ling Li ,  Xiao-Wei Liu

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引用本文: Cui-Cui Zhuang,  Jia Feng,  Hong Xu,  Ling Li,  Xiao-Wei Liu. Synthesis of boron nitride nanotube films with a nanoparticle catalyst[J]. Chinese Chemical Letters, 2016, 27(6): 871-874. doi: 10.1016/j.cclet.2016.01.034 shu
Citation:  Cui-Cui Zhuang,  Jia Feng,  Hong Xu,  Ling Li,  Xiao-Wei Liu. Synthesis of boron nitride nanotube films with a nanoparticle catalyst[J]. Chinese Chemical Letters, 2016, 27(6): 871-874. doi: 10.1016/j.cclet.2016.01.034 shu

Synthesis of boron nitride nanotube films with a nanoparticle catalyst

  • MEMS Center, Harbin Institute of Technology, Harbin 150001, China

  • 基金项目:

    This work was financially supported by the National Natural Science Funds of China (No. 61404036), the National Basic Research Program of China (No. 2012CB934104), the Fundamental Research Funds for the Central Universities (Nos. HIT.NSRIF. 2015039, 01508536).

摘要: Boron nitride nanotube (BNNT) films were synthesized by combining ball milling and thermal chemical vapor deposition (CVD) using nano-Fe3O4 as a catalyst. The as-produced BNNTs have a bamboo-like structure and have a diameter in the range of 50~200 nm with an average length of more than 40 mm. Moreover, BNNT nanojunction structures were synthesized. The structure and morphology of the BNNTs were characterized by XRD, SEM, TEM and HRTEM. The possible growth mechanism of BNNTs and BNNT nanojunction structures were proposed. Though the BNNT films were observed, out of our expectation, BNNTs with thin tube wall and small average diameter have not been achieved, and this could be mainly ascribed to the aggregation of the nanoparticle catalyst, resulting in greater catalyst particles during the process of BNNT growth. This result will provide a promising approach to obtain the desired shape of BNNTs and produce branched junctions of BNNTs.

English

    1. [1] A. Rubio, J.L. Corkill, M.L. Cohen, Theory of graphitic boron nitride nanotubes, Phys. Rev. B 49 (1994) 5081-5084.

    2. [2] Q. Huang, Y. Bando, X. Xu, et al., Enhancing superplasticity of engineering ceramics by introducing BN nanotubes, Nanotechnology 18 (2007) 485706.

    3. [3] H. Chen, Y. Chen, C.P. Li, et al., Eu-doped boron nitride nanotubes as a nanometersized visible-light source, Adv. Mater. 19 (2007) 1845-1848.

    4. [4] G. Ciofani, V. Raffa, A. Menciassi, A. Cuschieri, Boron nitride nanotubes: an innovative tool for nanomedicine, Nano Today 4 (2009) 8-10.

    5. [5] S. Komatsu, Y. Shimizu, Y. Moriyoshi, K. Okada, M. Mitomo, Preparation of boron nitride nanocapsules by plasma-assisted pulsed laser deposition, J. Appl. Phys. 91 (2002) 6181-6184.

    6. [6] V.G. Naumov, F.K. Kosyrev, V.G. Vostrikov, et al., Synthesis of boron nitride multiwalled nanotubes by laser ablation technique, Laser Phys. 19 (2009) 1198-1200.

    7. [7] J.Q. Bi, W.L. Wang, Y.X. Qi, et al., Large-scale synthesis of BN nanotubes using carbon nanotubes as template, Mater. Lett. 63 (2009) 1299-1302.

    8. [8] D. Golberg, Y. Bando, K. Kurashima, T. Sato, Ropes of BN multi-walled nanotubes, Solid State Commun. 116 (2000) 1-6.

    9. [9] Y. Huang, J. Lin, C.C. Tang, et al., Bulk synthesis, growth mechanism and properties of highly pure ultrafine boron nitride nanotubes with diameters of sub-10 nm, Nanotechnology 22 (2011) 145602.

    10. [10] C.H. Lee, M. Xie, V. Kayastha, J.S. Wang, Y.K. Yap, Patterned growth of boron nitride nanotubes by catalytic chemical vapor deposition, Chem. Mater. 22 (2010) 1782-1787.

    11. [11] D. Seo, J. Kim, S.H. Park, et al., Synthesis of boron nitride nanotubes using thermal chemical vapor deposition of ball milled boron powder, J. Ind. Eng. Chem. 19 (2013) 1117-1122.

    12. [12] J.S.M. Nithya, A. Pandurangan, Efficient mixed metal oxide routed synthesis of boron nitride nanotubes, RSC Adv. 4 (2014) 26697-26705.

    13. [13] Y.J. Li, J.E. Zhou, K. Zhao, S. Tung, E. Schneider, Synthesis of boron nitride nanotubes from boron oxide by ball milling and annealing process, Mater. Lett. 63 (2009) 1733-1736.

    14. [14] L. Li, X.W. Liu, L.H. Li, Y. Chen, High yield BNNTs synthesis by promotion effect of milling-assisted precursor, Microelectron. Eng. 110 (2013) 256-259.

    15. [15] H.J. Xin, A.T. Woolley, Directional orientation of carbon nanotubes on surfaces using a gas flow cell, Nano Lett. 4 (2004) 1481-1484.

    16. [16] Y.T. Liu, X.M. Xie, Y.F. Gao, et al., Gas flow directed assembly of carbon nanotubes into horizontal arrays, Mater. Lett. 61 (2007) 334-338.

    17. [17] J.T. Hu, T.W. Odom, C.M. Lieber, Chemistry and physics in one dimension: synthesis and properties of nanowires and nanotubes, Acc. Chem. Res. 32 (1999) 435-445.

    18. [18] P. Nguyen, H.T. Ng, M. Meyyappan, Growth of individual vertical germanium nanowires, Adv. Mater. 17 (2005) 549-553.

    19. [19] J.M. Ting, T.P. Li, C.C. Chang, Carbon nanotubes with 2D and 3D multiple junctions, Carbon 42 (2004) 2997-3002.

    20. [20] J.L. Wang, Z.L. Li, Y.L. Gu, et al., Synthesis of boron nitride nanotubes using glass fabrics as catalyst growth framework, Ceram. Int. 41 (2015) 1891-1896.

    21. [21] J.L. Wang, L.P. Zhang, G.W. Zhao, et al., Selective synthesis of boron nitride nanotubes by self-propagation high-temperature synthesis and annealing process, J. Solid State Chem. 184 (2011) 2478-2484.

    22. [22] L.P. Zhang, J.L. Wang, Y.L. Gu, et al., Catalytic growth of bamboo-like boron nitride nanotubes using self-propagation high temperature synthesized porous precursor, Mater. Lett. 67 (2012) 17-20.

    23. [23] W.H. Chiang, R.M. Sankaran, In-flight dimensional tuning of metal nanoparticles by microplasma synthesis for selective production of diameter-controlled carbon nanotubes, J. Phys. Chem. C 112 (2008) 17920-17925.

    24. [24] W.H. Chiang, R.M. Sankaran, Relating carbon nanotube growth parameters to the size and composition of nanocatalysts, Diamond Relat. Mater. 18 (2009) 946-952.

    25. [25] A. Pakdel, C.Y. Zhi, Y. Bando, T. Nakayama, D. Golberg, A comprehensive analysis of the CVD growth of boron nitride nanotubes, Nanotechnology 23 (2012) 215601.

    26. [26] P. Ahmad, M.U. Khandaker, Y.M. Amin, Synthesis of boron nitride nanotubes by argon supported thermal chemical vapor deposition, Physica E 67 (2015) 33-37.

    27. [27] S.K. Singhal, A.K. Srivastava, A.K. Gupta, Z.G. Chen, Synthesis of boron nitride nanotubes by an oxide-assisted chemical method, J. Nanopart. Res. 12 (2010) 2405-2413.

    28. [28] C.C. Tang, S.S. Fan, P. Li, Y.M. Liu, H.Y. Dang, Synthesis of boron nitride in tubular form, Mater. Lett. 51 (2001) 315-319.

    29. [29] C.C. Tang, M.L. De La Chapelle, P. Li, et al., Catalytic growth of nanotube and nanobamboo structures of boron nitride, Chem. Phys. Lett. 342 (2001) 492-496.

    30. [30] C.Y. Zhi, Y. Bando, C.C. Tang, D. Golberg, Effective precursor for high yield synthesis of pure BN nanotubes, Solid State Commun. 135 (2005) 67-70.

    31. [31] C.H. Lee, J.S. Wang, V.K. Kayatsha, J.Y. Huang, Y.K. Yap, Effective growth of boron nitride nanotubes by thermal chemical vapor deposition, Nanotechnology 19 (2008) 455605.

    32. [32] J.D. Guo, C.Y. Zhi, X.D. Bai, E.G. Wang, Boron carbonitride nanojunctions, Appl. Phys. Lett. 80 (2002) 124-126.

    33. [33] W.Z. Li, J.G. Wen, Z.F. Ren, Straight carbon nanotube Y junctions, Appl. Phys. Lett. 79 (2001) 1879-1881.

    34. [34] Y. Kobayashi, H. Nakashima, D. Takagi, Y. Homma, CVD growth of single-walled carbon nanotubes using size-controlled nanoparticle catalyst, Thin Solid Films 464-465 (2004) 286-289.

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  • 收稿日期:  2015-10-13
  • 修回日期:  2015-11-25
通讯作者: 陈斌, bchen63@163.com
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